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Glass and Ceramics

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06-11-2023

Bismuthate Glass as Backing for Gas Sensors

Authors: V. A. Kjutvitsky, I. A. Romanova, E. V. Mironova, V. V. Borisova, O. I. Ostanina, F. N. Karachevtsev

Published in: Glass and Ceramics | Issue 7-8/2023

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Abstract

Bismuthate-borate glasswas synthesized with the compositions (wt.%) 70 Bi₂O₃, 2 GeO₂, 25 B₂O₃, 3 MoO₃; 70 Bi₂O₃, 17 GeO₂, 10 B₂O₃, 3 MoO₃ and 80 Bi₂O₃, 4 GeO₂, 5 MoO₃, 11 SiO₂; 80 Bi₂O₃, 8 GeO₂, 8.5 SiO₂, 3.5 MoO₃. Methods were developed for forming a receptor layer on the resulting glass by means of ultrasonic spraying of the interacting components and applying a water-insoluble polymer film obtained via a chemical reaction between the polymer poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride and the modifier potassium hexacyanoferrate (II). The sensors prepared based on these glasses make it possible to determine to within2– 4% the content of hydrogen sulfide and water vapor in air.

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Title: Bismuthate Glass as Backing for Gas Sensors
Authors: V. A. Kjutvitsky
I. A. Romanova
E. V. Mironova
V. V. Borisova
O. I. Ostanina
F. N. Karachevtsev
Publication date: 06-11-2023
Publisher: Springer US
Published in: Glass and Ceramics / Issue 7-8/2023
Print ISSN: 0361-7610
Electronic ISSN: 1573-8515
DOI: https://doi.org/10.1007/s10717-023-00607-4

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