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Published in: Journal of Coatings Technology and Research 4/2013

01-07-2013

Aziridine cure of acrylic colloidal unimolecular polymers (CUPs)

Authors: Jigar K. Mistry, Michael R. Van De Mark

Published in: Journal of Coatings Technology and Research | Issue 4/2013

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Abstract

Polymers were synthesized with a 1:7 or 1:8 ratio of acrylic acid to acrylate monomers to produce an acid-rich resin. The polymers were water-reduced and solvent-stripped to produce colloidal unimolecular polymers (CUPs). These particles are typically 3–9 nm in diameter, depending upon the molecular weight, and have different rheological behavior from micelles, polyelectrolytes, fullerenes, and latex particles, due to their charged surface and large surface areas. They were then formulated into ambient cure clearcoatings with aziridine crosslinking. These aziridine-cured acrylic CUPs were either solvent-free or very low VOC. The coatings were evaluated for their MEK resistance, adhesion, hardness, gloss, flexibility, wet adhesion, and abrasion and impact resistance properties.

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Metadata
Title
Aziridine cure of acrylic colloidal unimolecular polymers (CUPs)
Authors
Jigar K. Mistry
Michael R. Van De Mark
Publication date
01-07-2013
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 4/2013
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-013-9489-z

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