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Journal of Materials Science: Materials in Electronics

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27-06-2020

Construction of BiPO₄/CdS heterojunction photocatalysts for enhanced degradation of organic pollutants under visible light

Authors: Min Shao, Anwei Wang, Haojie Cui, Yuzhe Zhang, Zhiying Liu, Yanhua Xu, Zhongyu Li, Song Xu

Published in: Journal of Materials Science: Materials in Electronics | Issue 15/2020

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Abstract

In this study, the composite of CdS nanorods loaded with BiPO₄ nanoparticles was fabricated as a novel efficient photocatalyst and exhibited strong photocatalytic degradation activities for the degradation of organic pollutants. Among the composites with different mass ratios, 1.8BiPO₄/CdS showed the best catalytic activity, and the removal rates of malachite green (MG), reactive red (X-3B) and ciprofloxacin (CIP) in 80 min were 98%, 99%, and 70%, respectively. The COD removal efficiencies of MG (55%), X-3B (50%) and CIP (44%) by 1.8BiPO₄/CdS composites further proved the superiority of the performance of BiPO₄/CdS heterojunctions under visible light. About 90% MG, 88% X-3B and 58% CIP could be degraded after four cycles indicating the good stability of the materials. The enhanced photocatalytic properties can be attributed to the efficient charge separation as well as interfacial charge transfer from CdS to BiPO₄, which is evidenced by XPS analysis and species trapping. The well dispersion of BiPO₄ on CdS can preserve it from photocorrosion, which effectively enhances the photostability of degradation properties. Moreover, several recommendations and ideas are proposed for improving the utilization of solar energy and environmental restoration in the future.

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Title: Construction of BiPO4/CdS heterojunction photocatalysts for enhanced degradation of organic pollutants under visible light
Authors: Min Shao
Anwei Wang
Haojie Cui
Yuzhe Zhang
Zhiying Liu
Yanhua Xu
Zhongyu Li
Song Xu
Publication date: 27-06-2020
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 15/2020
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-020-03711-1

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