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Journal of Nanoparticle Research

Published in:

01-06-2015

Controlled nanoclustering of magnetic nanoparticles using telechelic polysiloxane and disiloxane

Authors: Bandit Thong-On, Boonjira Rutnakornpituk, Uthai Wichai, Metha Rutnakornpituk

Published in: Journal of Nanoparticle Research | Issue 6/2015

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Abstract

Diacrylate-terminated polydimethylsiloxane (PDMS) and disiloxane were synthesized and used for controlling degree of nanoclustering of magnetite nanoparticles (MNPs). PDMS was synthesized via a ring-opening polymerization of octamethylcyclotetrasiloxane (D₄), followed by end functionalization with diacrylate groups. Diacrylate-terminated disiloxane was separately synthesized in a similar fashion without the use of D₄ in the reaction. They were then reacted with amino-coated MNPs to obtain MNP-embedded siloxane nanoclusters. Transmission electron microscopy showed the formation of MNP-siloxane nanoclusters with the size of 70–200 nm. Degree of MNP nanoclustering can be adjusted by varying the MNP-to-siloxane ratio to obtain hydrodynamic size ranging from 200 to 2400 nm. Using the same ratio of MNPs to the siloxanes, PDMS resulted in the nanoclusters with smaller D _h and more stable in toluene than those coated with disiloxane. These novel nanoclusters with controllable size might be ideal candidates for biomedical and other advanced applications after suitable surface modification.

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Title: Controlled nanoclustering of magnetic nanoparticles using telechelic polysiloxane and disiloxane
Authors: Bandit Thong-On
Boonjira Rutnakornpituk
Uthai Wichai
Metha Rutnakornpituk
Publication date: 01-06-2015
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 6/2015
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-015-3071-9

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