Skip to main content
Top
Published in: Biomass Conversion and Biorefinery 5/2021

19-11-2019 | Original Article

A biorefinery concept using forced chicory roots for the production of biogas, hydrochar, and platform chemicals

Authors: Katrin Stökle, Benedikt Hülsemann, David Steinbach, Zebin Cao, Hans Oechsner, Andrea Kruse

Published in: Biomass Conversion and Biorefinery | Issue 5/2021

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Chicory roots (Cichorium intybus L.) are an agricultural residue from salad production. After forcing, the roots contain ingredients from which further products can be obtained. Thus, forced chicory roots can still be considered as a low-cost feedstock for the production of valuable products. Sugars can be extracted and then be used for the production of platform chemicals like 5-hydroxymethylfurfural. Remaining sugars and other components can be degraded during hydrothermal carbonization, where a carbon-enriched hydrochar and a process water enriched in organic components are produced. The process water can be anaerobically digested to produce biogas. In this paper, a cascaded utilization of chicory roots was investigated. Of the initial sugars in the roots, 67.5 wt.% were extracted in a batch extraction with hot water. During hydrothermal carbonization in batch autoclaves, hydrochar yields of up to 66.2 wt.% were achieved. A methane potential of 255 L CH4/kg COD was determined from process water after carbonization. With this additional anaerobic digestion of the process water, a complete utilization of the forced chicory root is achieved. Therefore, in this work, a biorefinery concept for forced chicory roots combining sugar extraction, hydrothermal carbonization, and anaerobic digestion was investigated to elongate the value chain of chicory and to enable an optimum usage of the biomass. The carbon efficiency of this cascaded utilization was 96% whereas the state of the art process only showed 40%.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
3.
go back to reference Wonneberger C, Keller F, Bahnmüller H et al (2004) Gemüsebau. Eugen Ulmer GmbH & Co., Stuttgart Wonneberger C, Keller F, Bahnmüller H et al (2004) Gemüsebau. Eugen Ulmer GmbH & Co., Stuttgart
14.
go back to reference Quicker P, Weber K (eds) (2016) Biokohle: Herstellung, Eigenschaften und Verwendung von Biomassekarbonisaten. Springer Vieweg, Wiesbaden Quicker P, Weber K (eds) (2016) Biokohle: Herstellung, Eigenschaften und Verwendung von Biomassekarbonisaten. Springer Vieweg, Wiesbaden
16.
go back to reference Hoffmann V, Jung D, Zimmermann J et al (2019) Conductive carbon materials from the hydrothermal carbonization of vineyard residues for the application in electrochemical double-layer capacitors (EDLCs) and direct carbon fuel cells (DCFCs). Materials (Basel) 12(10). https://doi.org/10.3390/ma12101703 Hoffmann V, Jung D, Zimmermann J et al (2019) Conductive carbon materials from the hydrothermal carbonization of vineyard residues for the application in electrochemical double-layer capacitors (EDLCs) and direct carbon fuel cells (DCFCs). Materials (Basel) 12(10). https://​doi.​org/​10.​3390/​ma12101703
21.
go back to reference Helffrich D, Oechsner H (2003) The Hohenheim biogas yield test: comparison of different laboratory techniques for the digestion of biomass. Landtechnik 58(3):148–149 Helffrich D, Oechsner H (2003) The Hohenheim biogas yield test: comparison of different laboratory techniques for the digestion of biomass. Landtechnik 58(3):148–149
24.
go back to reference Sluiter A, Hames B, Ruiz R et al. (2008) Determination of structural carbohydrates and lignin in biomass: laboratory analytical procedure (LAP) (Revised July 2011) Sluiter A, Hames B, Ruiz R et al. (2008) Determination of structural carbohydrates and lignin in biomass: laboratory analytical procedure (LAP) (Revised July 2011)
25.
go back to reference Channiwala SA, Parikh PP (2002) A unified correlation for estimating HHV of solid, liquid and gaseous fuels. Fuel(81): 1051–1063 Channiwala SA, Parikh PP (2002) A unified correlation for estimating HHV of solid, liquid and gaseous fuels. Fuel(81): 1051–1063
26.
go back to reference Wilson RG, Smith JA, Yonts CD (2004) Chicory root yield and carbohydrate composition is influenced by cultivar selection, planting, and harvest date. Crop Sci. 44:748–752CrossRef Wilson RG, Smith JA, Yonts CD (2004) Chicory root yield and carbohydrate composition is influenced by cultivar selection, planting, and harvest date. Crop Sci. 44:748–752CrossRef
39.
go back to reference Santillán-Urquiza E, Arteaga-Cardona F, Hernandez-Herman E, Pacheco-García PF, González-Rodríguez R, Coffer JL, Mendoza-Alvarez ME, Vélez-Ruiz JF, Méndez-Rojas MA (2015) Inulin as a novel biocompatible coating: evaluation of surface affinities toward CaHPO4, α-Fe2O3, ZnO, CaHPO4@ZnO and α-Fe2O3@ZnO nanoparticles. J Colloid Interface Sci 460:339–348. https://doi.org/10.1016/j.jcis.2015.08.057CrossRef Santillán-Urquiza E, Arteaga-Cardona F, Hernandez-Herman E, Pacheco-García PF, González-Rodríguez R, Coffer JL, Mendoza-Alvarez ME, Vélez-Ruiz JF, Méndez-Rojas MA (2015) Inulin as a novel biocompatible coating: evaluation of surface affinities toward CaHPO4, α-Fe2O3, ZnO, CaHPO4@ZnO and α-Fe2O3@ZnO nanoparticles. J Colloid Interface Sci 460:339–348. https://​doi.​org/​10.​1016/​j.​jcis.​2015.​08.​057CrossRef
57.
go back to reference KTBL (2015) Gasausbeute in landwirtschaftlichen Biogasanlagen, 3rd edn. Kuratorium für Technik und Bauwesen in der Landwirtschaft e.V. (KTBL) KTBL (2015) Gasausbeute in landwirtschaftlichen Biogasanlagen, 3rd edn. Kuratorium für Technik und Bauwesen in der Landwirtschaft e.V. (KTBL)
Metadata
Title
A biorefinery concept using forced chicory roots for the production of biogas, hydrochar, and platform chemicals
Authors
Katrin Stökle
Benedikt Hülsemann
David Steinbach
Zebin Cao
Hans Oechsner
Andrea Kruse
Publication date
19-11-2019
Publisher
Springer Berlin Heidelberg
Published in
Biomass Conversion and Biorefinery / Issue 5/2021
Print ISSN: 2190-6815
Electronic ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-019-00527-w

Other articles of this Issue 5/2021

Biomass Conversion and Biorefinery 5/2021 Go to the issue