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Published in: Colloid and Polymer Science 8/2013

01-08-2013 | Short Comunication

Coating sulfonated polystyrene microspheres with highly dense gold nanoparticle shell for SERS application

Authors: Wujin Cai, Wenqin Wang, Linchao Lu, Tao Chen

Published in: Colloid and Polymer Science | Issue 8/2013

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Abstract

The fabrication of highly dense gold nanoparticles (NPs)-coated sulfonated polystyrene (PS) microspheres and their application in surface-enhanced Raman spectroscopy (SERS) were reported. After the preparation of PS microsphere using dispersion polymerization and subsequent sulfonation, [Ag(NH3)2]+ ions were adsorbed on the surfaces of the sulfonated PS microspheres and then reduced to silver nanoseeds for further growth of gold NPs shell by seeded growth approach. Reaction conditions such as the concentration of the growth solution and growth time were adjusted to achieve nonspherical gold NPs-coated PS microspheres with different coverage degree. The application of the as-prepared spiky gold NPs-coated PS microsphere hybrid composite in SERS was finally investigated by using 4-aminothiophenol as probe molecules. The results showed that as-prepared gold NPs-coated PS microspheres could be used as functional hybrid materials to exhibit excellent enhancement ability in SERS.

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Metadata
Title
Coating sulfonated polystyrene microspheres with highly dense gold nanoparticle shell for SERS application
Authors
Wujin Cai
Wenqin Wang
Linchao Lu
Tao Chen
Publication date
01-08-2013
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 8/2013
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-013-2928-7

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