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01-08-2012 | Original Paper

A comparison of analytical methods for the quantification of a reactive β-cyclodextrin fixed onto cotton yarns

Authors: R. Peila, G. Migliavacca, F. Aimone, A. Ferri, S. Sicardi

Published in: Cellulose | Issue 4/2012

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Abstract

Cotton yarns bobbins were treated in a water bath with different concentrations of a reactive β-cyclodextrin derivative. To quantify the amount of cyclodextrin fixed on the fiber different analytical methods were tested but none of them was reliable enough in the concentration range under investigation. Therefore, a new analytical method, fast and effective, was developed. From the measurement of cyclodextrin bath exhaustion, the amount of cyclodextrin chemically fixed and that physically adsorbed on the textile substrate was estimated. Two washing cycles were carried out to investigate the cyclodextrin washing fastness.

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Astray G et al (2009) A review on the use of cyclodextrins in foods. Food Hydrocoll 23:1631–1640. doi:10.1016/j.foodhyd.2009.01.001 CrossRef

Bereck A (2010) Cyclodextrins in textile finishing: fixation and analysis. Adv Mater Res 93:1–4. doi:10.4028/www.scientific.net/AMR.93-94.1 CrossRef

Boutelliez CB, Fontanay S, Finance C, Kedzierewic F (2010) Preparation and physicochemical characterization of amoxicilin β-cyclodetrin complexes. AAPS Pharm Sci Tech 11:574–581. doi:10.1208/s12249-010-9412-1 CrossRef

Buschmann H-J, Knittel D, Schollmeyer E (2001) New textile applications of cyclodextrins. J Incl Phenom Macrocycl Chem 40:169–172CrossRef

Cravotto G, Beltramo L, Sapino S, Binello A, Carlotti ME (2011) A new cyclodextrin-grafted viscose loaded with aescin formulations for a cosmeto-textile approach to chronicmvenous insufficiency. J Mater Sci Mater Med 22:2387–2395. doi:10.1007/s10856-011-4399-z CrossRef

De Bergamasco RC, Zanin GM, De Moraes FF (2007) Grafting of cyclodextrins onto filter paper. J Incl Phenom Macrocycl Chem 57:75–78. doi:10.1007/s10847-006-9217-8 CrossRef

Del Valle EM, Martin (2004) Cyclodextrins and their uses: a review. Process Biochem 39:1033–1046. doi:10.1016/S0032-9592(03)00258-9 CrossRef

Giordano F, Novak C, Moyano JR (2001) Thermal analysis of cyclodextrins and their inclusion compounds. Thermochim Acta 380:123–151CrossRef

Goel A, Nene SN (1995) Modifications in the phenolphthalein method for spectrophotometric estimation of beta cyclodextrin. Starch Stärke 47:399–400. doi:10.1002/star.19950471006 CrossRef

Grechin AG, Buschmann HJ, Schollmeyer E (2007) Quantification of cyclodextrins fixed onto cellulose fibers. Text Res J 77(3):161–164. doi:10.1177/0040517507078063 CrossRef

Hebeish A, Moustafa MG, Fouda IA, Hamdy, EL-Sawy SM, Abdel-Mohdy FA (2008) Preparation of durable insect repellent cotton fabric: limonene as insecticide. Carbohydr Polym 74:268–273. doi:10.1016/j.carbpol.2008.02.013 CrossRef

Heise HM, Kuckuk R, Damm U, Bereck A, Riegel D (2005) Quantitative diffuse reflectance infrared spectroscopy of cotton fabrics treated with a cyclodextrin derivative finishing auxiliary. J Mol Struct 744:877–880. doi:10.1016/j.molstruc.2004.10.097 CrossRef

Hirotsu T (2006) Plasma graft polymerization of glycidyl methacrylate and cyclodextrin immobilization. Thin Solid Films 506:173–175. doi:10.1016/j.tsf.2005.08.209 CrossRef

Kistamah N, Carr CM, Rosunee S (2006) Surface chemical analysis of tencel and cotton treated with a monochlorotriazinyl β-cyclodextrin derivative. J Mater Sci 41:2195–2200. doi:10.1007/s10853-006-7183-6 CrossRef

Kurkov SV, Ukhatskaya EV, Loftsson T (2011) Drug/cyclodextrin: beyond inclusion complexation. J Incl Phenom Macrocycl Chem 69:297–301. doi:10.1007/s10847-010-9756-x CrossRef

Lo Nostro P, Fratoni L, Baglioni P (2002) Modification of a cellulosic fabric with β-cyclodextrin for textile finishing applications. J Incl Phenom Macrocycl Chem 44:423–427CrossRef

Park CS, Park KH, Kim SH (1989) Rapid screening method for alkaline/J-cyclodextrin glucanotransferase using phenolphthalein-methyl orange-containing solid medium. Agric Biol Chem 53:1167–1169CrossRef

Popescu V, Muresan EI, Grigoriu A (2011) Monochlorotriazinyl-β-cyclodextrin grafting onto polyester fabrics and films. Carbohydr Polym 86:600–611. doi:10.1016/j.carbpol.2011.04.080 CrossRef

Qian L, Guan Y, Ziaee Z, He B, Zheng A, Xiao H (2009) Rendering cellulose fibers antimicrobial using cationic β-cyclodextrin-based polymers included with antibiotics. Cellul 16:309–317. doi:10.1007/s10570-008-9270-0 CrossRef

Scalia S, Tursilli R, Bianchi A, Lo Nostro P, Bocci E, Ridi F, Baglioni P (2006) Incorporation of the sunscreen agent, octyl methoxycinnamate in a cellulosic fabric grafted with β-cyclodextrin. Int J Pharma 308:155–159. doi:10.1016/j.ijpharm.2005.11.007

Szejtli J (2004) Past, present, and future of cyclodextrin research. Pure Appl Chem 76:1825–1845CrossRef

Van der Maarel MJEC, Van der Veen B, Uitdehaag JCM, Leemhuis H, Dijkhuizen L (2002) Properties and applications of starch-converting enzymes of the α-amylase family. J Biotechnol 94:137–155CrossRef

Voncina B, Le Marechal MA (2005) Grafting of cotton with β-cyclodextrin via poly(carboxylic acid). J Appl Polym Sci 96:1323–1328. doi:10.1002/app.21442 CrossRef

Wang J, Cai Z (2008) Incorporation of the antibacterial agent, miconazole nitrate into a cellulosic fabric grafted with β-cyclodextrin. Carbohydr Polym 72:695–700. doi:10.1016/j.carbpol.2007.10.019 CrossRef

Wang CX, Lin SC (2004) Anchoring β-cyclodextrin to retain fragrances on cotton by means of heterobifunctional reactive dyes. Color Technol 120:14–18CrossRef

Wuppertal University—Wacker (2010) Cyclodextrin. http://www.chemiedidaktik.uni-wuppertal.de/disido_cy/cyen/index_en.html

Title: A comparison of analytical methods for the quantification of a reactive β-cyclodextrin fixed onto cotton yarns
Authors: R. Peila
G. Migliavacca
F. Aimone
A. Ferri
S. Sicardi
Publication date: 01-08-2012
Publisher: Springer Netherlands
Published in: Cellulose / Issue 4/2012
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-012-9710-8

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