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Metallurgical and Materials Transactions B
Published in: Metallurgical and Materials Transactions B 2/2016

31-12-2015

A Structural Molar Volume Model for Oxide Melts Part II: Li2O-Na2O-K2O-MgO-CaO-MnO-PbO-Al2O3-SiO2 Melts—Ternary and Multicomponent Systems

Authors: Eric Thibodeau, Aimen E. Gheribi, In-Ho Jung

Published in: Metallurgical and Materials Transactions B | Issue 2/2016

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Abstract

A structural molar volume model based on the silicate tetrahedral Q-species has been developed to accurately predict the molar volume of molten oxides. In this study, the molar volumes of ternary and multicomponent melts in the Li2O-Na2O-K2O-MgO-CaO-MnO-PbO-Al2O3-SiO2 system are reviewed and compared with the predicted molar volumes from the newly developed structural model. The model can accurately predict the molar volumes using binary model parameters without any ternary or multicomponent parameters. The nonlinear behavior in the molar volume of silicate melts is well predicted by the present model.
previous article A Structural Molar Volume Model for Oxide Melts Part I: Li2O-Na2O-K2O-MgO-CaO-MnO-PbO-Al2O3-SiO2 Melts—Binary Systems
next article A Structural Molar Volume Model for Oxide Melts Part III: Fe Oxide-Containing Melts

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Literature
1.
A. D. Pelton and M. Blander, Metallurgical and Materials Transactions B, vol. 17B, pp. 805-815 (1986).CrossRef
2.
C. W. Bale, E. Bélisle, P. Chartrand, S. A. Decterov, G. Eriksson, K. Hack, I. H. Jung, Y. B. Kang, J. Melançon, A. D. Pelton, C. Robelin, and S. Petersen, “FactSage thermochemical software and databases — recent developments,” Calphad, vol. 33, pp. 295-311 (2009).CrossRef
3.
R. L. Lange and I. S. E. Carmichael, “Thermodynamic properties of silicate liquids with emphasis on density, thermal expansion and compressibility,” Reviews in Mineralogy and Geochemistry, vol. 24, pp. 25-64 (1990).
4.
J. O. M. Bockris, J. W. Tomlinson, and J. L. White, “The structure of the liquid silicates: Partial molar volumes and expansivities,” Transactions of the Faraday Society, vol. 52, pp. 299-310 (1956).CrossRef
5.
A. Din: Untersuchungen zum strukturellen Aufbau der Gläser Na2O*xMeO*(6-x)SiO2 aus der Temperaturabhängigkeit der Dichte, der Viskosität und davon abgeleiteter Größen., Technische Universitaet Clausthal (Germany), Ph.D. Thesis (1968).
6.
L. Sasek and A. Lisy, “Structure and properties of silicate melts. I. Effect of the size of ions on glass melt density at high temperatures,” Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, L: Chemie a Technologie Silikatu, vol. L2, pp. 165-215 (1972).
7.
L. Sasek and A. Lisy, “Structure and properties of silicate melts. II. Density of binary alkali-silica glass melts,” Sbornik Vysoke Skoly Chemicko-Technologicke v Praze, L: Chemie a Technologie Silikatu, vol. L2, pp. 217-254 (1972).
8.
N. K. Dertev and E. P. Golovin, “Analytical method of calculation of density of a three component silicate melt,” Trudy Gor’kovskogo Politekhnicheskogo Instituta im. A. A. Zhdanova, vol. 29, pp. 27-30 (1973).
9.
Y. Suginohara, T. Yanagase, and H. Ito, “The effects of oxide additions on the structure-sensitive properties of lead silicate melts,” Transactions of the Japan Institute of Metals, vol. 3, pp. 227-233 (1962).CrossRef
10.
T. Ejima, M. Hino, and M. Kameda, “Surface tension, density and viscosity of PbO-SiO2-Li2O ternary melts,” Journal of the Japan Institute of Metals, vol. 34, pp. 546-550 (1970).
11.
R. A. Lange and I. S. E. Carmichael, “Densities of Na2O-K2O-MgO-MgO-FeO-Fe2O3-Al3O3-TiO2-SiO2 liquids: New measurements and derived partial molar properties,” Geochimica et Cosmochimica Acta, vol. 51, pp. 2931-2946 (1987).CrossRef
12.
A. Adachi, K. Ogino, and H. Toritani, “The surface tension of molten silicates,” Technology Reports of the Osaka University, vol. 10, pp. 149-156 (1960).
13.
M. Coenen, “Density of cord glasses at high temperatures,” Glastechnische Berichte, vol. 39, pp. 81-89 (1966).
14.
K. A. Kostanyan and E. K. Karapetyan, “Density of molten glasses,” Armyanskii Khimicheskii Zhurnal, vol. 20, pp. 253-256 (1967).
15.
M. Hino, T. Ejima, and M. Kameda, “Surface tension, density and viscosity of PbO-Na2O-SiO2 ternary melts,” Journal of the Japan Institute of Metals, vol. 32, pp. 809-814 (1968).
16.
E. F. Riebling, “Structure of sodium aluminosilicate melts containing at least 50 mol pct SiO2 at 1500C,” The Journal of Chemical Physics, vol. 44, pp. 2857-2865 (1966).CrossRef
17.
S. A. Nelson and I. S. E. Carmichael, “Partial molar volumes of oxide components in silicate liquids,” Contributions to Mineralogy and Petrology, vol. 71, pp. 117-124 (1979).CrossRef
18.
D. J. Stein, J. F. Stebbins, and I. S. E. Carmichael, “Density of molten sodium aluminosilicates,” Journal of the American Ceramic Society, vol. 69, pp. 396-399 (1986).CrossRef
19.
M. Hino, T. Ejima, and M. Kameda, “Surface tension, density and viscosity of PbO-K2O-SiO2 ternary melts,” Journal of the Japan Institute of Metals, vol. 33, pp. 617-622 (1969).
20.
E. V. Ermolaeva, “Surface tension, viscosity, and density relations of three-component refractory oxide melts,” Ogneupory, vol. 20, pp. 221-228 (1955).
21.
T. Licko and V. Danek, “Densities of melts in the system calcium silicate-calcium magnesium silicate (CaMgSi2O6)-calcium magnesium silicate (Ca2MgSi2O7),” Physics and Chemistry of Glasses, vol. 23, pp. 67-71 (1982).
22.
H. Taniguchi, “Densities of melts in the system CaMgSi2O6-CaAl2Si2O8 at low and high pressures, and their structural significance,” Contributions to Mineralogy and Petrology, vol. 103, pp. 325-334 (1989).CrossRef
23.
R. Knoche, D. B. Dingwell, and S. L. Webb, “Temperature-dependent thermal expansivities of silicate melts: The system anorthite-diopside,” Geochimica et Cosmochimica Acta, vol. 56, pp. 689-699 (1992).CrossRef
24.
Y. Ouchi, T. Yoshida, and E. Kato, “Densities of ternary lead-silicate melts,” Journal of the Japan Institute of Metals, vol. 41, pp. 865-874 (1977).
25.
E. F. Riebling, “Structure of magnesium aluminosilicate liquids at 1700 °C,” Canadian Journal of Chemistry, vol. 42, pp. 2811-2821 (1964).CrossRef
26.
T. M. Kekelidze, S. M. Mikiashvili, T. I. Dzhincharadze, and R. V. Khomeriki, “Density and surface tension of oxide melts of the manganese oxide-calcium oxide-silica and manganese oxide-calcium oxide-silica-alumina systems,” Izvestiya Akademii Nauk Gruzinskoi SSR, Seriya Khimicheskaya, vol. 4, pp. 240-244 (1978).
27.
L. Segers, A. Fontana, and R. Winand, “Poids specifiques et volumes molaires de melanges d’oxydes fondus du systeme CaO-SiO2-MnO,” Electrochimica Acta, vol. 23, pp. 1275-1280 (1978).CrossRef
28.
J. Lee, L. T. Hoai, J. Choe, and J. H. Park, “Density measurements of CaO-MnO-SiO2 slags,” ISIJ International, vol. 52, pp. 2145-2148 (2012).CrossRef
29.
L. R. Barrett and A. G. Thomas, “Surface tension and density measurements on molten glasses in the CaO-Al2O3-SiO2 system,” Journal of the Society of Glass Technology, vol. 43, pp. 179-190 (1959).
30.
R. Kammel and H. Winterhager, “Structure and properties of metallurgical slags. V. Density determinations and electrical conductivity measurements on melts in the system lime-alumina-silica,” Zeitschrift fuer Erzbergbau und Metallhuettenwesen, vol. 18, pp. 9-17 (1965).
31.
V. D. Smolyarenko, A. M. Yakushev, and F. P. Edneral, “Density and surface tension of lime-alumina slags with additions of SiO2, MgO, and Na3AlF6,” Izvestiya Vysshikh Uchebnykh Zavedenii, Chernaya Metallurgiya, vol. 8, pp. 55-60 (1965).
32.
P. P. Evseev and A. F. Filippov, “Physical and chemical properties of slags of the CaO-Al2O3-MxAy system. II. Surface tension and density of the slags,” Izvestiya Vysshikh Uchebnykh Zavedenii, Chernaya Metallurgiya, vol. 10, pp. 55-59 (1967).
33.
A. I. Bochorishvili and S. B. Yakobashvili, “Effect of metal oxide on the surface tension of lime-alumina slags,” Svarochnoe Proizvodstvo, vol. 1, pp. 13-15 (1968).
34.
A. N. Sokolov, V. V. Baidov, and L. L. Kunin, “Velocity of ultrasound density, and surface tension as information on the structure of calcium oxide-alumina-silica system,” Fizicheskaya Khimiya i Elektrokhimiya Rasplavlennykh Solei i Shlakov, vol. No. 1, pp. 299-307 (1969).
35.
E. V. Krinochkin, K. T. Kurochkin, and P. V. Umrikhin, “Surface tension and density of oxide melts in the calcium oxide-silica-alumina system,” Fizicheskaya Khimiya Poverkhnostnykh Yavlenii v Rasplavakh, vol. 1, pp. 179-183 (1971).
36.
A.M. Yakushev, V.M. Romashin, and N. Ivanova, Izvestiya Vysshikh Uchebnykh Zavedenii, Chernaya Metallurgiya pp. 47–50 (1985).
37.
P. Courtial and D. B. Dingwell, “Nonlinear composition dependence of molar volume of melts in the CaO-Al2O3-SiO2 system,” Geochimica et Cosmochimica Acta, vol. 59, pp. 3685-3695 (1995).CrossRef
38.
I. A. Magidson, A. V. Basov, and N. A. Smirnov, “Density and molar volume of CaO-Al2O3-SiO2 (+Na2O) melts,” Izvestiya Vysshikh Uchebnykh Zavedenii, Chernaya Metallurgiya, vol. 5, pp. 8-13 (2007).
39.
L. Muhmood and S. Seetharaman, “Density measurements of low silica CaO-SiO2-Al2O3 slags,” Metallurgical and Materials Transactions B, vol. 41, pp. 833-840 (2010).CrossRef
40.
M. Zielinski and B. Sikora, “Surface tension of the calcium oxide-alumina system with additions of silica, iron(III) oxide, calcium fluoride, sodium fluoride, and magnesia,” Prace Instytutu Metalurgii Zelaza im. Stanislawa Staszica, vol. 29, pp. 157-165 (1977).
41.
J. Li, T. Zeng, J. Xu, C. Jie, J. Zhang, and K. Chou, in 4th International Symposium on High-Temperature Metallurgical Processing, pp. 95–102 (2013).
42.
A. Din, M. R. Sheikh, and H. W. Hennicke, “Coordination number of magnesium ions in silicate glasses,” Pakistan Journal of Scientific and Industrial Research, vol. 17, pp. 93-95 (1974).
43.
P. Courtial and D. B. Dingwell, “Densities of melts in the CaO-MgO-Al2O3-SiO2 system,” American Mineralogist, vol. 84, pp. 465-476 (1999).CrossRef
44.
J. W. Tomlinson, M. S. R. Heynes, and J. O. M. Bockris, “The structure of liquid silicates. Part 2.-Molar volumes and expansivities,” Transactions of the Faraday Society, vol. 54, pp. 1822-1833 (1958).CrossRef
45.
Y. Bottinga, D. Weill, and P. Richet, “Density calculations for silicate liquids. I. Revised method for aluminosilicate compositions,” Geochimica et Cosmochimica Acta, vol. 46, pp. 909-919 (1982).CrossRef
46.
J.-F. Xu, J.-Y. Zhang, C. Jie, L. Tang, and K.-C. Chou, “Measuring and modeling of density for selected CaO-MgO-Al2O3-SiO2 slag with low silica,” Journal of Iron and Steel Research, International, vol. 19, pp. 26-32 (2012).CrossRef
47.
H. G. L. K. R. Winterhager, “Untersuchungen über die Dichte und die elektrische Leitfähigkeit von Schmelzen der Systeme CaO-Al2O3-SiO2 und CaO-MgO-Al2O3-SiO2.” Westdeutscher Verlag: Köln u. Opladen, (1966).
48.
T.I. Dzhincharadze, S.M. Mikiashvili, and R.V. Khomeriki, Pererab. Zhelezn. i Margantsev. Rud Zakavraz’ya, Tbilisi, pp. 141–48 (1979).
49.
I. A. Aksay, J. A. Pask, and R. F. Davis, “Densities of SiO2-Al2O3 melts,” Journal of the American Ceramic Society, vol. 62, pp. 332-336 (1979).CrossRef
50.
Y. S. Anisimov, E. F. Grits, and B. S. Mitin, “Surface tension and density of aluminum oxide-silicon dioxide and aluminum oxide-chromic oxide melts,” Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, vol. 13, pp. 1444-1446 (1977).
51.
W.-Y. Kim, Modelling viscosity of molten slags and glasses, École Polytechnique de Montréal, Ph.D. Thesis (2011).
Metadata
Title
A Structural Molar Volume Model for Oxide Melts Part II: Li2O-Na2O-K2O-MgO-CaO-MnO-PbO-Al2O3-SiO2 Melts—Ternary and Multicomponent Systems
Authors
Eric Thibodeau
Aimen E. Gheribi
In-Ho Jung
Publication date
31-12-2015
Publisher
Springer US
Published in
Metallurgical and Materials Transactions B / Issue 2/2016
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-015-0543-3

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