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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 2/2012

01-11-2012 | Original Paper

A novel lariat-silacrown ether based in sol–gel process: synthesis, characterization and interaction study with the copper(II) ion

Authors: Rômulo A. L. Campos, Ana Gabriela S. Bezerra, Mônica F. Belian, Valberes B. Nascimento, André Galembeck

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2012

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Abstract

The synthesis and characterization of the lariat-silacrown ether (Sila15NH—IUPAC name: 3-[1-[[1-(3-aminopropyl)-2,5,8,11,14-pentaoxa-1-silacyclotetradec-1-yl] oxy]-2,5,8,11,14-pentaoxa-1-silacyclotetradec-1-yl]propan-1-amine) and its complex with copper(II) ion, Cu(II)–Sila15NH, are reported in this work. Tetraethylene glycol, 3-aminopropyl triethoxysilane and metallic sodium were employed as precursors and the lariat-silacrown ether obtained in a good yield (64 %) was characterized by elemental analysis, infrared spectroscopy (FTIR) and nuclear magnetic resonance of 1H, 13C and 29Si. The Cu(II)–Sila15NH was characterized by elemental analysis and FTIR. The straightforward Cu(II) complex formation suggests this property could be explored for analytical purposes.
previous article Microstructure and dielectrical responses of pure and cobalt-doped CaCu3Ti4O12 ceramics by sol–gel synthesis route
next article Crucial factors affecting the physicochemical properties of sol–gel produced Fe3O4@SiO2–NH2 core–shell nanomaterials

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Appendix
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Metadata
Title
A novel lariat-silacrown ether based in sol–gel process: synthesis, characterization and interaction study with the copper(II) ion
Authors
Rômulo A. L. Campos
Ana Gabriela S. Bezerra
Mônica F. Belian
Valberes B. Nascimento
André Galembeck
Publication date
01-11-2012
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2012
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-012-2863-y

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