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Published in: Structural and Multidisciplinary Optimization 3/2013

01-03-2013 | Industrial Application

A 2D model for shape optimization of solid oxide fuel cell cathodes

Authors: X. Song, A. R. Diaz, A. Benard, J. D. Nicholas

Published in: Structural and Multidisciplinary Optimization | Issue 3/2013

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Abstract

A topology optimization method is used to identify the optimal shape of the nano-composite cathode of a solid oxide fuel cell (SOFC). A simplified analysis model is used in computations aimed at reducing ohmic losses by optimizing the shape of the cathode to minimize resistance. The model of the SOFC is reduced to a periodic, 2D conduction problem with design-dependent ionic transfer boundary conditions. Special techniques are introduced to avoid physically inadmissible designs that would otherwise be allowed by the 2D model. Isoperimetric constraints on the perimeter and the amount of material are used in the problem. Numerical examples are provided to discuss the effect of material properties and the resource restrictions introduced by the constraints. The methodology discussed can be applied to similar problems involving design-dependent boundary conditions.

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Appendix
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Literature
go back to reference Adler SB (2004) Factors governing oxygen reduction in solid oxide fuel cell cathodes. Chem Rev 104:4791–4843CrossRef Adler SB (2004) Factors governing oxygen reduction in solid oxide fuel cell cathodes. Chem Rev 104:4791–4843CrossRef
go back to reference Bendsøe MP (1989) Optimal shape design as a material distribution problem. Struct Optim 1(4):193–202CrossRef Bendsøe MP (1989) Optimal shape design as a material distribution problem. Struct Optim 1(4):193–202CrossRef
go back to reference Bruns TE (2007) Topology optimization of convection-dominated steady-state heat transfer problems. Int J Heat Mass Transfer 50:2859–2873MATHCrossRef Bruns TE (2007) Topology optimization of convection-dominated steady-state heat transfer problems. Int J Heat Mass Transfer 50:2859–2873MATHCrossRef
go back to reference Chan SH, Khor K, Xia ZT (2001) A complete polarization model of a solid oxide fuel cell its sensitivity to the change of cell component thickness. J Power Sources 93:130–140CrossRef Chan SH, Khor K, Xia ZT (2001) A complete polarization model of a solid oxide fuel cell its sensitivity to the change of cell component thickness. J Power Sources 93:130–140CrossRef
go back to reference Deseure J, Bultel Y, Dessemond L, Siebert E (2005) Theoretical optimization of a SOFC composite cathode. Electrochim Acta 50(10):2037–2046CrossRef Deseure J, Bultel Y, Dessemond L, Siebert E (2005) Theoretical optimization of a SOFC composite cathode. Electrochim Acta 50(10):2037–2046CrossRef
go back to reference Farhad S, Hamdullahpur F (2012) Optimization of the microstructure of porous composite cathodes in solid oxide fuel cells. AICHE J 58(4):1248–1261CrossRef Farhad S, Hamdullahpur F (2012) Optimization of the microstructure of porous composite cathodes in solid oxide fuel cells. AICHE J 58(4):1248–1261CrossRef
go back to reference Glowinski R, Pan TW, Wells RO, Zhou XD (1996) Wavelet finite element solutions for the Neumann problem using fictitious domains. J Comput Phys 126(1):40–51MathSciNetMATHCrossRef Glowinski R, Pan TW, Wells RO, Zhou XD (1996) Wavelet finite element solutions for the Neumann problem using fictitious domains. J Comput Phys 126(1):40–51MathSciNetMATHCrossRef
go back to reference Haanappel VAC, Mertens J, Rutenbeck D, Tropartz C, Herzhof W, Sebold D, Tietz F (2005) Optimisation of processing microstructural parameters of LSM cathodes to improve the electrochemical performance of anode-supported SOFCs. J Power Sources 141:216–226CrossRef Haanappel VAC, Mertens J, Rutenbeck D, Tropartz C, Herzhof W, Sebold D, Tietz F (2005) Optimisation of processing microstructural parameters of LSM cathodes to improve the electrochemical performance of anode-supported SOFCs. J Power Sources 141:216–226CrossRef
go back to reference Haralick RM, Shapiro LG (1992) Computer robot vision. Wiley, New York, pp 157–253 Haralick RM, Shapiro LG (1992) Computer robot vision. Wiley, New York, pp 157–253
go back to reference Iga A, Nishiwaki S, Izui K, Yoshimura M (2009) Topology optimization for thermal conductors considering design-dependent effects, including heat conduction convection. Int J Heat Mass Transfer 52:2721–2732MATHCrossRef Iga A, Nishiwaki S, Izui K, Yoshimura M (2009) Topology optimization for thermal conductors considering design-dependent effects, including heat conduction convection. Int J Heat Mass Transfer 52:2721–2732MATHCrossRef
go back to reference Iwai H, Kuroyanagi A, Saito M, Konno A, Yoshida H, Yamada T, Nishiwaki S (2011) Power generation enhancement of solid oxide fuel cell by cathode-electrolyte interface modification in mesoscale assisted by level set-based optimization calculation. J Power Sources 196:3485–3495CrossRef Iwai H, Kuroyanagi A, Saito M, Konno A, Yoshida H, Yamada T, Nishiwaki S (2011) Power generation enhancement of solid oxide fuel cell by cathode-electrolyte interface modification in mesoscale assisted by level set-based optimization calculation. J Power Sources 196:3485–3495CrossRef
go back to reference Kawamoto A, Matsumori T, Yamasaki S, Nomura T, Kondoh T, Nishiwaki S (2011) Heaviside projection based topology optimization by a PDE-filtered scalar function. Struct Multidisc Optim 44:19–24CrossRef Kawamoto A, Matsumori T, Yamasaki S, Nomura T, Kondoh T, Nishiwaki S (2011) Heaviside projection based topology optimization by a PDE-filtered scalar function. Struct Multidisc Optim 44:19–24CrossRef
go back to reference Kenney B, Karan K (2007) Engineering of microstructure design of a planar porous composite SOFC cathode: a numerical analysis. Solid State Ionics 178:297–306CrossRef Kenney B, Karan K (2007) Engineering of microstructure design of a planar porous composite SOFC cathode: a numerical analysis. Solid State Ionics 178:297–306CrossRef
go back to reference Li XG (2006) Principles of fuel cells, Taylor Francis, New York, pp 494–503 Li XG (2006) Principles of fuel cells, Taylor Francis, New York, pp 494–503
go back to reference Nicholas JD, Barnett SA (2009) Finite-element modeling of idealized infiltrated composite solid oxide fuel cell cathodes. J Electrochem Soc 156(4):458–464CrossRef Nicholas JD, Barnett SA (2009) Finite-element modeling of idealized infiltrated composite solid oxide fuel cell cathodes. J Electrochem Soc 156(4):458–464CrossRef
go back to reference Nicholas JD, Barnett SA (2010) Measurements and modeling of Sm0.5Sr0.5CoO3 − x —Ce0.9Gd0.1O1.95 SOFC cathodes produced using infiltrate solution additives. J Electrochem Soc 157:B536CrossRef Nicholas JD, Barnett SA (2010) Measurements and modeling of Sm0.5Sr0.5CoO3 − x —Ce0.9Gd0.1O1.95 SOFC cathodes produced using infiltrate solution additives. J Electrochem Soc 157:B536CrossRef
go back to reference O’Hayre RP, Cha SW, Colella WG, Prinz FB (2009) Fuel cell fundamentals. Wiley, New York, pp 270–272 O’Hayre RP, Cha SW, Colella WG, Prinz FB (2009) Fuel cell fundamentals. Wiley, New York, pp 270–272
go back to reference Shah M, Barnett SA (2008) Solid oxide fuel cell cathodes by infiltration of La0.6Sr0.4Co0.2Fe0.8O3 − x into Gd-doped ceria. Solid State Ionics 179:2059–2064CrossRef Shah M, Barnett SA (2008) Solid oxide fuel cell cathodes by infiltration of La0.6Sr0.4Co0.2Fe0.8O3 − x into Gd-doped ceria. Solid State Ionics 179:2059–2064CrossRef
go back to reference Shah M, Nicholas JD, Barnett SA (2009) Prediction of infiltrated solid oxide fuel cell cathode polarization resistance using simple models. Electrochem Commun 11:2–5CrossRef Shah M, Nicholas JD, Barnett SA (2009) Prediction of infiltrated solid oxide fuel cell cathode polarization resistance using simple models. Electrochem Commun 11:2–5CrossRef
go back to reference Sigmund O, Petersson J (1998) Numerical instabilities in topology optimization: a survey on procedures dealing with checkboards, mesh dependencies local minima. Struct Optim 16:68–75CrossRef Sigmund O, Petersson J (1998) Numerical instabilities in topology optimization: a survey on procedures dealing with checkboards, mesh dependencies local minima. Struct Optim 16:68–75CrossRef
go back to reference Svanberg K (1987) The method of moving asymptotes—a new method for structural optimization. Int J Numer Methods Eng 24(2):359–373MathSciNetMATHCrossRef Svanberg K (1987) The method of moving asymptotes—a new method for structural optimization. Int J Numer Methods Eng 24(2):359–373MathSciNetMATHCrossRef
go back to reference Tanner CW, Fung KZ, Virkar AV (1997) The effect of porous composite electrode structure on solid oxide fuel cell performance: theoretical analysis. J Electrochem Soc 144(1):21–30CrossRef Tanner CW, Fung KZ, Virkar AV (1997) The effect of porous composite electrode structure on solid oxide fuel cell performance: theoretical analysis. J Electrochem Soc 144(1):21–30CrossRef
go back to reference Wang L, Nicholas JD (2011) Simple Infiltrated Microstructure Polarization Loss Estimation (SIMPLE) model predictions of today tomorrow’s nano-composite SOFC cathodes. In: Singhal S, Eguchi K (eds) Twelfth international symposium on solid oxide fuel cells, pp 2321–2329 (ECS Transactions, The Electrochemical Society, Montreal, Canada, 2011) Wang L, Nicholas JD (2011) Simple Infiltrated Microstructure Polarization Loss Estimation (SIMPLE) model predictions of today tomorrow’s nano-composite SOFC cathodes. In: Singhal S, Eguchi K (eds) Twelfth international symposium on solid oxide fuel cells, pp 2321–2329 (ECS Transactions, The Electrochemical Society, Montreal, Canada, 2011)
go back to reference Wells RO, Zhou XD (1992) Wavelet solutions for the Dirichlet problem. Technical report 92 02, Rice University, Computational Mathematics Lab, vol 126 no 1, pp 40–51 Wells RO, Zhou XD (1992) Wavelet solutions for the Dirichlet problem. Technical report 92 02, Rice University, Computational Mathematics Lab, vol 126 no 1, pp 40–51
go back to reference Yoon GH, Kim YY (2005) The element connectivity parameterization formulation for the topology design optimization of multiphysics system. Int J Numer Methods Eng 64:1649–1677MathSciNetMATHCrossRef Yoon GH, Kim YY (2005) The element connectivity parameterization formulation for the topology design optimization of multiphysics system. Int J Numer Methods Eng 64:1649–1677MathSciNetMATHCrossRef
Metadata
Title
A 2D model for shape optimization of solid oxide fuel cell cathodes
Authors
X. Song
A. R. Diaz
A. Benard
J. D. Nicholas
Publication date
01-03-2013
Publisher
Springer-Verlag
Published in
Structural and Multidisciplinary Optimization / Issue 3/2013
Print ISSN: 1615-147X
Electronic ISSN: 1615-1488
DOI
https://doi.org/10.1007/s00158-012-0837-x

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