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Journal of Materials Science

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14-05-2020 | Ceramics

Spectroscopic study of some new cobalt-doped tellurite glass–ceramics

Authors: Liviu Bolunduţ, Petru Păşcuţă, Eugen Culea, Maria Boşca, Lidia Pop, Răzvan Ştefan

Published in: Journal of Materials Science | Issue 23/2020

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Abstract

New glass–ceramics of the xCo₂O₃(100 − x)[80TeO₂–19Li₂O–1ZrO₂] system (where 0 ≤ x ≤ 20 mol%) were prepared by melt-quenching technique and investigated by X-ray diffraction, FTIR, UV–Vis and EPR spectroscopies. The nature of the samples and the structural changes that take place with increasing the cobalt oxide content were followed by X-ray diffraction. FTIR spectroscopy shows that the network structure of the studied samples consists of TeO₃, TeO₄, LiO₄, CoO₆ and ZrO₄ structural units and the proportion between these units depends on the cobalt content of samples. UV–Vis measurements performed in the 300–1800 nm spectral range show absorption peaks characteristics of transitions belonging to both Co²⁺ and Co³⁺ ions. Based on the UV–Vis data, the optical band gap energy, refractive index, dielectric constant and tendency of metallization of the studied system were determined. The compositional evolution of these parameters was discussed with respect to the cobalt ions content of samples. The EPR spectra show the presence of Co²⁺ ions in both their high- and low-spin states, S = 3/2 and S = 1/2.

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Title: Spectroscopic study of some new cobalt-doped tellurite glass–ceramics
Authors: Liviu Bolunduţ
Petru Păşcuţă
Eugen Culea
Maria Boşca
Lidia Pop
Răzvan Ştefan
Publication date: 14-05-2020
Publisher: Springer US
Published in: Journal of Materials Science / Issue 23/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-04749-6

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