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Metallurgical and Materials Transactions A
Published in: Metallurgical and Materials Transactions A 10/2016

20-07-2016

Calorimetric Measurements of Liquid Al-Zn Alloys

Authors: Adam Dębski, Władysław Gąsior, Katarzyna Szmit

Published in: Metallurgical and Materials Transactions A | Issue 10/2016

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ABSTRACT

The integral molar enthalpies of mixing were determined by the drop calorimetric method for binary AL-Zn liquid solutions and compared with the Miedema model as well as the earlier experimental data. The measurements were conducted at two temperatures: 957 K and 1001 K (684 °C and 728 °C), in the entire concentration range. Based on the experimental calorimetric data of this study as well as those available in the literature and the results of the activity studies, the interaction parameters of the Redlich-Kister equation for the liquid Al-Zn phase were worked out with the use of the least square method. The partial and integral Gibbs energies, entropies and enthalpies were calculated and presented in tables and figures. Additionally, the concentration-concentration partial structure factors for the ideal and real Al-Zn solutions were calculated and graphically presented.
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Metadata
Title
Calorimetric Measurements of Liquid Al-Zn Alloys
Authors
Adam Dębski
Władysław Gąsior
Katarzyna Szmit
Publication date
20-07-2016
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 10/2016
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-016-3643-z

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