Skip to main content
Top
Published in: Journal of Coatings Technology and Research 2/2013

01-03-2013

A comparative study on the effect of type of reinforcement on the scratch behavior of a polyacrylic-based nanocomposite coating

Authors: S. A. Sajjadi, M. H. Avazkonandeh-Gharavol, S. M. Zebarjad, M. Mohammadtaheri, M. Abbasi, K. Mossaddegh

Published in: Journal of Coatings Technology and Research | Issue 2/2013

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this article the effects of type of reinforcement on the scratch behavior of nanocomposite coatings are studied. Such coatings can be used in the automotive industry as clear top paint coats. Three types of reinforcements were used, including detonation nanodiamond, nondetonation nanodiamond, and nano-alumina, with an average particle size of 4–6, 50–60, and ~50 nm, respectively. Nanocomposites containing 1.5 and 3 wt% of each filler type in polyacrylic as matrix were produced by sonication. The macrostructure, microstructure, and scratch behavior of coatings were investigated and compared with those of neat polyacrylic polymer. The scratch behavior was evaluated based on the ASTM G171 standard and also by common industrial tests such as the pencil hardness test. The results revealed that the nano-alumina coatings showed the best, and the nondetonation nanodiamond coatings the worst, scratch resistance—even less than that of the neat polyacrylic polymer.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Dasari, A, Yu, ZZ, Mai, YW, “Fundamental Aspects and Recent Progress on Wear/Scratch Damage in Polymer Nanocomposites.” Mater. Sci. Eng. R Rep., 63 (2) 31–80 (2009)CrossRef Dasari, A, Yu, ZZ, Mai, YW, “Fundamental Aspects and Recent Progress on Wear/Scratch Damage in Polymer Nanocomposites.” Mater. Sci. Eng. R Rep., 63 (2) 31–80 (2009)CrossRef
2.
go back to reference Zhou, S, Wu, L, Suna, J, Shen, W, “The Change of the Properties of Acrylic-Based Polyurethane via Addition of Nano-Silica.” Prog. Org. Coat., 45 (1) 33–42 (2002)CrossRef Zhou, S, Wu, L, Suna, J, Shen, W, “The Change of the Properties of Acrylic-Based Polyurethane via Addition of Nano-Silica.” Prog. Org. Coat., 45 (1) 33–42 (2002)CrossRef
3.
go back to reference Zhou, S, Wu, L, Shen, W, Gu, G, “Study on the Morphology and Tribological Properties of Acrylic Based Polyurethane/Fumed Silica Composite Coatings.” J. Mater. Sci., 39 (5) 1593–1600 (2004)CrossRef Zhou, S, Wu, L, Shen, W, Gu, G, “Study on the Morphology and Tribological Properties of Acrylic Based Polyurethane/Fumed Silica Composite Coatings.” J. Mater. Sci., 39 (5) 1593–1600 (2004)CrossRef
4.
go back to reference Ahmadi, B, Kassiriha, M, Khodabakhshi, K, Mafi, ER, “Effect of Nano Layered Silicates on Automotive Polyurethane Refinish Clear Coat.” Prog. Org. Coat., 60 (2) 99–104 (2007)CrossRef Ahmadi, B, Kassiriha, M, Khodabakhshi, K, Mafi, ER, “Effect of Nano Layered Silicates on Automotive Polyurethane Refinish Clear Coat.” Prog. Org. Coat., 60 (2) 99–104 (2007)CrossRef
5.
go back to reference Jalili, MM, Moradian, S, Dastmalchian, H, Karbasi, A, “Investigating the Variations in Properties of 2-Pack Polyurethane Clear Coat Through Separate Incorporation of Hydrophilic and Hydrophobic Nano-Silica.” Prog. Org. Coat., 59 (1) 81–87 (2007)CrossRef Jalili, MM, Moradian, S, Dastmalchian, H, Karbasi, A, “Investigating the Variations in Properties of 2-Pack Polyurethane Clear Coat Through Separate Incorporation of Hydrophilic and Hydrophobic Nano-Silica.” Prog. Org. Coat., 59 (1) 81–87 (2007)CrossRef
6.
go back to reference Amerio, E, Fabbri, P, Malucelli, G, Messori, M, Sangermano, M, Taurino, R, “Scratch Resistance of Nano-Silica Reinforced Acrylic Coatings.” Prog. Org. Coat., 62 (2) 129–133 (2008)CrossRef Amerio, E, Fabbri, P, Malucelli, G, Messori, M, Sangermano, M, Taurino, R, “Scratch Resistance of Nano-Silica Reinforced Acrylic Coatings.” Prog. Org. Coat., 62 (2) 129–133 (2008)CrossRef
7.
go back to reference Tahmassebi, N, Moradian, S, Ramezanzadeh, B, Khosravi, A, Behdad, S, “Effect of Addition of Hydrophobic Nano-Silica on Viscoelastic Properties and Scratch Resistance of an Acrylic/Melamine Automotive Clear Coat.” Tribol. Int., 43 (3) 685–693 (2010)CrossRef Tahmassebi, N, Moradian, S, Ramezanzadeh, B, Khosravi, A, Behdad, S, “Effect of Addition of Hydrophobic Nano-Silica on Viscoelastic Properties and Scratch Resistance of an Acrylic/Melamine Automotive Clear Coat.” Tribol. Int., 43 (3) 685–693 (2010)CrossRef
8.
go back to reference Shenderova, OA, Zhirnov, VV, Brenner, DW, “Carbon nanostructures.” Crit. Rev. Solid State Mater. Sci., 27 (3–4) 227–356 (2002)CrossRef Shenderova, OA, Zhirnov, VV, Brenner, DW, “Carbon nanostructures.” Crit. Rev. Solid State Mater. Sci., 27 (3–4) 227–356 (2002)CrossRef
9.
go back to reference Schrand, AM, Ciftan Hens, SA, Shenderova, OA, “Nanodiamond Particles: Properties and Perspectives for Bioapplications.” Crit. Rev. Solid State Mater. Sci., 34 (1–2) 18–74 (2009)CrossRef Schrand, AM, Ciftan Hens, SA, Shenderova, OA, “Nanodiamond Particles: Properties and Perspectives for Bioapplications.” Crit. Rev. Solid State Mater. Sci., 34 (1–2) 18–74 (2009)CrossRef
10.
go back to reference Shenderova, OA, Gruen, DM, Ultrananocrystalline Diamond: Synthesis, Properties, and Applications. William Andrew Publishing, New York, 2006 Shenderova, OA, Gruen, DM, Ultrananocrystalline Diamond: Synthesis, Properties, and Applications. William Andrew Publishing, New York, 2006
11.
go back to reference Behler, KD, Stravato, A, Mochalin, V, Korneva, G, Yushin, G, Gogotsi, Y, “Nanodiamond-Polymer Composite Fibers and Coatings.” ACS Nano, 3 (2) 363–369 (2009)CrossRef Behler, KD, Stravato, A, Mochalin, V, Korneva, G, Yushin, G, Gogotsi, Y, “Nanodiamond-Polymer Composite Fibers and Coatings.” ACS Nano, 3 (2) 363–369 (2009)CrossRef
12.
go back to reference Maitra, U, Prasad, KE, Ramamurty, U, Rao, CNR, “Mechanical Properties of Nanodiamond-Reinforced Polymer-Matrix Composites.” Solid State Commun., 149 (39–40) 1693–1697 (2009)CrossRef Maitra, U, Prasad, KE, Ramamurty, U, Rao, CNR, “Mechanical Properties of Nanodiamond-Reinforced Polymer-Matrix Composites.” Solid State Commun., 149 (39–40) 1693–1697 (2009)CrossRef
13.
go back to reference Shenderova, O, Tyler, T, Cunningham, G, Ray, M, Walsh, J, Casulli, M, Hens, S, McGuire, G, Kuznetsov, V, Lipa, S, “Nanodiamond and Onion-Like Carbon Polymer Nanocomposites.” Diamond Relat. Mater., 16 (4–7 spec. iss.) 1213–1217 (2007) Shenderova, O, Tyler, T, Cunningham, G, Ray, M, Walsh, J, Casulli, M, Hens, S, McGuire, G, Kuznetsov, V, Lipa, S, “Nanodiamond and Onion-Like Carbon Polymer Nanocomposites.” Diamond Relat. Mater., 16 (4–7 spec. iss.) 1213–1217 (2007)
14.
go back to reference Korobko, AP, Bessonova, NP, Krasheninnikov, SV, Konyukhova, EV, Drozd, SN, Chvalun, SN, “Nanodiamonds as Modifier of Ethylene-1-Octene Copolymer Structure and Properties.” Diamond Relat. Mater., 16 (12) 2141–2144 (2007)CrossRef Korobko, AP, Bessonova, NP, Krasheninnikov, SV, Konyukhova, EV, Drozd, SN, Chvalun, SN, “Nanodiamonds as Modifier of Ethylene-1-Octene Copolymer Structure and Properties.” Diamond Relat. Mater., 16 (12) 2141–2144 (2007)CrossRef
15.
go back to reference Karbushev, VV, Konstantinov, II, Parsamyan, IL, Kulichikhin, VG, Popov, VA, George, TF, “Preparation of Polymer-Nanodiamond Composites with Improved Properties.” Adv. Mater. Res., 59 275–278 (2009)CrossRef Karbushev, VV, Konstantinov, II, Parsamyan, IL, Kulichikhin, VG, Popov, VA, George, TF, “Preparation of Polymer-Nanodiamond Composites with Improved Properties.” Adv. Mater. Res., 59 275–278 (2009)CrossRef
16.
go back to reference Voznyakovskioe, AP, “Self-Organization in Nanocomposites Based on Detonation Nanodiamonds.” Phys. Solid State, 46 (4) 644–648 (2004)CrossRef Voznyakovskioe, AP, “Self-Organization in Nanocomposites Based on Detonation Nanodiamonds.” Phys. Solid State, 46 (4) 644–648 (2004)CrossRef
17.
go back to reference Sung, LP, Comer, J, Forster, AM, Hu, H, Floryancic, B, Brickweg, L, Fernando, RH, “Scratch Behavior of Nano-Alumina/Polyurethane Coatings.” J. Coat. Technol. Res., 5 (4) 419–430 (2008)CrossRef Sung, LP, Comer, J, Forster, AM, Hu, H, Floryancic, B, Brickweg, L, Fernando, RH, “Scratch Behavior of Nano-Alumina/Polyurethane Coatings.” J. Coat. Technol. Res., 5 (4) 419–430 (2008)CrossRef
18.
go back to reference Floryancic, BR, Brickweg, LJ, Fernando, RH, “Effects of alumina and silica nanoparticles on automotive clear-coat properties.” In: Provder, T, et al. (eds.) Smart Coatings II, pp. 220–235. ACS Symposium Series, Washington, DC, 2009 Floryancic, BR, Brickweg, LJ, Fernando, RH, “Effects of alumina and silica nanoparticles on automotive clear-coat properties.” In: Provder, T, et al. (eds.) Smart Coatings II, pp. 220–235. ACS Symposium Series, Washington, DC, 2009
19.
go back to reference Zhou, S, Wu, L, “Development of Nanotechnology-Based Organic Coatings.” Compos. Interfaces, 16 (4) 281–292 (2009)CrossRef Zhou, S, Wu, L, “Development of Nanotechnology-Based Organic Coatings.” Compos. Interfaces, 16 (4) 281–292 (2009)CrossRef
20.
go back to reference Dashtizadeha, A, Abdouss, M, Mahdavi, H, Khorassani, M, “Acrylic Coatings Exhibiting Improved Hardness, Solvent Resistance and Glossiness by Using Silica Nano-Composites.” Appl. Surf. Sci., 257 (6) 2118–2125 (2011)CrossRef Dashtizadeha, A, Abdouss, M, Mahdavi, H, Khorassani, M, “Acrylic Coatings Exhibiting Improved Hardness, Solvent Resistance and Glossiness by Using Silica Nano-Composites.” Appl. Surf. Sci., 257 (6) 2118–2125 (2011)CrossRef
Metadata
Title
A comparative study on the effect of type of reinforcement on the scratch behavior of a polyacrylic-based nanocomposite coating
Authors
S. A. Sajjadi
M. H. Avazkonandeh-Gharavol
S. M. Zebarjad
M. Mohammadtaheri
M. Abbasi
K. Mossaddegh
Publication date
01-03-2013
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 2/2013
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-012-9442-6

Other articles of this Issue 2/2013

Journal of Coatings Technology and Research 2/2013 Go to the issue

Premium Partners