Top

Polymer Bulletin

Published in:

12-09-2023 | ORIGINAL PAPER

Chemically functionalized poly(AAm-AMPSA) superadsorbent hydrogels for removal of uranyl from aqueous solutions

Authors: Yasemin Işıkver, Nihat Alkan

Published in: Polymer Bulletin | Issue 1/2024

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

In the present study, anionic hydrogels, acrylamide (AAm) monomer, and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPSA) comonomer were prepared in the presence of two different cross-linkers. Then, super-anionic hydrogels were prepared by converting the amide groups of neutral AAm in anionic hydrogels to hydroxamic acid with hydroxylamine hydrochloride. The hydrogels were characterized by FTIR, SEM, TG, and DSC analyses. Uranyl adsorption in the hydrogels was investigated by spectroscopic, kinetic, and equilibrium studies. It was determined that uranyl adsorption kinetics in hydrogels were compatible with pseudo-second-order and intra-particular diffusion models. It was determined that the uranyl adsorption isotherms on the hydrogels were L-type according to the Giles isotherm classification. Adsorption parameters were calculated by applying Freundlich and Langmuir models to these isotherms. In addition, it was determined that the amount of adsorbed uranyl increased with the increase in adsorbent mass, did not change with temperature, decreased in the range of pH 2–4, and increased at pH 4–7. It was observed that super-anionic hydrogels had the highest adsorption capacity among these new hydrogels. In addition, molecular electrostatic potential (MEP) mapping was performed to predict the reactive regions of the hydrogels. The results showed that the theoretical and experimental data of hydrogels are in agreement with each other. In conclusion, it can be said that the anionic and super-anionic hydrogels prepared in this study are unique hydrogels with fast and effective properties in removing uranyl.

previous article Determination of the crosslink density of silica-filled styrene butadiene rubber compounds by different analytical methods

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Ozay O, Ekici S, Baran Y, Aktas N, Sahiner N (2009) Removal of toxic metal ions with magnetic hydrogels. Water Res 43(17):4403–4411. https://doi.org/10.1016/j.watres.2009.06.058CrossRefPubMed

Li J, Wang X, Zhao G, Chen C, Chai Z, Alsaedi A, Hayat T, Wang X (2018) Metal–organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions. Chem Soc Rev 47(7):2322–2356. https://doi.org/10.1039/c7cs00543aCrossRefPubMed

Sahiner N, Ozay H, Ozay O, Aktas N (2010) A soft hydrogel reactor for cobalt nanoparticle preparation and use in the reduction of nitrophenols. Appl Catal B 101(1–2):137–143. https://doi.org/10.1016/j.apcatb.2010.09.022CrossRef

Atta AM, Wahab ZHAE, Shafey ZAE, Zidan WI, Akl ZF (2010) Uranyl ions uptake from aqueous solutions using crosslinked ionic copolymers based on 2-acrylamido-2-methylpropane sulfonic acid copolymers. J Dispersion Sci Technol 31(12):1601–1610. https://doi.org/10.1080/01932690903296977CrossRef

Saraydin D, Karadağ E, Güven O (1995) Adsorptions of some heavy metal ions in aqueous solutions by acrylamide/maleic acid hydrogels. Sep Sci Technol 30(17):3287–3298. https://doi.org/10.1080/01496399508013145CrossRef

Sang K, Mei D, Wang Y, Liu L, Li H, Yang G, Ma F, Zhang C, Dong H (2022) Amidoxime-functionalized zeolitic imidazolate frameworks with antimicrobial property for the removal of U (VI) from wastewater. J Environ Chem Eng 10(5):10834. https://doi.org/10.1016/j.jece.2022.108344CrossRef

Saraydin D, Şolpan D, Işıkver Y, Ekici S, Güven O (2002) Radiation crosslinked poly(acrylamide/2-hydroxypropyl methacrylate/maleic acid) and their usability in the uptake of uranium. J Macromol Sci Part A 39(9):969–990. https://doi.org/10.1081/ma-120013574CrossRef

Karadağ E, Saraydin D, Güven O (1995) Behaviors of acrylamide/itaconic acid hydrogels in uptake of uranyl ions from aqueous solutions. Sep Sci Technol 30(20):3747–3760. https://doi.org/10.1080/01496399508015140CrossRef

Saraydin D, Isikver Y, Sahiner N (2001) Uranyl ion binding properties of poly(hydroxamic acid) hydrogels. Polym Bull 47(1):81–89. https://doi.org/10.1007/s002890170024CrossRef

10.

Işıkver Y (2017) Synthesis of anionic hydrogels for uranyl ion adsorption. CSJ 38(4):770–780. https://doi.org/10.17776/csj.345147CrossRef

11.

Kundakcı S, Üzüm ÖB, Karadağ E (2008) Behaviors of chemically crosslinked CAAMPS hydrogels in uptake of uranyl ions from aqueous solutions. Polym Plast Technol Eng 48(1):69–74. https://doi.org/10.1080/03602550802539775CrossRef

12.

Hazer O, Kartal Ş (2010) Use of amidoximated hydrogel for removal and recovery of U(VI) ion from water samples. Talanta 82(5):1974–1979. https://doi.org/10.1016/j.talanta.2010.08.023CrossRefPubMed

13.

Chi F, Hu S, Xiong J, Wang X (2013) Adsorption behavior of uranium on polyvinyl alcohol-g-amidoxime: Physicochemical properties, kinetic and thermodynamic aspects. Sci China Chem 56(11):1495–1503. https://doi.org/10.1007/s11426-013-5003-9CrossRef

14.

Karadağ E, Nalbantoğlu A, Kundakcı S, Üzüm ÖB (2016) Uranyl Ion sorption characteristics of novel polymer/montmorillonite/carboxymethyl cellulose-composite biosorbent-based AAm/AMPS hydrogels and semi-IPNs. Adv Polym Technol 37(2):575–585. https://doi.org/10.1002/adv.21698CrossRef

15.

Ye T, Huang B, Wang Y, Zhou L, Liu Z (2020) Rapid removal of uranium(VI) using functionalized luffa rattan biochar from aqueous solution. Colloids Surf, A 606:125480. https://doi.org/10.1016/j.colsurfa.2020.125480CrossRef

16.

Tan J, Xie S, Wang G, Yu CW, Zeng T, Cai P, Huang H (2020) Fabrication and optimization of the thermo-sensitive hydrogel carboxymethyl cellulose/poly(N-isopropylacrylamide-co-acrylic acid) for U(VI) removal from aqueous solution. Polymers 12(1):151. https://doi.org/10.3390/polym12010151CrossRefPubMedPubMedCentral

17.

Atta AM, Wahab ZHAE, El Shafey ZA, Zidan WI, Akl ZF (2010) Characterization and evaluation of acrylic acid Co-2-acrylamido-2-methylpropane-1-sulfonic Acid Hydrogels for Uranium Recovery. J Dispers Sci Technol 31(10):1415–1422. https://doi.org/10.1080/01932690903269560CrossRef

18.

Tatarchuk T, Shyichuk A, Mironyuk I, Naushad M (2019) A review on removal of uranium(VI) ions using titanium dioxide based sorbents. J Mol Liq 293:111563. https://doi.org/10.1016/j.molliq.2019.111563CrossRef

19.

Saraydın D, Işıkver Y, Karadağ E (2018) A study on the correlation between adsorption and swelling for poly(Hydroxamic Acid) hydrogels-triarylmethane dyes systems. J Polym Environ 26(9):3924–3936. https://doi.org/10.1007/s10924-018-1257-9CrossRef

20.

Kundakci S, Üzüm ÖB, Karadağ E (2008) Swelling and dye sorption studies of acrylamide/2-acrylamido-2-methyl-1-propanesulfonic acid/bentonite highly swollen composite hydrogels. React Funct Polym 68(2):458–473. https://doi.org/10.1016/j.reactfunctpolym.2007.11.008CrossRef

21.

Işikver Y (2017) Removal of some cationic dyes from aqueous solution by acrylamide- or 2-hydroxyethyl methacrylate-based copolymeric hydrogels. Fibers Polym 18(11):2070–2078. https://doi.org/10.1007/s12221-017-7215-7CrossRef

22.

Isikver Y, Saraydin D, Sahiner N (2001) Poly(hydroxamic acid) hydrogels from poly(acrylamide): preparation and characterization. Polym Bull 47(1):71–79. https://doi.org/10.1007/s002890170023CrossRef

23.

Saraydın D, Işıkver Y, Karadağ E (2022) An evaluation on S-type adsorption isotherm in the model of crosslinked polyhydroxamates/oxazine dyes/water interactions. Adsorption 28(5–6):249–260. https://doi.org/10.1007/s10450-022-00367-7CrossRef

24.

Saraydın D, Işıkver Y, Karadağ E (2017) Adsorption of phenazine dyes using poly(hydroxamic acid) hydrogels from aqueous solutions. Polym Eng Sci 58(3):310–318. https://doi.org/10.1002/pen.24574CrossRef

25.

Sahoo TR, Prelot B (2020) Adsorption processes for the removal of contaminants from wastewater. Nanomater Detect Removal Wastew Pollut. https://doi.org/10.1016/b978-0-12-818489-9.00007-4CrossRef

26.

Hazer O, Soykan C, Kartal Ş (2007) Synthesis and swelling behavior analysis of Poly(acrylamidoxime-co-2-acrylamido-2-methylpropane Sulfonic Acid) hydrogels. J Macromol Sci, Part A 45(1):45–51. https://doi.org/10.1080/10601320701683223CrossRef

27.

Nesic A, Panic V, Ostojic S, Micic D, Pajic-Lijakovic I, Onjia A, Velickovic S (2016) Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid. Mater Chem Phys 174:156–163. https://doi.org/10.1016/j.matchemphys.2016.02.063CrossRef

28.

Öztop HN, Akyildiz F, Saraydin D (2020) Poly(acrylamide/vinylsulfonic acid) hydrogel for invertase immobilization. Microsc Res Tech 83(12):1487–1498. https://doi.org/10.1002/jemt.23542CrossRefPubMed

29.

Haerifar M, Azizian S (2013) Mixed surface reaction and diffusion-controlled kinetic model for adsorption at the solid/solution interface. J Phys Chem C 117(16):8310–8317. https://doi.org/10.1021/jp401571mCrossRef

30.

Ho Y (2006) Review of second-order models for adsorption systems. J Hazard Mater 136(3):681–689. https://doi.org/10.1016/j.jhazmat.2005.12.043CrossRefPubMed

31.

Plazinski W, Rudzinski W, Plazinska A (2009) Theoretical models of sorption kinetics including a surface reaction mechanism: a review. Adv Colloid Interface Sci 152(1–2):2–13. https://doi.org/10.1016/j.cis.2009.07.009CrossRefPubMed

32.

Wu F-C, Tseng R-L, Juang R-S (2009) Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics. Chem Eng J 153(1–3):1–8. https://doi.org/10.1016/j.cej.2009.04.042CrossRef

33.

Crini G, Peindy H, Gimbert F, Robert C (2007) Removal of C.I. basic green 4 (Malachite Green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: kinetic and equilibrium studies. Sep Purif Technol 53(1):97–110. https://doi.org/10.1016/j.seppur.2006.06.018CrossRef

34.

Choudhary S, Sharma K, Kumar V, Bhatia JK, Sharma S, Sharma V (2019) Microwave-assisted synthesis of gum gellan-cl-poly(acrylic-co- methacrylic acid) hydrogel for cationic dyes removal. Polym Bull 77(9):4917–4935. https://doi.org/10.1007/s00289-019-02998-3CrossRef

35.

Giles CH, MacEwan TH, Nakhwa SN, Smith D (1960) 786. Studies in adsorption Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. J Chem Soc (Resumed). https://doi.org/10.1039/jr9600003973CrossRef

36.

Politzer P, Truhlar DG (Eds) (1981) Chemical applications of atomic and molecular electrostatic potentials: reactivity, structure, scattering and energies of organic, inorganic and biological systems, Plenum, New York

37.

Ehresmann B, Martin B, Horn AHC, Clark T (2003) Local molecular properties and their use in predicting reactivity. J Mol Model 9(5):342–347. https://doi.org/10.1007/s00894-003-0153-xCrossRefPubMed

38.

Akman F (2016) Spectroscopic investigation, HOMO–LUMO energies, natural bond orbital (NBO) analysis and thermodynamic properties of two-armed macroinitiator containing coumarin with DFT quantum chemical calculations. Can J Phys 94(6):583–593. https://doi.org/10.1139/cjp-2016-0041CrossRef

39.

Gaussian 16, Revision C.01, Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Petersson GA, Nakatsuji H, Li X, Caricato M, Marenich AV, Bloino J, Janesko BG, Gomperts R, Mennucci B, Hratchian HP, Ortiz JV, Izmaylov AF, Sonnenberg JL, Williams-Young D, Ding F, Lipparini F, Egidi F, Goings J, Peng B, Petrone A, Henderson T, Ranasinghe D, Zakrzewski VG, Gao J, Rega N, Zheng G, Liang W, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Vreven T, Throssell K, Montgomery JA, Jr, Peralta JE, Ogliaro F, Bearpark MJ, Heyd JJ, Brothers EN, Kudin KN, Staroverov VN, Keith TA, Kobayashi R, Normand J, Raghavachari K, Rendell AP, Burant JC, Iyengar SS, Tomasi J, Cossi M, Millam JM, Klene M, Adamo C, Cammi R, Ochterski JW, Martin RL, Morokuma K, Farkas O, Foresman JB, Fox DJ (2019) Gaussian, Inc., Wallingford CT

40.

Dennington R, Keith TA, Millam JM (2016) GaussView, Version 6, Semichem, Inc., Shawnee Mission, KS

41.

Frisch MJ, Trucks G, Schlegel H, Scuseria G, Robb M, Cheeseman J, Scalmani G, Barone V, Mennucci B, Petersson G (2009) Gaussian 09, Revision D. 01, Gaussian, Inc., Wallingford, CT

42.

Stephens PJ, Devlin FJ, Chabalowski CF, Frisch MJ (1994) Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields. J Phys Chem 98(45):11623–11627. https://doi.org/10.1021/j100096a001CrossRef

43.

Raghavachari K (2000) Perspective on “Density functional thermochemistry. III. The role of exact exchange.” Theor Chim Acta 103(3–4):361–363. https://doi.org/10.1007/s002149900065CrossRef

44.

WOS: https://www.webofscience.com/wos/woscc/summary/cb588014-8766-4beb-a7fd-192b027b902a-5cc202ce/relevance/1.

Title: Chemically functionalized poly(AAm-AMPSA) superadsorbent hydrogels for removal of uranyl from aqueous solutions
Authors: Yasemin Işıkver
Nihat Alkan
Publication date: 12-09-2023
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 1/2024
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-023-05000-3

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 1/2024

Green synthesized guar plant composites for wastewater remediation: a comprehensive review

Starches in the encapsulation of plant active ingredients: state of the art and research trends

Synthesis and characterization of polypropylene glycol–polytetrahydrofuran–polypropylene glycol copolymer: investigation of effective parameters on the synthesis and preparation of elastomer

Shape memory properties of epoxy with hybrid multi-walled carbon nanotube and montmorillonite nanoclay nanofiller

Effect of particle sizes on physical, thermal and mechanical behavior of a hybrid composite with polymer matrix with raffia vinifera cork and Bambusa vulgaris

A two-layer nanofiber-Tragacanth hydrogel composite containing Lavender extract and Mupirocin as a wound dressing

Premium Partners