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2016 | OriginalPaper | Chapter

10. Chemical Kinetics and Fire

Authors : Gregory T. Linteris, John F. Griffiths

Published in: SFPE Handbook of Fire Protection Engineering

Publisher: Springer New York

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Abstract

The purpose of this chapter is to set out the principles of chemical kinetics as they apply to combustion in flames and fires. Chemical equilibrium, which was discussed in a previous chapter, deals with the final preferred state of a given set of reactants after an infinite time has passed. In contrast, chemical kinetics deals with the rate at which the system proceeds to the equilibrium state, i.e., the specific participating chemical reactions and their rates. Chemical equilibrium and chemical kinetics are related in that the thermodynamic, equilibrium state provides the driving force for chemical reaction. The material in this chapter is covered briefly; more detailed descriptions can be found in chemistry [1] and combustion [2–4] text books, upon which much of the material is based.

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Literature
1.
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2.
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3.
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4.
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5.
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11.
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go back to reference NFPA 2001 Standard on Clean Agent Fire Extinguishing Systems 2008 Edition, NFPA, 2007. NFPA 2001 Standard on Clean Agent Fire Extinguishing Systems 2008 Edition, NFPA, 2007.
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go back to reference F. Takahashi, G.T. Linteris, V.R. Katta, O. Meier, Proc. Combust. Inst. 34 (2012) 2707–2717. F. Takahashi, G.T. Linteris, V.R. Katta, O. Meier, Proc. Combust. Inst. 34 (2012) 2707–2717.
Metadata
Title
Chemical Kinetics and Fire
Authors
Gregory T. Linteris
John F. Griffiths
Copyright Year
2016
Publisher
Springer New York
DOI
https://doi.org/10.1007/978-1-4939-2565-0_10