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Polymer Bulletin
Published in: Polymer Bulletin 4/2018

15-06-2017 | Original Paper

A novel comb-shaped polymethacrylate-based copolymers with immobilized 2,4-dihydroxybenzaldehyde for antifungal activity

Authors: Nalinthip Chanthaset, Hiroharu Ajiro, Mitsuru Akashi, Chantiga Choochottiros

Published in: Polymer Bulletin | Issue 4/2018

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Abstract

Poly(methacrylic acid-co-2-aminoethyl methacrylate) (MAA-AMA) was simply synthesized by free radical polymerization. Immobilization of 2,4-dihydroxybenzaldehyde on MAA-AMA was done via Schiff base formation to obtain MAA-AMA(BZ). The qualitative and quantitative analyses of immobilization were done by nuclear magnetic resonance spectroscopy. The degree of immobilization of 2,4-dihydroxybenzaldehyde on MAA-AMA was 16–18%. Surface charge and particle size of MAA-AMA(BZ) is pH sensitive. In addition, intermolecular amidation provided cross-link structure at pH 12. The MAA-AMA(BZ) acted as an antifungal against Aspergillus genus with a percentage efficiency up to 25% against A. fumigatus.
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Appendix
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Metadata
Title
A novel comb-shaped polymethacrylate-based copolymers with immobilized 2,4-dihydroxybenzaldehyde for antifungal activity
Authors
Nalinthip Chanthaset
Hiroharu Ajiro
Mitsuru Akashi
Chantiga Choochottiros
Publication date
15-06-2017
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 4/2018
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2095-y

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