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Journal of Materials Science
Published in: Journal of Materials Science 23/2020

11-05-2020 | Ceramics

Effects of oxygen partial pressure on the electrical properties and phase transitions in (Ba,Ca)(Ti,Zr)O3 ceramics

Authors: Wei Cai, Qianwei Zhang, Chuang Zhou, Rongli Gao, Fengqi Wang, Gang Chen, Xiaoling Deng, Zhenhua Wang, Nengyun Deng, Li Cheng, Chunlin Fu

Published in: Journal of Materials Science | Issue 23/2020

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Abstract

To enhance the piezoelectric responses, Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) ceramics were fabricated by a sol–gel method in various sintering atmospheres. The effects of oxygen partial pressure on the microstructure and electrical properties of BCZT ceramics were systematically investigated. The samples sintered in air, O2 and N2 are the coexistence of the orthorhombic (O)-tetragonal (T) phase at room temperature. The phase transition temperature of the O–T phase of BCZT samples sintered in air, O2 and N2 is gradually closer to room temperature. The results of EDS, XPS and the activation energy confirm the significant effect of oxygen sintering atmosphere. BCZT samples sintered in oxygen atmosphere show excellent ferroelectricity (2Pr = 31.62 μC/cm2, 2EC = 3.46 kV/cm) and significantly enhanced piezoelectricity (d33 = 604.3 pC/N, d 33 *  = 647.5 pm/V and kp = 58%), resulting from the minimum oxygen vacancy, the phase transition temperature of O–T closer to room temperature and dense microstructure. These results demonstrate that adjusting oxygen partial pressure in sintering is an effective way to enhance the piezoelectric responses of BCZT ceramics.
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Metadata
Title
Effects of oxygen partial pressure on the electrical properties and phase transitions in (Ba,Ca)(Ti,Zr)O3 ceramics
Authors
Wei Cai
Qianwei Zhang
Chuang Zhou
Rongli Gao
Fengqi Wang
Gang Chen
Xiaoling Deng
Zhenhua Wang
Nengyun Deng
Li Cheng
Chunlin Fu
Publication date
11-05-2020
Publisher
Springer US
Published in
Journal of Materials Science / Issue 23/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04771-8

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