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Journal of Polymer Research

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01-02-2019 | ORIGINAL PAPER

Adsorptive removal of chromium(VI) using spherical resorcinol-formaldehyde beads prepared by inverse suspension polymerization

Authors: Khudbudin Mulani, Vishwanath Patil, Nayaku Chavan, Kamini Donde

Published in: Journal of Polymer Research | Issue 2/2019

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Abstract

The spherical cross-linked beaded polymers were prepared by condensation of resorcinol and formaldehyde in presence of tri-ethylamine by inverse suspension polymerization technique. The m-cresol, aniline, urea and thiourea were used as co-monomer and polyethylene glycol (PEG 400) was used as porogen. Paraffin oil was used as non-aqueous suspension agent. The polymeric spherical beads were prepared using various types of comonomers exhibiting range of particle size 77.62 to 158.84 μm at 90 °C and 300 rpm for 4 h. The resulting beads were analyzed by elemental analysis, particle size analysis and scanning electron microscope (SEM). The synthesized beads were used for the removal of Cr(VI) from aqueous solutions. A simple and sensitive solid phase extraction procedure was used for the determination of chromium at trace level by spectrophotometric method using 1,5-diphenylcarbazide reagent. The adsorption of Cr(VI) on the resorcinol-formaldehyde beads was monitored by energy-dispersive X-ray spectroscopy (EDX) analysis. The metal adsorption parameters such as contact time, pH, metal ion concentration and adsorbent dose were investigated. For Cr(VI), the maximum adsorption capacity was about 99% at pH 2 for the resorcinol-formaldehyde beads obtained.

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Title: Adsorptive removal of chromium(VI) using spherical resorcinol-formaldehyde beads prepared by inverse suspension polymerization
Authors: Khudbudin Mulani
Vishwanath Patil
Nayaku Chavan
Kamini Donde
Publication date: 01-02-2019
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 2/2019
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-019-1705-9

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