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Journal of Nanoparticle Research

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01-11-2014 | Research Paper

Catechol versus bisphosphonate ligand exchange at the surface of iron oxide nanoparticles: towards multi-functionalization

Authors: Erwann Guénin, Yoann Lalatonne, Julie Bolley, Irena Milosevic, Carlos Platas-Iglesias, Laurence Motte

Published in: Journal of Nanoparticle Research | Issue 11/2014

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Abstract

We report an investigation of the ligand exchange at the surface of iron oxide nanoparticles in water. For this purpose we compared two strong chelating agents on the iron oxide surface containing catechol and bisphosphonate moieties. Interactions between the coating agents (catechol/bisphosphonate) and the nanoparticle’s surface were studied by FTIR and DFT calculations. Ligand exchange experiments were performed using sonication and the exchange yield was characterized by FTIR and EDX. This methodology allowed introducing bisphosphonates with various functionalities (alkyne or biotin) permitting multi-functionalization.

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Title: Catechol versus bisphosphonate ligand exchange at the surface of iron oxide nanoparticles: towards multi-functionalization
Authors: Erwann Guénin
Yoann Lalatonne
Julie Bolley
Irena Milosevic
Carlos Platas-Iglesias
Laurence Motte
Publication date: 01-11-2014
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 11/2014
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-014-2596-7

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