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Journal of Coatings Technology and Research
Published in: Journal of Coatings Technology and Research 4/2016

22-01-2016

3D laser scanning confocal microscopy of siloxane-based comb and double-comb polymers in PVDF-HFP thin films

Authors: Eva Cznotka, Steffen Jeschke, Sebastian Schmohl, Patrik Johansson, Hans-Dieter Wiemhöfer

Published in: Journal of Coatings Technology and Research | Issue 4/2016

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Abstract

Currently, atomic force microscopy is the preferred technique to determine roughness on membrane surfaces. In this paper, a new method to measure surface roughness is presented using a 3D laser scanning confocal microscope for high-resolution topographic analysis and is compared to conventional SEM. For this study, the surfaces of eight samples based on a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) host polymer with different liquid interpenetrating components were analyzed. Polymethylhydrosiloxane, triethylene glycolallylmethylether, (3,3,3-trifluoropropyl)methylcyclotrisiloxane (D3-C2H4CF3), polysiloxane-comb-propyloxymethoxytriglycol (PSx), polysiloxane-comb-propyl-3,3,3-trifluoro (PSx-C2H4CF3), poly[bis(2-(2-methoxyethoxy) ethoxy) phosphazene, or poly[bis(trifluoro)ethoxy] phosphazene was chosen as interpenetrating compound to investigate the impact of comb and double-comb-structured polymer backbones, as well as their dipolar or fluorous residues on the PVDF-HFP-miscibility. Different phases of the constituting ingredients were identified via their thermal properties determined by DSC. Additionally, the COSMO-RS method supported the experimental results, and with regard to computed σ-profiles, new modified structures for polysiloxane and polyphosphazene synthesis were suggested.
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Metadata
Title
3D laser scanning confocal microscopy of siloxane-based comb and double-comb polymers in PVDF-HFP thin films
Authors
Eva Cznotka
Steffen Jeschke
Sebastian Schmohl
Patrik Johansson
Hans-Dieter Wiemhöfer
Publication date
22-01-2016
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 4/2016
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-015-9754-4

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