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Colloid and Polymer Science
Published in: Colloid and Polymer Science 11/2017

05-09-2017 | Original Contribution

A colorimetric study of the interaction of cationic and anionic surfactants with anionic gold nanoparticles

Authors: Julia Kazakova, Alejandro García-Povea, Marta Fernández-Palacios, Mercedes Villar-Navarro, Jose Maria Carnerero, Aila Jimenez-Ruiz, Rafael Prado-Gotor

Published in: Colloid and Polymer Science | Issue 11/2017

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Abstract

The interactions of citrate-capped 10-nm gold nanoparticles with a cationic model surfactant, CTACl, and an anionic one, SDS, are explored. Results show that for CTACl, values of the c.m.c. close to those reported in the absence of nanoparticles can be obtained by simple colorimetric measurements. For SDS, its interaction with the same-charge nanoparticles is explored through the use of an indirect colorimetric method involving NaCl addition, and a surfactant-nanoparticle interaction model is postulated in this basis. C.m.c. measurements for SDS in the presence of AuNPs show that, despite both substrates being anionic, SDS micelle formation is actually promoted in the presence of gold nanoparticles.
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Appendix
Available only for authorised users
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Metadata
Title
A colorimetric study of the interaction of cationic and anionic surfactants with anionic gold nanoparticles
Authors
Julia Kazakova
Alejandro García-Povea
Marta Fernández-Palacios
Mercedes Villar-Navarro
Jose Maria Carnerero
Aila Jimenez-Ruiz
Rafael Prado-Gotor
Publication date
05-09-2017
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 11/2017
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4186-6

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