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Journal of Sol-Gel Science and Technology

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04-04-2022 | Invited Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Colloidal dispersion of chiral layered hydroxide salt (LHS) nanocrystals exhibiting chiroptical response

Authors: Yasuaki Tokudome, Akihiro Koyama, Hidenobu Murata, Kenji Okada, Atsushi Nakahira, Shigenori Nishimura, Masahide Takahashi

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2022

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Abstract

Chiral inorganic materials have attracted increasing attention in the fields such as catalysis, electronics, photonics, and sensing. A new class of functional materials with chirality is extensively explored. Herein, we demonstrate the synthesis of nanometric nickel layered hydroxide salt (Ni-LHS) modified with chiral amino acids, (D- or L-) phenylalanine (PHE). An alkalization reaction in a starting mixture of nickel-phenylalanine aqua complexes was induced by using propylene oxide, leading to intercalate and adsorb phenylalanine on the surface and into the interlayers of Ni-LHS in an in-situ manner. The chiral molecules also act as surface modifier to inhibit the extensive crystal growth and aggregation, to form Ni-LHS with a diameter of 2–3 nm in a state of stablly-suspended in a solvent. It was also found that Ni-LHS exhibit induced circular dichroism (ICD) in the spectral range of d-d transitions of Ni(II) metal centres. The layered nanomaterials with chiroptical response demonstrated here is a promising option as an advanced adsorbent for detection of molecules.

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Title: Colloidal dispersion of chiral layered hydroxide salt (LHS) nanocrystals exhibiting chiroptical response
Authors: Yasuaki Tokudome
Akihiro Koyama
Hidenobu Murata
Kenji Okada
Atsushi Nakahira
Shigenori Nishimura
Masahide Takahashi
Publication date: 04-04-2022
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 3/2022
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-022-05766-4

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