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Colloid and Polymer Science
Published in: Colloid and Polymer Science 4/2013

01-04-2013 | Original Contribution

Blend or copolymer? Spectroelectrochemical evidence of copolymerization and blending of two electrochromic monomers

Authors: Metin Ak, Halil Cetişli, Levent Toppare

Published in: Colloid and Polymer Science | Issue 4/2013

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Abstract

A dipyrromethane functionalized monomer, 5-(4-tert-butylphenyl)dipyrromethane (DP), was synthesized to examine the spectral differences of its copolymer and blend with 3,4-ethylenedioxythiophene. Electrochemical polymerization, copolymerization, and blending of DP were achieved in LiClO4/Acetonitrile. Spectral and electrochromic properties of products were investigated. Spectral properties of copolymer and blend revealed great differences from each other and also from their corresponding homopolymers. Effect of monomer feed ratio on the spectral properties of copolymer was also investigated.
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Metadata
Title
Blend or copolymer? Spectroelectrochemical evidence of copolymerization and blending of two electrochromic monomers
Authors
Metin Ak
Halil Cetişli
Levent Toppare
Publication date
01-04-2013
Publisher
Springer-Verlag
Published in
Colloid and Polymer Science / Issue 4/2013
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-012-2787-7

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