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Colloid and Polymer Science

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13-09-2019 | Original Contribution

Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid

Authors: Alexandra Grigoreva, Egor Polozov, Sergey Zaitsev

Published in: Colloid and Polymer Science | Issue 11-12/2019

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Abstract

The reversible addition–fragmentation chain transfer (RAFT) polymerization of 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) in the presence of different concentrations of S,S-dibenzyl carbonotrithioate as chain transfer agent (CTA) was investigated. The estimate of C_tr was defined using the size-exclusion chromatography measurements. Copolymers of acrylic acid and OFPA with different microstructure were synthesized by three methods: block copolymerization, copolymerization of acrylic acid and OFPA, and chemical modification of copolymer of tert-butyl acrylate and OFPA. Copolymerization of abovementioned monomer pairs was studied. The reactivity ratios were calculated by using the Fineman–Ross and Kelen–Tudos models, as well as the method of least squares. Aggregation behavior of the obtained amphiphilic copolymers at the air/water interface was defined by the Langmuir monolayer technique. Monomolecular films of amphiphilic copolymers were studied using atomic force microscopy. The effect of the chain microstructure, the acrylic acid content in the copolymer, and subphase pH on the isotherm curves were shown.

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Title: Controlled synthesis and self-assembly of amphiphilic copolymers based on 2,2,3,3,4,4,5,5-octafluoropentyl acrylate and acrylic acid
Authors: Alexandra Grigoreva
Egor Polozov
Sergey Zaitsev
Publication date: 13-09-2019
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 11-12/2019
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-019-04559-6

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