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Metallurgical and Materials Transactions B
Published in: Metallurgical and Materials Transactions B 6/2012

01-12-2012

A Critical Evaluation and Thermodynamic Optimization of the CaO-CaF2 System

Authors: Dong-Geun Kim, Marie-Aline Van Ende, Corrie van Hoek, Christian Liebske, Sieger van der Laan, In-Ho Jung

Published in: Metallurgical and Materials Transactions B | Issue 6/2012

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Abstract

A critical evaluation and thermodynamic optimization of all the available literature experimental data of the CaO-CaF2 system was conducted to obtain a set of thermodynamic functions which can reproduce all available and reliable experimental phase diagrams and thermodynamic data. The liquid solution was described using the Modified Quasichemical Model which assumes the mixing of O2 and F− in the pseudo anionic sublattice and CaF2 solid solution was described using the compound energy formalism. The discrepancies in the CaO and CaF2 liquidii among the available experimental data were resolved. The recent experimental data on the solubility of CaO in solid CaF2 phase were well reproduced, which is critical to explain the eutectic temperature of the system.
previous article Kinetics of Carbon Dissolution of Coke in Molten Iron
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Metadata
Title
A Critical Evaluation and Thermodynamic Optimization of the CaO-CaF2 System
Authors
Dong-Geun Kim
Marie-Aline Van Ende
Corrie van Hoek
Christian Liebske
Sieger van der Laan
In-Ho Jung
Publication date
01-12-2012
Publisher
Springer US
Published in
Metallurgical and Materials Transactions B / Issue 6/2012
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-012-9733-4

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