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Journal of Material Cycles and Waste Management
Published in: Journal of Material Cycles and Waste Management 3/2019

26-10-2018 | ORIGINAL ARTICLE

Adsorption of copper ions by fly ash modified through microwave-assisted hydrothermal process

Authors: Qili Qiu, Xuguang Jiang, Guojun Lv, Zhiliang Chen, Shengyong Lu, Mingjiang Ni, Jianhua Yan, Xuliang Lin, Huibo Song, Junjun Cao

Published in: Journal of Material Cycles and Waste Management | Issue 3/2019

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Abstract

In this study, a microwave-assisted hydrothermal process (MAHP) is used to modify municipal solid waste incineration (MSWI) fly ash. The influences of the dosage, additives, liquid-to-solid ratio (L/S), temperature, and reaction time are investigated in detail, and it is found that the modified fly ash (MFA) exhibits the highest adsorption capacity of Cu2+ (32.05 mg/g) when modified under the conditions of 1 mol/L Na2HPO4, an L/S ratio of 3 mL/g, a reaction temperature of 200 °C and a reaction time of 30 min. The cation exchange capacity (CEC) of the fly ash remarkably increases from 0.022 to 0.498 meq/g after treatment, which is an increase of approximately 22 times. X-ray diffraction results reveal the formation of zeolitic crystals in the MFA. To study the adsorption mechanism, the Cu2+ adsorption isotherms and kinetics are measured. The adsorption behaviors are well described by the Freundlich isotherm equation with a correlation coefficient of 0.986 and by a pseudo-second-order kinetic equation with a correlation coefficient of 0.998. Overall, utilizing MSWI fly ash as adsorbents should receive more attention, and the MAHP is considered to be a promising technology.
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Metadata
Title
Adsorption of copper ions by fly ash modified through microwave-assisted hydrothermal process
Authors
Qili Qiu
Xuguang Jiang
Guojun Lv
Zhiliang Chen
Shengyong Lu
Mingjiang Ni
Jianhua Yan
Xuliang Lin
Huibo Song
Junjun Cao
Publication date
26-10-2018
Publisher
Springer Japan
Published in
Journal of Material Cycles and Waste Management / Issue 3/2019
Print ISSN: 1438-4957
Electronic ISSN: 1611-8227
DOI
https://doi.org/10.1007/s10163-018-0806-6

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