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Critical Review of Contributions to the Jahn-Teller Symposium JT2010 and Beyond Read chapter Read first chapter

2012 | OriginalPaper | Chapter

9. Vibronic Transitions to a State with Jahn-Teller Effect: Contribution of Phonons

Authors : V. Hizhnyakov, K. Pae, T. Vaikjärv

Published in: Vibronic Interactions and the Jahn-Teller Effect

Publisher: Springer Netherlands

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Abstract

A theory of electronic transitions from a non-degenerated to a two-fold degenerated or quasi-degenerated electronic state in an impurity centre of a crystal is proposed. The coupling of optical electron(s) with non-totally symmetrical vibration(s) and with phonons are taken into account. The latter interaction results in the replacement of vibronic lines by phonon-assisted bands. The widths of bands, the rates of the energy relaxation of vibronic states and the shapes of optical spectra are calculated for some values of parameters.

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previous chapter Raman Scattering for Weakened Bonds in the Intermediate States of Impurity Centres
next chapter Many-Electron Multiplet Theory Applied to O-Vacancies in (i) Nanocrystalline HfO2 and (ii) Non-crystalline SiO2 and Si Oxynitride Alloys
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Metadata
Title
Vibronic Transitions to a State with Jahn-Teller Effect: Contribution of Phonons
Authors
V. Hizhnyakov
K. Pae
T. Vaikjärv
Copyright Year
2012
Publisher
Springer Netherlands
Book
Vibronic Interactions and the Jahn-Teller Effect

Print ISBN: 978-94-007-2383-2

Electronic ISBN: 978-94-007-2384-9

Copyright Year: 2012

DOI
https://doi.org/10.1007/978-94-007-2384-9_9

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