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Journal of Materials Science

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11-05-2020 | Chemical routes to materials

A covalent organic framework–MnO₂ nanosheet system for determination of glutathione

Authors: Fei Qu, Hang Yan, Kexin Li, Jinmao You, Wenli Han

Published in: Journal of Materials Science | Issue 23/2020

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Abstract

Covalent organic frameworks (COFs) are usually synthesized by virtue of Schiff base reaction between amino and aldehyde groups. Owing to their electron-rich property, COFs are widely applied to detect electron-deficient nitroaromatic explosives through photoinduced electron transfer mechanism. However, except for these cases, the COFs-based chemosensors are rarely reported for the analysis of electron-rich biomolecules. In this work, a fluorescent platform constructed by COFs and MnO₂ nanosheets is developed for sensitive detection of glutathione (GSH). It is found that the fluorescence of COFs can be effectively quenched by MnO₂ nanosheets. The quenching mechanisms involving inner filter effect and static quenching effect are discussed in detail. Due to the reducing ability of GSH, it can trigger the reduction of MnO₂ to Mn²⁺, accompanying with the fluorescence recovery of COFs. The linear range of GSH is achieved from 0.5 to 100 µM with a detection limit of 0.28 µM. This method is further applied for GSH detection in human serum samples with satisfactory results.

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Title: A covalent organic framework–MnO2 nanosheet system for determination of glutathione
Authors: Fei Qu
Hang Yan
Kexin Li
Jinmao You
Wenli Han
Publication date: 11-05-2020
Publisher: Springer US
Published in: Journal of Materials Science / Issue 23/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-04754-9

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