Introduction
Present mining situation
Geological setting of the dolerite dike swarm in Uruguay
Characterization of the dolerite deposits
Group | Sample | Quarry/Location | Grain size (mm) | Dike width (m) | |
---|---|---|---|---|---|
Zone 2 | Zone 3 | ||||
Group A (high TiO2) | U215 | La Sierra | 0.68 | 16 | |
U62 | Las Acacias | 0.40 | 1.00 | 19 | |
U12B | Talita Chica | 1.70 | 20 | ||
U12A | Talita Grande | 1.70 | 25 | ||
U55 | Mexico | 0.60 | 1.30 | 30 | |
U56 | Los Fresnos | 1.70 | 30 | ||
U64 | Pintado | 0.44 | 1.70 | 35 | |
U11 | Blackstone | 0.80 | 1.50 | 38 | |
U59 | Omar Mendez | 0.65 | 2.00 | 40 | |
U8 | Rosarito | 0.45 | 1.80 | 41 | |
Group B (low TiO2) | U199 | Arroyo Polonia | 0.60 | 20 | |
U66 | Pimafox | 0.76 | 1.65 | 24 | |
U61 | Inex S.A. | 0.20 | 25 | ||
U13 | Victor | 0.40 | 1.50 | 30 | |
U58 | Boria | 0.50 | 30 | ||
U243 | Arroyo de la Quinta | 1.75 | 30 |
Geochemistry
Sample | SiO2
| TiO2
| Al2O3
| FeOt
| MnO | MgO | CaO | Na2O | K2O | P2O5
| Fe2O3
| FeO | H2O | CO2
| mg# |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Group A | |||||||||||||||
U8Z2 | 54.2 | 2.409 | 12.3 | 13.56 | 0.162 | 2.73 | 6.79 | 2.60 | 1.86 | 0.276 | 1.71 | 12.02 | 1.12 | 0.25 | 0.17 |
U8Z3 | 53.2 | 2.261 | 12.0 | 14.37 | 0.185 | 3.18 | 7.25 | 2.49 | 1.59 | 0.238 | 1.81 | 12.73 | 0.92 | 0.19 | 0.18 |
U11AZ2 | 55.4 | 1.733 | 12.9 | 12.54 | 0.173 | 3.04 | 6.97 | 2.58 | 1.75 | 0.224 | 1.58 | 11.11 | 0.63 | 0.13 | 0.20 |
U110Z3 | 53.2 | 2.332 | 12.2 | 14.50 | 0.184 | 3.07 | 7.25 | 2.56 | 1.64 | 0.247 | 1.82 | 12.85 | 0.59 | 0.09 | 0.17 |
U11Z2 | 54.1 | 2.269 | 12.2 | 13.53 | 0.171 | 2.94 | 6.99 | 2.58 | 1.74 | 0.255 | 1.70 | 11.99 | 1.10 | 0.19 | 0.18 |
U11Z3 | 53.2 | 2.243 | 12.0 | 14.35 | 0.184 | 3.22 | 7.26 | 2.50 | 1.61 | 0.238 | 1.80 | 12.71 | 0.89 | 0.19 | 0.18 |
U12AZ3 | 51.1 | 2.278 | 12.2 | 14.90 | 0.197 | 3.77 | 7.83 | 2.49 | 1.45 | 0.291 | 1.87 | 13.20 | 0.95 | 0.26 | 0.20 |
U12BZ3 | 51.2 | 2.297 | 12.3 | 14.96 | 0.196 | 3.77 | 7.81 | 2.50 | 1.46 | 0.288 | 1.88 | 13.25 | 0.86 | 0.22 | 0.20 |
U55Z2 | 50.2 | 2.419 | 12.9 | 14.10 | 0.205 | 4.26 | 8.22 | 2.56 | 1.51 | 0.369 | 1.77 | 12.50 | 0.95 | 0.24 | 0.23 |
U55Z3 | 53.6 | 2.192 | 11.7 | 14.20 | 0.184 | 3.11 | 7.11 | 2.49 | 1.62 | 0.262 | 1.79 | 12.58 | 1.08 | 0.32 | 0.18 |
U56Z3 | 53.1 | 2.251 | 11.9 | 14.48 | 0.186 | 3.19 | 7.22 | 2.53 | 1.63 | 0.240 | 1.82 | 12.83 | 0.88 | 0.20 | 0.18 |
U59Z3 | 49.4 | 2.380 | 13.0 | 14.32 | 0.212 | 4.81 | 8.63 | 2.46 | 1.37 | 0.343 | 1.80 | 12.69 | 0.80 | 0.25 | 0.25 |
U62Z2 | 55.1 | 1.750 | 12.7 | 12.77 | 0.173 | 2.99 | 6.92 | 2.55 | 1.76 | 0.224 | 1.61 | 11.31 | 0.78 | 0.13 | 0.19 |
U62Z3 | 55.2 | 1.782 | 12.7 | 12.83 | 0.175 | 2.98 | 6.93 | 2.57 | 1.78 | 0.223 | 1.61 | 11.36 | 0.74 | 0.21 | 0.19 |
U64Z2 | 53.4 | 2.300 | 12.1 | 14.27 | 0.184 | 2.99 | 7.06 | 2.57 | 1.69 | 0.322 | 1.80 | 12.65 | 0.81 | 0.19 | 0.17 |
U64M2 | 52.4 | 2.190 | 12.3 | 14.37 | 0.193 | 3.51 | 7.64 | 2.50 | 1.48 | 0.254 | 1.81 | 12.73 | 0.76 | 0.24 | 0.20 |
U215Z2 | 55.4 | 1.761 | 12.8 | 12.40 | 0.162 | 2.95 | 6.69 | 2.57 | 1.82 | 0.226 | 1.56 | 10.99 | 1.13 | 0.13 | 0.19 |
U215Z3 | 55.6 | 1.786 | 12.9 | 12.36 | 0.163 | 2.92 | 6.70 | 2.57 | 1.84 | 0.226 | 1.55 | 10.95 | 1.12 | 0.14 | 0.19 |
Group B | |||||||||||||||
U13Z2 | 52.2 | 0.844 | 15.5 | 8.81 | 0.151 | 5.94 | 8.68 | 2.18 | 1.83 | 0.115 | 0.97 | 7.93 | 2.18 | 0.17 | 0.40 |
U13Z3 | 53.2 | 0.812 | 14.9 | 9.24 | 0.149 | 6.68 | 9.62 | 1.94 | 0.98 | 0.109 | 1.02 | 8.32 | 0.79 | 0.34 | 0.42 |
U58Z2 | 53.7 | 0.912 | 14.4 | 10.07 | 0.157 | 5.60 | 9.34 | 2.08 | 1.14 | 0.121 | 1.11 | 9.07 | 0.86 | 0.20 | 0.36 |
U58Z3 | 53.8 | 0.873 | 14.2 | 10.00 | 0.158 | 5.67 | 9.32 | 2.04 | 1.08 | 0.116 | 1.10 | 9.00 | 1.16 | 0.33 | 0.36 |
U61Z2 | 53.9 | 0.929 | 14.5 | 9.94 | 0.150 | 5.44 | 9.34 | 2.09 | 1.17 | 0.123 | 1.09 | 8.94 | 0.89 | 0.17 | 0.35 |
U66Z2 | 53.9 | 0.789 | 14.7 | 9.07 | 0.146 | 6.48 | 9.56 | 1.94 | 0.96 | 0.106 | 1.00 | 8.17 | 0.99 | 0.17 | 0.42 |
U66Z3 | 53.2 | 0.737 | 15.0 | 8.82 | 0.145 | 7.13 | 9.74 | 1.87 | 0.91 | 0.099 | 0.97 | 7.94 | 0.82 | 0.29 | 0.45 |
U199Z2 | 53.4 | 0.826 | 15.1 | 9.16 | 0.150 | 6.47 | 9.34 | 1.94 | 1.04 | 0.113 | 1.01 | 8.25 | 1.04 | 0.17 | 0.41 |
U243Z3 | 53.5 | 0.808 | 15.2 | 9.05 | 0.141 | 6.42 | 9.42 | 1.94 | 1.04 | 0.112 | 0.99 | 8.14 | 1.13 | 0.09 | 0.42 |
Sample | Cr | Ni | Rb | Nb | Zr | Y | Sr | Ba | Zn | Ga | V |
---|---|---|---|---|---|---|---|---|---|---|---|
Group A | |||||||||||
U8Z2 | 136 | 107 | 24 | 8 | 115 | 20 | 194 | 386 | 76 | 16 | 211 |
U8Z3 | 22 | 29 | 39 | 10 | 203 | 37 | 198 | 478 | 128 | 22 | 328 |
U11AZ2 | 54 | 31 | 52 | 11 | 212 | 37 | 207 | 485 | 115 | 20 | 381 |
U110Z3 | 25 | 25 | 47 | 10 | 195 | 34 | 211 | 453 | 132 | 21 | 404 |
U11Z2 | 41 | 44 | 35 | 10 | 180 | 34 | 195 | 403 | 124 | 20 | 437 |
U11Z3 | 54 | 33 | 50 | 10 | 215 | 36 | 214 | 482 | 118 | 21 | 373 |
U12AZ3 | 135 | 103 | 15 | 6 | 112 | 20 | 189 | 270 | 74 | 20 | 206 |
U12BZ3 | 175 | 115 | 16 | 6 | 106 | 16 | 187 | 275 | 72 | 16 | 201 |
U55Z2 | 140 | 109 | 30 | 7 | 115 | 22 | 195 | 355 | 80 | 19 | 208 |
U55Z3 | 77 | 106 | 21 | 4 | 126 | 22 | 212 | 661 | 84 | 18 | 222 |
U56Z3 | 49 | 30 | 44 | 13 | 204 | 36 | 214 | 483 | 118 | 19 | 368 |
U59Z3 | 54 | 32 | 49 | 12 | 224 | 37 | 235 | 817 | 98 | 21 | 398 |
U62Z2 | 28 | 33 | 45 | 10 | 192 | 32 | 199 | 463 | 125 | 20 | 404 |
U62Z3 | 82 | 107 | 25 | 6 | 125 | 24 | 196 | 307 | 85 | 18 | 220 |
U64Z2 | 51 | 30 | 47 | 12 | 209 | 39 | 283 | 1,732 | 102 | 21 | 385 |
U64M2 | 100 | 63 | 33 | 11 | 244 | 44 | 146 | 339 | 147 | 21 | 377 |
U215Z2 | 28 | 31 | 33 | 6 | 194 | 33 | 201 | 447 | 127 | 20 | 440 |
U215Z3 | 81 | 111 | 33 | 7 | 116 | 21 | 193 | 283 | 84 | 19 | 227 |
Group B | |||||||||||
U13Z2 | 32 | 47 | 30 | 10 | 194 | 40 | 176 | 409 | 130 | 21 | 440 |
U13Z3 | 25 | 31 | 41 | 10 | 193 | 36 | 200 | 451 | 125 | 22 | 411 |
U58Z2 | 147 | 110 | 18 | 8 | 111 | 17 | 191 | 282 | 77 | 16 | 203 |
U58Z3 | 139 | 109 | 66 | 6 | 119 | 18 | 235 | 528 | 52 | 18 | 213 |
U61Z2 | 81 | 54 | 37 | 13 | 267 | 46 | 155 | 373 | 136 | 20 | 348 |
U66Z2 | 26 | 27 | 45 | 9 | 187 | 35 | 205 | 451 | 127 | 21 | 414 |
U66Z3 | 22 | 20 | 52 | 12 | 211 | 39 | 214 | 516 | 121 | 22 | 323 |
U199Z2 | 30 | 49 | 33 | 8 | 192 | 35 | 174 | 393 | 129 | 20 | 429 |
U243Z3 | 25 | 25 | 43 | 11 | 206 | 34 | 253 | 1,117 | 118 | 19 | 392 |
Petrography
Geochemical classification | Group A, high TiO2 content (between 1.5 and 2.5%) Andesi-basalt | Group B, low TiO2 content (less than 1.2%) Basalt |
---|---|---|
Plagioclase | Between An34 and An44. Up to 40%, no significant differences between both zones | Between An47 and An60. Up to 48% in Zone 2 and 44% in Zone 3 |
Clinopyroxene | Mostly augite, some pigeonite can be present, up to 25%, no significant differences between both zones | Mostly augite, some pigeonite can occur, up to 40%, no significant differences between both zones |
Granophyric intergrowth | Around 10% in Zone 2 and 20% in Zone 3 | Around 2% in Zone 2 and 10% in Zone 3 |
Amphibole | Hornblende as uralitization product of clinopyroxene, up to 13% in Zone 2 and 7% in Zone 3 | Hornblende as uralitization product of clinopyroxene, up to 4% in Zone 2 and 6% in Zone 3 |
Opaques | Magnetite in euhedral to subhedral crystals, ilmenite in skeletal crystals, up to 8%, no significant differences between both zones | Ilmenite in elongated crystals, up to 2% |
Apatite | Always present in granophyric intergrowth and as inclusions in PI | Always present in granophyric intergrowth and as inclusions in PI |
Biotite | As accessory associated with clinopyroxenes and opaques | As accessory associated with clinopyroxenes and opaques |
Texture | Subophitic, occasionally porphyritic in Zone 1 and 2, phenocrystals of PI and Aug | Subophitic, frequently porphyritic in Zone 1 and 2, phenocrystals of PI and Aug |
Grain size (Pg) | Between 0.5 and 1 mm in Zone 2, and between 1 and 2 mm in Zone 3 | Between 0.5 and 1 mm in Zone 2, and between 1.5 and 2 mm in Zone 4 |
Group | Sample | Q | Ort | Ab | An | Hy | Di | Mag | Ilm | Ap | Cc | Percentage of An in PI |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Group A (high TiO2) | U8M1 | 10.4 | 11.3 | 22.6 | 16.8 | 18.2 | 12.2 | 2.5 | 4.7 | 0.7 | 0.6 | 42.7 |
U8P7 | 8.9 | 9.7 | 21.7 | 17.3 | 19.9 | 14.3 | 2.7 | 4.4 | 0.6 | 0.5 | 44.4 | |
U11A | 10.9 | 10.6 | 22.3 | 19.0 | 18.6 | 11.9 | 2.3 | 3.4 | 0.5 | 0.3 | 45.9 | |
U110 | 8.3 | 9.9 | 22.2 | 17.3 | 19.4 | 14.8 | 2.7 | 4.5 | 0.6 | 0.2 | 43.7 | |
U11M1 | 10.0 | 10.6 | 22.5 | 17.2 | 18.5 | 13.3 | 2.5 | 4.4 | 0.6 | 0.4 | 43.3 | |
U11M12 | 8.8 | 9.8 | 21.8 | 17.2 | 19.9 | 14.5 | 2.7 | 4.4 | 0.6 | 0.4 | 44.2 | |
U12A | 5.4 | 8.8 | 21.7 | 18.4 | 21.8 | 15.3 | 2.8 | 4.5 | 0.7 | 0.6 | 45.8 | |
U12B | 5.2 | 8.9 | 21.8 | 18.5 | 21.9 | 15.2 | 2.8 | 4.5 | 0.7 | 0.5 | 46.0 | |
U55M1 | 3.0 | 9.2 | 22.3 | 19.9 | 21.6 | 15.2 | 2.7 | 4.7 | 0.9 | 0.6 | 47.2 | |
U55M4 | 10.0 | 9.9 | 21.7 | 16.5 | 19.9 | 13.7 | 2.7 | 4.3 | 0.6 | 0.7 | 43.2 | |
U56 | 8.5 | 9.9 | 22.0 | 16.7 | 19.9 | 14.7 | 2.7 | 4.4 | 0.6 | 0.5 | 43.1 | |
U59 | 1.6 | 8.3 | 21.4 | 20.8 | 23.0 | 16.1 | 2.7 | 4.6 | 0.8 | 0.6 | 49.3 | |
U62M3 | 10.8 | 10.7 | 22.2 | 18.6 | 18.8 | 12.2 | 2.4 | 3.4 | 0.5 | 0.3 | 45.6 | |
U62M6 | 10.8 | 10.8 | 22.3 | 18.4 | 18.9 | 11.9 | 2.4 | 3.5 | 0.5 | 0.5 | 45.2 | |
U64M1 | 9.1 | 10.3 | 22.4 | 16.9 | 19.6 | 13.4 | 2.7 | 4.5 | 0.8 | 0.5 | 43.0 | |
U64M2 | 7.3 | 9.0 | 21.8 | 18.4 | 20.7 | 14.7 | 2.7 | 4.3 | 0.6 | 0.6 | 45.8 | |
U215M1 | 11.4 | 11.1 | 22.4 | 18.6 | 18.6 | 11.2 | 2.3 | 3.4 | 0.6 | 0.3 | 45.4 | |
U215M3 | 11.6 | 11.2 | 22.3 | 18.7 | 18.4 | 11.1 | 2.3 | 3.5 | 0.5 | 0.3 | 45.6 | |
Average | 8.4 | 10.0 | 22.1 | 18.1 | 19.9 | 13.6 | 2.6 | 4.2 | 0.6 | 0.5 | 45.0 | |
Group B (low TiO2) | U13M1 | 3.3 | 11.2 | 19.1 | 28.2 | 22.5 | 12.0 | 1.5 | 1.7 | 0.3 | 0.4 | 59.6 |
U13M10 | 6.3 | 5.9 | 16.7 | 29.6 | 24.1 | 13.3 | 1.5 | 1.6 | 0.3 | 0.8 | 63.9 | |
U58M1 | 7.1 | 6.9 | 18.0 | 27.3 | 21.7 | 14.9 | 1.6 | 1.8 | 0.3 | 0.5 | 60.3 | |
U58M3 | 7.9 | 6.5 | 17.7 | 26.9 | 22.1 | 14.5 | 1.6 | 1.7 | 0.3 | 0.8 | 60.4 | |
U61 | 7.4 | 7.1 | 18.1 | 27.3 | 21.0 | 15.0 | 1.6 | 1.8 | 0.3 | 0.4 | 60.2 | |
U66P1 | 7.4 | 5.8 | 16.8 | 29.1 | 22.8 | 14.4 | 1.5 | 1.5 | 0.3 | 0.4 | 63.4 | |
U66P12 | 6.1 | 5.5 | 16.1 | 30.4 | 24.6 | 13.4 | 1.4 | 1.4 | 0.2 | 0.7 | 65.3 | |
U199 | 6.7 | 6.3 | 16.8 | 30.0 | 23.7 | 12.7 | 1.5 | 1.6 | 0.3 | 0.4 | 64.2 | |
U243 | 6.6 | 6.3 | 16.8 | 30.4 | 23.2 | 13.2 | 1.5 | 1.6 | 0.3 | 0.2 | 64.4 | |
Average | 6.5 | 6.8 | 17.3 | 28.8 | 22.9 | 13.7 | 1.5 | 1.6 | 0.3 | 0.5 | 62.4 |
Determination of commercial varieties: influence of grain size, fabric, chemical and mineral composition
Color measurements
Occurrences and deposits
Regional distribution: length, width, frequency, country rock relations
Characterization of dolerite deposits: controlling parameters
Quality assessment of dolerites deposits
Characterization of the waste material
Petrophysical properties
Group | Sample | Quarry/Location | Dike width (m) | Present condition | Quarry depth (m) | Quarry/Outcrop length (m) | Dike length (m) | Strike |
---|---|---|---|---|---|---|---|---|
Group A (high TiO2) | U8 | Rosarito | 41 | In activity | At least 8 | 100 | 3,500 | N060° |
U11 | Blackstone | 38 | In activity | 8 | 140 | 500 | N080° | |
U12A | Talita grande | 25 | Flooded | At least 4 | 135 | 2,000 | N075° | |
U12B | Talita chica | 20 | Flooded | At least 3 | 150 | 2,000 | N080° | |
U55 | Mexico | 30 | Flooded | At least 6 | 135 | 1,500 | N053° | |
U56 | Los Fresnos | 30 | Abandoned | Superficial | 170 | 3,400 | N060° | |
U59 | Omar Mendez | 40 | Flooded | At least 4 | 110 | 1,250 | N070° | |
U62 | Las Acacias | 19 | Flooded | 5 | 130 | 2,600 | N072° | |
U64 | Pintado | 35 | Abandoned | Superficial | 430 | 430 | N075° | |
U215 | La Sierra | 16 | No quarry | – | 220 | 500 | N056° | |
Group B (low TiO2) | U13 | Victor | 30 | Abandoned | 8.5 | 110 | 1,900 | N076° |
U58 | Boria | 30 | Flooded | At least 5 | 120 | 1,700 | N076° | |
U61 | Inex | 25 | Flooded | 11 | 225 | 2,400 | N065° | |
U66 | Pimafox | 24 | In activity | 4 | 60 | 2,000 | N072° | |
U199 | Arroyo Polonia | 20 | No quarry | – | 55 | 560 | N065° | |
U243 | Arroyo de la Quinta | 30 | No quarry | – | 120 | 800 | N050° |
Commercial name | Negro Absoluto (Zone 2) | Negro Oriental (Zone 3) | ||||
---|---|---|---|---|---|---|
Rock type | Dolerite | Dolerite | ||||
Direction |
X
|
Y
|
Z
|
X
|
Y
|
Z
|
UCS (MPa) | 399.6 ± 33.6 | 371.4 ± 37.0 | 367.00 ± 16.2 | 266.2 ± 26.8 | 285.8 ± 29.2 | 274.7 ± 24.6 |
Young modulus (GPa) | 32.90 ± 7.38 | 29.60 ± 9.90 | 30.59 ± 11.93 | 27.33 ± 15.77 | 23.47 ± 8.84 | 17.40 ± 4.54 |
Tensile strength (MPa) | 16.7 ± 4.5 | 19.5 ± 4.3 | 17.4 ± 5.8 | 16.7 ± 3.0 | 15.9 ± 3.0 | 14.3 ± 3.4 |
Flexural strength (MPa) | 51.8 ± 2.2 | 52.8 ± 2.1 | 46.1 ± 1.5 | 35.7 ± 2.5 | 30.8 ± 1.3 | 32.9 ± 1.3 |
Abrasion strength (cm3/50 cm2) | 2.2 | 2.4 | 2.2 | 2.3 | 2.5 | 2.4 |
Breaking load at dowel hole (MPa) | 4.7 ± 0.8 | 4.2 ± 0.7 | ||||
Real density (g/cm3) | 2.99 | 3.02 | ||||
Apparent density (g/cm3) | 2.99 | 3.02 | ||||
Porosity (%) (vacuum) | 0.03 | 0.06 | ||||
Average pore radii (μm) | 0.10 | 0.06 | ||||
Most abundant pore radii class (μm) | 0.01 | 0.02 | ||||
Water uptake (%) (atmospheric) | 0.01 | 0.02 | ||||
Water uptake (%) (vacuum) | 0.01 | 0.02 | ||||
Vapor diffusion resistance factor | 6,489 | 5,010 | ||||
Thermal expansion (×10−6 K−1) | 6.63 | 6.60 | 6.53 | 6.54 | 6.56 | 6.90 |
Density, porosity and thermal expansion
Sample | Origin | Lithology | Density (kg/dm3) | UCS (N/mm2) | Flexural strength (N/mm2) | Water uptake (vol.%) | Reference object |
---|---|---|---|---|---|---|---|
Shanxi Black (G1401) | China | Dolerite | 3.0 | 350 | 0.33 | Interior stone paving of Düsseldorf Airport | |
Ebony Black | Sweden | Dolerite | 3.1–3.3 | 294 | 25 | 0.10 | Facade of Empire State Building in New York |
Impala | South Africa | Gabbro/Norit | 2.8–3.0 | 221–260 | 22–26 | 0.08–0.32 | Haus Sommer, Pariser Platz 1 in Berlin |
Impala Dark | South Africa | Gabbro/Norit | 3.0 | 290–300 | 0.10 | Bundespräsidalamt in Berlin | |
Nero Assoluto | Zimbabwe | Fine-grained Gabbro/Norit | 3.0–3.1 | 240–252 | 24–29 | 0.12–0.16 | Wallraf-Richartz- Museum in Koln; Gramercy Plaza/Torrance in California |
Preto Absoluto | Brazil | Fine to middle-grained basalt (Diabas) with a touch of green | 3.1 | 210 | 34 | 0.05 | |
Star Galaxy | India | Fine to middle-grained Gabbro/Norit with bronzite scales | 2.8–2.9 | 183–203 | 19–20 | 0.08–0.12 | |
Absolute Black | Uruguay | Dolerite | 3.0 | 367–400 | 46–53 | 0.01 | Antel Tower in Montevideo |
Moderate Black | Uruguay | Dolerite | 3.0 | 266–286 | 31–36 | 0.02 |