Top

Polymer Bulletin

15-04-2024 | ORIGINAL PAPER

Chitosan-modified graphene oxide filled photo-curable nanocomposite coating with advanced properties

Authors: Mehdi Sharif, Sahar Tavakoli

Published in: Polymer Bulletin

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

This study presents the eco-friendly composites coating with advanced properties that are prepared by chitosan (CS)-modified graphene oxide (GO) filled acrylic-based coating. Photo-curable acrylic-based nanocomposite containing different amounts of chitosan-modified graphene oxide (CS–GO) and the effect of CS–GO on the coating morphology, UV-curing, transparency, tribological, antimicrobial, thermal and anticorrosion properties was studied. The curing study confirmed that the CS–GO absorbed photon but did not affect the final conversion of the coatings. The results of corrosion analysis demonstrated that the CS–GO filled nanocomposite coatings have higher corrosion protection ability than that of pure acrylic and GO filled coatings. The antimicrobial properties of CS–GO filled coating showed that the antimicrobial performance enhanced as the concentration of CS–GO increased. The optical transmittance study shows that the coating's film transparency decreased with increasing CS–GO concentration, but all of the nanocomposite coatings have a high visible transmittance. This study attributes the enhanced properties to the dispersion of the chitosan-modified GO, which greatly improved the interfacial strength of CS–GO and polymeric matrix and enhanced corrosion properties.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Ceccia S, Turcato EA, Maffettone PL, Bongiovanni R (2008) Nanocomposite UV-cured coatings: organoclay intercalation by an epoxy resin. Prog Org Coat 63:110–115. https://doi.org/10.1016/j.porgcoat.2008.04.012CrossRef

Shemper BS, Morizur JF, Alirol M et al (2004) Synthetic clay nanocomposite-based coatings prepared by UV-cure photopolymerization. J Appl Polym Sci 93:1252–1263. https://doi.org/10.1002/app.20580CrossRef

Decker C, Keller L, Zahouily K, Benfarhi S (2005) Synthesis of nanocomposite polymers by UV-radiation curing. Polymer 46:6640–6648. https://doi.org/10.1016/j.polymer.2005.05.018CrossRef

Dixit A, Wazarkar K, Sabnis AS (2021) Antimicrobial UV curable wood coatings based on citric acid. Pigment Resin Technol 50:533–544. https://doi.org/10.1108/PRT-07-2020-0067CrossRef

Uh FM, Davuluri SP, Wong SC, Webster DC (2004) Nanoclay reinforced UV curable high-barrier coatings. Compos Technol 2020:719–724

Belon C, Chemtob A, Croutxé-Barghorn C et al (2010) Nanocomposite coatings via simultaneous organic-inorganic photo-induced polymerization: synthesis, structural investigation and mechanical characterization. Polym Int 59:1175–1186. https://doi.org/10.1002/pi.2846CrossRef

Xiao C, Zheng K, Chen S et al (2023) Additive manufacturing of high solid content lunar regolith simulant paste based on vat photopolymerization and the effect of water addition on paste retention properties. Addit Manuf 71:103607. https://doi.org/10.1016/j.addma.2023.103607CrossRef

Sangermano M, Malucelli G, Amerio E et al (2005) Photopolymerization of epoxy coatings containing silica nanoparticles. Prog Org Coat 54:134–138. https://doi.org/10.1016/j.porgcoat.2005.05.004CrossRef

Amerio E, Sangermano M, Malucelli G et al (2005) Preparation and characterization of hybrid nanocomposite coatings by photopolymerization and sol-gel process. Polymer 46:11241–11246. https://doi.org/10.1016/j.polymer.2005.09.062CrossRef

10.

Njoku CN, Arukalam IO, Bai W, Li Y (2018) Optimizing maleic anhydride microcapsules size for use in self-healing epoxy-based coatings for corrosion protection of aluminum alloy. Mater Corros 69:1257–1267. https://doi.org/10.1002/maco.201709972CrossRef

11.

Arukalam IO, Ishidi EY, Obasi HC et al (2020) Exploitation of natural gum exudates as green fillers in self-healing corrosion-resistant epoxy coatings. J Polym Res 27:1. https://doi.org/10.1007/s10965-020-02055-yCrossRef

12.

Keller L, Decker C, Zahouily K et al (2004) Synthesis of polymer nanocomposites by UV-curing of organoclay-acrylic resins. Polymer 45:7437–7447. https://doi.org/10.1016/j.polymer.2004.08.040CrossRef

13.

Sangermano M, Amerio E, Priola A et al (2006) Preparation and characterization of acrylic resin/titania hybrid nanocomposite coatings by photopolymerization and sol-gel process. J Appl Polym Sci 102:4659–4664. https://doi.org/10.1002/app.24707CrossRef

14.

Wang YY, Hsieh TE (2005) Preparation and properties of polyacrylate/clay photocured nanocomposite materials. Chem Mater 17:3331–3337. https://doi.org/10.1021/cm0487268CrossRef

15.

Uhl FM, Webster DC, Davuluri SP, Wong SC (2006) UV curable epoxy acrylate-clay nanocomposites. Eur Polym J 42:2596–2605. https://doi.org/10.1016/j.eurpolymj.2006.06.016CrossRef

16.

Cho JD, Kim YB, Ju HT, Hong JW (2005) The effects of silica nanoparticles on the photocuring behaviors of UV-curable polyester acrylate-based coating systems. Macromol Res 13:362–365. https://doi.org/10.1007/BF03218467CrossRef

17.

Sørensen PA, Kiil S, Dam-Johansen K, Weinell CE (2009) Anticorrosive coatings: a review. J Coat Technol Res 6:135–176. https://doi.org/10.1007/s11998-008-9144-2CrossRef

18.

Yang F, Liu T, Li J et al (2018) Anticorrosive behavior of a zinc-rich epoxy coating containing sulfonated polyaniline in 3.5% NaCl solution. RSC Adv 8:13237–13247. https://doi.org/10.1039/c8ra00845kCrossRefPubMedPubMedCentral

19.

Zhang C, Zhang X, Santosh M et al (2020) Zircon Hf–O–Li isotopes of granitoids from the central Asian orogenic belt: implications for supercontinent evolution. Gondwana Res 83:132–140. https://doi.org/10.1016/j.gr.2020.02.003CrossRef

20.

Pecora M, Pannier Y, Lafarie-Frenot MC et al (2016) Effect of thermo-oxidation on the failure properties of an epoxy resin. Polym Test 52:209–217. https://doi.org/10.1016/j.polymertesting.2016.04.008CrossRef

21.

Woo RSC, Chen Y, Zhu H et al (2007) Environmental degradation of epoxy-organoclay nanocomposites due to UV exposure. Part I: photo-degradation. Compos Sci Technol 67:3448–3456. https://doi.org/10.1016/j.compscitech.2007.03.004CrossRef

22.

Foroutani K, Pourabbas B, Sharif M et al (2014) In situ deposition of polythiophene nanoparticles on flexible transparent films: effect of the process conditions. Mater Sci Semicond Process 19:57–65. https://doi.org/10.1016/j.mssp.2013.11.012CrossRef

23.

Zhao X, Fan B, Qiao N et al (2024) Stabilized Ti₃C₂T_x-doped 3D vesicle polypyrrole coating for efficient protection toward copper in artificial seawater. Appl Surf Sci 642:158639. https://doi.org/10.1016/j.apsusc.2023.158639CrossRef

24.

Wang K, Zhu J, Wang H et al (2022) Air plasma-sprayed high-entropy (Y_0.2Yb_0.2Lu_0.2Eu_0.2Er_0.2)3Al₅O₁₂ coating with high thermal protection performance. J Adv Ceram 11:1571–1582. https://doi.org/10.1007/s40145-022-0630-2CrossRef

25.

Xie J, Chen Y, Yin L et al (2021) Microstructure and mechanical properties of ultrasonic spot welding TiNi/Ti₆Al₄V dissimilar materials using pure Al coating. J Manuf Process 64:473–480. https://doi.org/10.1016/j.jmapro.2021.02.009CrossRef

26.

Cho JD, Ju HT, Hong JW (2005) Photocuring kinetics of UV-initiated free-radical photopolymerizations with and without silica nanoparticles. J Polym Sci Part A Polym Chem 43:658–670. https://doi.org/10.1002/pola.20529CrossRef

27.

Xu GC, Li AY, De ZL et al (2003) Synthesis and characterization of silica nanocomposite in situ photopolymerization. J Appl Polym Sci 90:837–840. https://doi.org/10.1002/app.12650CrossRef

28.

Foroutani K, Pourabbas B, Sharif M et al (2014) Preparation of conductive flexible films by in situ deposition of polythiophene nanoparticles on polyethylene naphthalate. Mater Sci Semicond Process 18:6–14. https://doi.org/10.1016/j.mssp.2013.10.015CrossRef

29.

Chen J, Zhang Z, Lu H (2022) Structure design and properties investigation of Bi₂O₂Se/graphene van der Waals heterojunction from first-principles study. Surf Interfaces 33:102289. https://doi.org/10.1016/j.surfin.2022.102289CrossRef

30.

Esmaeili-Faraj SH, Hassanzadeh A, Shakeriankhoo F et al (2021) Diesel fuel desulfurization by alumina/polymer nanocomposite membrane: experimental analysis and modeling by the response surface methodology. Chem Eng Process Process Intensif 164:108396. https://doi.org/10.1016/j.cep.2021.108396CrossRef

31.

Dhanola A, Bisht AS, Kumar A, Kumar A (2018) Influence of natural fillers on physico-mechanical properties of luffa cylindrica/ polyester composites. Mater Today Proc 5:17021–17029. https://doi.org/10.1016/j.matpr.2018.04.107CrossRef

32.

Kocaman S, Ahmetli G, Materials A (2016) Eco-friendly natural filler based epoxy composites. Int J Chem Mol Eng 10:471–474

33.

Zhang X, Tang Y, Zhang F, Lee CS (2016) A novel aluminum-graphite dual-ion battery. Adv Energy Mater 6:1502588. https://doi.org/10.1002/aenm.201502588CrossRef

34.

Huang Z, Luo P, Jia S et al (2022) A sulfur-doped carbon-enhanced Na₃V₂(PO₄)₃ nanocomposite for sodium-ion storage. J Phys Chem Solids 167:110746. https://doi.org/10.1016/j.jpcs.2022.110746CrossRef

35.

Ashassi-Sorkhabi H, Kazempour A (2020) Chitosan, its derivatives and composites with superior potentials for the corrosion protection of steel alloys: a comprehensive review. Carbohydr Polym 237:116110. https://doi.org/10.1016/j.carbpol.2020.116110CrossRefPubMed

36.

John S, Joseph A, Jose AJ, Narayana B (2015) Enhancement of corrosion protection of mild steel by chitosan/ZnO nanoparticle composite membranes. Prog Org Coat 84:28–34. https://doi.org/10.1016/j.porgcoat.2015.02.005CrossRef

37.

Zheludkevich ML, Tedim J, Freire CSR et al (2011) Self-healing protective coatings with “green” chitosan based pre-layer reservoir of corrosion inhibitor. J Mater Chem 21:4805–4812. https://doi.org/10.1039/c1jm10304kCrossRef

38.

Selvam V, Kumar MSC, Vadivel M (2013) Mechanical properties of epoxy/chitosan biocomposites. Int J Chem Sci 11:1103–1109

39.

Jabeen S, Saeed S, Kausar A et al (2016) Influence of chitosan and epoxy cross-linking on physical properties of binary blends. Int J Polym Anal Charact 21:163–174. https://doi.org/10.1080/1023666X.2016.1131404CrossRef

40.

Ahmad B, Ashfaq M, Joy A, Carlos ZASM (2017) Fabrication and characterization of an eco-friendly biodegradable epoxy/chitosan composites. Am J Mater Sci 7:166–169

41.

El-Fattah MA, El Saeed AM, Azzam AM et al (2016) Improvement of corrosion resistance, antimicrobial activity, mechanical and chemical properties of epoxy coating by loading chitosan as a natural renewable resource. Prog Org Coat 101:288–296. https://doi.org/10.1016/j.porgcoat.2016.09.002CrossRef

42.

Ma IW, Sh A, Ramesh K, Vengadaesvaran B, Ramesh S, Arof AK (2017) Anticorrosion properties of epoxy-nanochitosan nanocomposite coating. Progress Org Coat 113:74–81. https://doi.org/10.1016/j.porgcoat.2017.08.014CrossRef

43.

Khakpour M, Vaferi B (2023) Experimental and modeling analyses of stability and thermophysical characteristics of graphene oxide, carbon nanotube, and silicon carbide dispersion in propylene glycol. Heat Transf Res 54:1–15. https://doi.org/10.1615/HeatTransRes.2023047129CrossRef

44.

Rana VK, Choi MC, Kong JY et al (2011) Synthesis and drug-delivery behavior of chitosan-functionalized graphene oxide hybrid nanosheets. Macromol Mater Eng 296:131–140. https://doi.org/10.1002/mame.201000307CrossRef

45.

Wang Z, Fu W, Hu L et al (2021) Improvement of electron transfer efficiency during denitrification process by Fe-Pd/multi-walled carbon nanotubes: possessed redox characteristics and secreted endogenous electron mediator. Sci Total Environ 781:146686. https://doi.org/10.1016/j.scitotenv.2021.146686CrossRef

46.

Huang Z, Luo P, Wu Q, Zheng H (2022) Constructing one-dimensional mesoporous carbon nanofibers loaded with NaTi₂(PO₄)₃ nanodots as novel anodes for sodium energy storage. J Phys Chem Solids 161:110479. https://doi.org/10.1016/j.jpcs.2021.110479CrossRef

47.

Fang M, Wang K, Lu H et al (2009) Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites. J Mater Chem 19:7098–7105. https://doi.org/10.1039/b908220dCrossRef

48.

Han D, Yan L, Chen W, Li W (2011) Preparation of chitosan/graphene oxide composite film with enhanced mechanical strength in the wet state. Carbohydr Polym 83:653–658. https://doi.org/10.1016/j.carbpol.2010.08.038CrossRef

49.

Zare M, Sharif M, Kashkooli A (2014) Study on the effect of polypyrrole and polypyrrole/graphene oxide nanoparticles on the microstructure, electrical and tensile properties of polypropylene nanocomposites. Polym Plast Technol Eng 53:1392–1401. https://doi.org/10.1080/03602559.2014.909472CrossRef

50.

Le TT, Nguyen TV, Nguyen TA et al (2019) Thermal, mechanical and antibacterial properties of water-based acrylic polymer/SiO₂–Ag nanocomposite coating. Mater Chem Phys 232:362–366. https://doi.org/10.1016/j.matchemphys.2019.05.001CrossRef

51.

Nguyen TV, Do TV, Ha MH et al (2020) Crosslinking process, mechanical and antibacterial properties of UV-curable acrylate/Fe₃O₄-Ag nanocomposite coating. Prog Org Coat 139:105325. https://doi.org/10.1016/j.porgcoat.2019.105325CrossRef

52.

Shimazaki Y, Miyazaki Y, Takezawa Y et al (2007) Excellent thermal conductivity of transparent cellulose nanofiber/epoxy resin nanocomposites. Biomacromol 8:2976–2978. https://doi.org/10.1021/bm7004998CrossRef

53.

Iijima T, Miura S, Fukuda W, Tomoi M (1993) Effect of cross-link density on modification of epoxy resins by N-phenylmaleimide-styrene copolymers. Eur Polym J 29:1103–1113CrossRef

54.

Su Y, Shen Z, Long X et al (2023) Gaussian filtering method of evaluating the elastic/elasto-plastic properties of sintered nanocomposites with quasi-continuous volume distribution. Mater Sci Eng A 872:145001. https://doi.org/10.1016/j.msea.2023.145001CrossRef

55.

Helander IM, Nurmiaho-Lassila EL, Ahvenainen R et al (2001) Chitosan disrupts the barrier properties of the outer membrane of gram-negative bacteria. Int J Food Microbiol 71:235–244. https://doi.org/10.1016/S0168-1605(01)00609-2CrossRefPubMed

56.

Liu H, Du Y, Wang X, Sun L (2004) Chitosan kills bacteria through cell membrane damage. Int J Food Microbiol 95:147–155. https://doi.org/10.1016/j.ijfoodmicro.2004.01.022CrossRefPubMed

57.

Carlson RP, Taffs R, Davison WM, Stewart PS (2008) Anti-biofilm properties of chitosan-coated surfaces. J Biomater Sci Polym Ed 19:1035–1046. https://doi.org/10.1163/156856208784909372CrossRefPubMed

58.

Zhu S, Zhu J, Ye S et al (2023) High-entropy rare earth titanates with low thermal conductivity designed by lattice distortion. J Am Ceram Soc 106:6279–6291. https://doi.org/10.1111/jace.19233CrossRef

Title: Chitosan-modified graphene oxide filled photo-curable nanocomposite coating with advanced properties
Authors: Mehdi Sharif
Sahar Tavakoli
Publication date: 15-04-2024
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-024-05202-3

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Premium Partners