Top

Journal of Coatings Technology and Research

Published in:

13-03-2018

Considering the effect of graphene loading in water-based epoxy coatings

Authors: T. Monetta, A. Acquesta, A. Carangelo, F. Bellucci

Published in: Journal of Coatings Technology and Research | Issue 5/2018

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Recently, graphene has gained increasing interest in numerous fields of application and, in particular, it has been used as a nanofiller in the preparation of polymeric composites to improve their mechanical and transport properties. However, the effect of graphene as a potential additive for anticorrosive organic coatings is not widely studied. In this work, low levels of graphene nanosheets, 0.5 and 1 wt%, were added to an additive-free waterborne epoxy resin applied to Al2024-T3 aluminum alloy samples. The presence of graphene did not affect the polymerization process of the resin and the adhesion at coating/substrate interface, as demonstrated by experimental results, while showing a slight effect on coatings wettability. Electrochemical analysis revealed an improvement of the protective properties of the coating that could be assigned to a slow absorption rate of the electrolytes in the polymeric matrix and a lesser amount of absorbed water than the unloaded film.

previous article A macroscopically nondestructive method for characterizing surface mechanical properties of polymeric coatings under accelerated weathering

next article Evaluation of the ASTM D7869-13 test method to predict the gloss and color retention of premium architectural finishes-I

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Kumar, S, Raj, S, Jain, S, Chatterjee, K, “Multifunctional Biodegradable Polymer Nanocomposite Incorporating Graphene-Silver Hybrid for Biomedical Applications.” Mater. Des., 108 319–332 (2016)CrossRef

Ladani, RB, Wu, S, Kinloch, AJ, Ghorbani, K, Zhang, J, Mouritz, AP, Wang, CH, “Multifunctional Properties of Epoxy Nanocomposites Reinforced by Aligned Nanoscale Carbon.” Mater. Des., 94 554–564 (2016)CrossRef

Wang, C, Lan, Y, Yu, W, Li, X, Qian, Y, Liu, H, “Preparation of Amino-Functionalized Graphene Oxide/Polyimide Composite Films with Improved Mechanical, Thermal and Hydrophobic Properties.” Appl. Surf. Sci., 362 11–19 (2016)CrossRef

Zhao, S, Chang, H, Chen, S, Cui, J, Yan, Y, “High-Performance and Multifunctional Epoxy Composites Filled with Epoxide-Functionalized Graphene.” Eur. Polym. J., 84 300–312 (2016)CrossRef

Kim, H, Miura, Y, Macosko, CW, “Graphene/Polyurethane Nanocomposites for Improved Gas Barrier and Electrical Conductivity.” Chem. Mater., 22 3441–3450 (2010)CrossRef

Song, SH, Park, KH, Kim, BH, Choi, YW, Jun, GH, Lee, DJ, Kong, BS, Paik, KW, Jeon, S, “Enhanced Thermal Conductivity of Epoxy-Graphene Composites by Using Non-Oxidized Graphene Flakes with Non-Covalent Functionalization.” Adv. Mater., 25 732–737 (2013)CrossRef

Tang, B, Hu, G, Gao, H, Hai, L, “Application of Graphene as Filler to Improve Thermal Transport Property of Epoxy Resin for Thermal Interface Materials.” Int. J. Heat Mass Transf., 85 420–429 (2015)CrossRef

Wang, Y, Yu, J, Dai, W, Song, Y, Wang, D, Zeng, L, Jiang, N, “Enhanced Thermal and Electrical Properties of Epoxy Composites Reinforced with Graphene Nanoplatelets.” Polym. Compos., 36 556–565 (2015)CrossRef

Wajid, AS, Ahmed, HST, Das, S, Irin, F, Jankowski, AF, Green, MJ, “High-Performance Pristine Graphene/Epoxy Composites with Enhanced Mechanical and Electrical Properties.” Macromol. Mater. Eng., 298 339–347 (2013)CrossRef

10.

Wang, F, Drzal, LT, Qin, Y, Huang, Z, “Mechanical Properties and Thermal Conductivity of Graphene Nanoplatelet/Epoxy Composites.” J. Mater. Sci., 50 1082–1093 (2015)CrossRef

11.

Zhang, B, Asmatulu, R, Soltani, SA, Le, LN, Kumar, SSS, “Mechanical and Thermal Properties of Hierarchical Composites Enhanced by Pristine Graphene and Graphene Oxide Nanoinclusions.” J. Appl. Polym. Sci., 131 40826–40834 (2014)

12.

Chang, KC, Hsu, MH, Lu, HI, Lai, MC, Liu, PJ, Hsu, CH, Ji, WF, Chuang, TL, Wei, Y, Yeh, JM, Liu, WR, “Room-Temperature Cured Hydrophobic Epoxy/Graphene Composites as Corrosion Inhibitor for Cold-Rolled Steel.” Carbon, 66 144–153 (2014)CrossRef

13.

Chang, KC, Ji, WF, Lai, MC, Hsiao, YR, Hsu, CH, Chuang, TL, Wei, Y, Yeh, JM, Liu, WR, “Synergistic Effects of Hydrophobicity and Gas Barrier Properties on the Anticorrosion Property of PMMA Nanocomposite Coatings Embedded with Graphene Nanosheets.” Polym. Chem. (UK), 5 1049–1056 (2014)CrossRef

14.

Liu, D, Zhao, W, Liu, S, Cen, Q, Xue, Q, “Comparative Tribological and Corrosion Resistance Properties of Epoxy Composite Coatings Reinforced with Functionalized Fullerene C60 and Graphene.” Surf. Coat. Technol., 286 354–364 (2016)CrossRef

15.

Liu, S, Gu, L, Zhao, H, Chen, J, Yu, H, “Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings.” J. Mater. Sci. Technol., 32 425–431 (2016)CrossRef

16.

Rajabi, M, Rashed, GR, Zaarei, D, “Assessment of Graphene Oxide/Epoxy Nanocomposite as Corrosion Resistance Coating on Carbon Steel.” Corros. Eng. Sci. Technol., 50 509–516 (2015)CrossRef

17.

Ramezanzadeh, B, Niroumandrad, S, Ahmadi, A, Mahdavian, M, Moghadam, MHM, “Enhancement of Barrier and Corrosion Protection Performance of an Epoxy Coating Through Wet Transfer of Amino Functionalized Graphene Oxide.” Corros. Sci., 103 283–304 (2016)CrossRef

18.

Ramezanzadeh, B, Ahmadi, A, Mahdavian, M, “Enhancement of the Corrosion Protection Performance and Cathodic Delamination Resistance of Epoxy Coating Through Treatment of Steel Substrate by a Novel Nanometric Sol–Gel Based Silane Composite Film Filled with Functionalized Graphene Oxide Nanosheets.” Corros. Sci., 109 182–205 (2016)CrossRef

19.

Yu, Z, Di, H, Ma, Y, He, Y, Liang, L, Lv, L, Ran, X, Pan, Y, Luo, Z, “Preparation of Graphene Oxide Modified by Titanium Dioxide to Enhance the Anti-corrosion Performance of Epoxy Coatings.” Surf. Coat. Technol., 276 471–478 (2015)CrossRef

20.

Yu, Z, Lv, L, Ma, Y, Di, H, He, Y, “Covalent Modification of Graphene Oxide by Metronidazole for Reinforced Anti-Corrosion Properties of Epoxy Coatings.” RSC Adv., 6 18217–18226 (2016)CrossRef

21.

Xiao, W, Liu, Y, Guo, S, “Composites of Graphene Oxide and Epoxy Resin Assuming a Uniform 3D Graphene Oxide Network Structure.” RSC Adv., 6 86904–86908 (2016)CrossRef

22.

Yousefi, N, Lin, X, Zheng, Q, Shen, X, Pothnis, JR, Jia, J, Zussman, E, Kim, JK, “Simultaneous In Situ Reduction, Self-Alignment and Covalent Bonding in Graphene Oxide/Epoxy Composites.” Carbon, 59 406–417 (2013)CrossRef

23.

Gu, L, Liu, S, Zhao, H, Yu, H, “Facile Preparation of Water-Dispersible Graphene Sheets Stabilized by Carboxylated Oligoanilines and Their Anticorrosion Coatings.” ACS Appl. Mater. Interfaces, 7 17641–17648 (2015)CrossRef

24.

Monetta, T, Acquesta, A, Bellucci, F, “Graphene/Epoxy Coating as Multifunctional Material for Aircraft Structures.” Aerospace, 2 423–434 (2015)CrossRef

25.

C.D. 1999/13/EC, Official Journal of the European Communities L 85/1-22 (1999)

26.

Andreatta, F, Bortolotto, M, Lanzutti, A, Paussa, L, Bravin, D, Fedrizzi, L, “Environmentally friendly conversion coating for aluminium alloy AA6014.” 18th International Corrosion Congress, Perth, Australia, 2011

27.

Deflorian, F, Rossi, S, Fedel, M, “Aluminium Components for Marine Applications Protected Against Corrosion by Organic Coating Cycles with Low Environmental Impact.” Corros. Eng. Sci. Technol., 46 237–244 (2011)CrossRef

28.

Sinagra, C, Bravaccino, F, Bitondo, C, Bossio, A, Monetta, T, Mitton, DB, Bellucci, F, “Green Technology for Surface Treatments of Aluminium Foil For Flexible Packaging.” Key Eng. Mater., 710 186–191 (2016)CrossRef

29.

Carangelo, A, Curioni, M, Acquesta, A, Monetta, T, Bellucci, F, “Cerium-Based Sealing of Anodic Films on AA2024T3: Effect of Pore Morphology on Anticorrosion Performance.” J. Electrochem. Soc., 163 C907–C916 (2016)CrossRef

30.

Carangelo, A, Curioni, M, Acquesta, A, Monetta, T, Bellucci, F, “Application of EIS to In Situ Characterization of Hydrothermal Sealing of Anodized Aluminum Alloys: Comparison Between Hexavalent Chromium-Based Sealing, Hot Water Sealing and Cerium-Based Sealing.” J. Electrochem. Soc., 163 C619–C626 (2016)CrossRef

31.

Carneiro, J, Tedim, J, Fernandes, SCM, Freire, CSR, Silvestre, AJD, Gandini, A, Ferreira, MGS, Zheludkevich, ML, “Chitosan-Based Self-Healing Protective Coatings Doped with Cerium Nitrate for Corrosion Protection of Aluminum Alloy 2024.” Prog. Org. Coat., 75 8–13 (2012)CrossRef

32.

Fetouh, HA, Abdel-Fattah, TM, El-Tantawy, MS, “Novel Plant Extracts as Green Corrosion Inhibitors for 7075-T6 Aluminium Alloy in an Aqueous Medium.” Int. J. Electrochem. Sci., 9 1565–1582 (2014)

33.

Gobara, M, Kamel, H, Akid, R, Baraka, A, “Corrosion Behaviour of AA2024 Coated with an Acid-Soluble Collagen/Hybrid Silica Sol–Gel Matrix.” Prog. Org. Coat., 89 57–66 (2015)CrossRef

34.

Monetta, T, Acquesta, A, Maresca, V, Signore, R, Bellucci, F, Di Petta, P, Lo Masti, M, “Characterization of Aluminum Alloys Environmentally Friendly Surface Treatments for Aircraft and Aerospace Industry.” Surf. Interface Anal., 45 1522–1529 (2013)CrossRef

35.

Bitondo, C, Bossio, A, Monetta, T, Curioni, M, Bellucci, F, “The Effect of Annealing on the Corrosion Behaviour of 444 Stainless Steel for Drinking Water Applications.” Corros. Sci., 87 6–10 (2014)CrossRef

36.

Monetta, T, Mitton, DB, Bellucci, F, “Protective Properties of Organic Coatings on Plasma-Treated Cold Rolled Aluminum.” Electrochem. Solid State Lett., 7 B39–B41 (2004)CrossRef

37.

De Rosa, L, Monetta, T, Bellucci, F, “Moisture Uptake in Organic Coatings Monitored with EIS.” Mater. Sci. Forum, 289–292 315–326 (1998)CrossRef

38.

Mansfeld, F, “Use of Electrochemical Impedance Spectroscopy for the Study of Corrosion Protection by Polymer Coatings.” J. Appl. Electrochem., 25 187–202 (1995)

39.

Bellucci, F, Nicodemo, L, “Water Transport in Organic Coatings.” Corrosion, 49 235–247 (1993)CrossRef

40.

Nicodemo, L, Bellucci, F, Marcone, A, Monetta, T, “Water and Oxygen Transport as Performance Parameters of Paint Films.” J. Membr. Sci., 52 393–403 (1990)CrossRef

41.

Walter, GW, “A Review of Impedance Plot Methods Used for Corrosion Performance Analysis of Painted Metals.” Corros. Sci., 26 681–703 (1986)CrossRef

42.

Ku, CC, Liepins, R, Appendix 1 in Electrical Properties of Polymers: Chemical Principles, pp. 334–345. Hanser Publishers, Munich (1987)

43.

Su, Y, Kravets, VG, Wong, SL, Waters, J, Geim, AK, Nair, RR, “Impermeable Barrier Films and Protective Coatings Based on Reduced Graphene Oxide.” Nat. Commun., 5 4843–4847 (2014)CrossRef

44.

Yoo, BM, Shin, HJ, Yoon, HW, Park, HB, “Graphene and Graphene Oxide and Their Uses in Barrier Polymers.” J. Appl. Polym. Sci., 131 39628–39651 (2014)CrossRef

Title: Considering the effect of graphene loading in water-based epoxy coatings
Authors: T. Monetta
A. Acquesta
A. Carangelo
F. Bellucci
Publication date: 13-03-2018
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 5/2018
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-018-0045-8

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 5/2018

UV irradiation grafting of acrylamide onto dopamine-modified 316L stainless steel

Evaluation of the ASTM D7869-13 test method to predict the gloss and color retention of premium architectural finishes-I

Fabrication and properties of polysilsesquioxane-based trilayer core–shell structure latex coatings with fluorinated polyacrylate and silica nanocomposite as the shell layer

Shaping characteristics in alginate hydrogel encapsulation via a two-fluid spraying method

Effect of orange peel attribute of automotive finishes on their blackness perception

Cyclodextrin-based hyperbranched polyester: synthesis, characterization, and antimicrobial activity

Premium Partners