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Journal of Coatings Technology and Research

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22-06-2023

Characteristics, antibacterial activity, and antibiofilm performance of a polysiloxane coating filled with organically modified Cu₂O

Authors: Phi Hung Dao, Anh Hiep Nguyen, Thanh Thuy Tran, Thuy Chinh Nguyen, Thi Thu Trang Nguyen, Xuan Thai Nguyen, Thi Mai Tran, An Quan Vo, Huu Nghi Do, Minh Quan Pham, Ngoc Nhiem Dao, Ngoc Tan Nguyen, Hoang Nghia Trinh, Hoang Thai

Published in: Journal of Coatings Technology and Research | Issue 6/2023

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Abstract

The effects of Cu₂O nanoparticles (Cu₂O NPs) modified with 3-(trimethoxysilyl)propyl methacrylate (TMSPM) (m-Cu₂O NPs) on the properties of a polysiloxane (PS) coating were investigated. The organic surface modifications improved the antimicrobial activity of the Cu₂O NPs and their dispersion in a PS matrix. Due to the broad dispersion of the m-Cu₂O NPs, the PS/m-Cu₂O coating exhibited better mechanical properties and better thermal stability than unmodified Cu₂O (u-Cu₂O) coatings. The onset temperature of PS/m-Cu₂O was 24 °C higher than that of the neat PS coating and 11 °C higher than that of the PS/u-Cu₂O coating. The PS/m-Cu₂O coating exhibited high antibacterial activity for sulfate-reducing bacterial strains, but the PS/m-Cu₂O coating showed slight bacterial inhibition of Pseudomonas stutzeri B27 bacteria (which were isolated under seawater at Phu Quoc Island, Kien Giang Province, Vietnam). Biofilm inhibition by the PS coatings with and without the m-Cu₂O NPs was also tested with a natural seawater immersion test. After a 60-day test, the biofilm formed on the PS coating surface was ten times thicker than that on the PS/m-Cu₂O coating. Fourier transform infrared spectroscopy (FTIR) data and the surface properties of the coating indicated that immersion in natural seawater insignificantly affected the functional groups of the coating but had a substantial influence on the smoothness of the coating, which made the surface of the coating more hydrophilic. These results suggested that the PS/m-Cu₂O could be used as an antifouling coating for the marine industry.

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Title: Characteristics, antibacterial activity, and antibiofilm performance of a polysiloxane coating filled with organically modified Cu2O
Authors: Phi Hung Dao
Anh Hiep Nguyen
Thanh Thuy Tran
Thuy Chinh Nguyen
Thi Thu Trang Nguyen
Xuan Thai Nguyen
Thi Mai Tran
An Quan Vo
Huu Nghi Do
Minh Quan Pham
Ngoc Nhiem Dao
Ngoc Tan Nguyen
Hoang Nghia Trinh
Hoang Thai
Publication date: 22-06-2023
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 6/2023
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-023-00789-0

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