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Journal of Materials Science

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13-03-2023 | Materials for life sciences

Bio-nanocomposites films based on unmodified and modified thermoplastic starch reinforced with chemically modified nanoclays

Authors: M. P. Guarás, M. Menossi, A. Torres Nicolini, V. A. Alvarez, L. N. Ludueña

Published in: Journal of Materials Science | Issue 12/2023

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Abstract

The use of polymers capable of being degraded by the action of microorganisms and/or enzymes without causing harmful effects is a strategy in waste management and environmental care. In this work, bio-nanocomposites based on thermoplastic starch (TPS) were synthesized by reactive extrusion using a twin-screw extruder. Two strategies were evaluated to reduce the disadvantages of TPS for packaging applications. First, starch was chemically modified producing the reaction of native starch with chemical reagents that introduce new functional groups to reduce the water adsorption. And two, nano-fillers were incorporated into TPS in order to enhance the mechanical and barrier properties, driving to materials with improved performance/cost ratio. The synergistic strategies of chemical modification and incorporation of modified nanoclays were also effective to reduce the dependence of properties of TPS with the environment humidity and the evolution thereof over time, which influences the performance during the service life of the product.

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Title: Bio-nanocomposites films based on unmodified and modified thermoplastic starch reinforced with chemically modified nanoclays
Authors: M. P. Guarás
M. Menossi
A. Torres Nicolini
V. A. Alvarez
L. N. Ludueña
Publication date: 13-03-2023
Publisher: Springer US
Published in: Journal of Materials Science / Issue 12/2023
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-023-08354-1

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