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Polymer Science, Series B
Published in: Polymer Science, Series B 2/2020

01-03-2020 | STRUCTURE AND PROPERTIES

Copolymers of Acrylonitrile and Acrylic Acid: Effect of Composition and Distribution of Chain Units on the Thermal Behavior of Copolymers

Authors: R. V. Toms, M. S. Balashov, A. A. Shaova, A. Yu. Gerval’d, N. I. Prokopov, A. V. Plutalova, N. A. Grebenkina, E. V. Chernikova

Published in: Polymer Science, Series B | Issue 2/2020

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Abstract

The copolymers of acrylonitrile and acrylic acid are synthesized for the first time by trithiocarbonate-mediated reversible addition-fragmentation chain transfer polymerization in DMSO at a content of comonomers in the reaction mixture of 40%. Various regimes of acrylic acid introduction into the reaction are tested. This makes it possible to synthesize copolymers with close average composition and different unit distribution in a chain. It is shown that, with an increase in the fraction of acrylic acid in the copolymer, the contribution of the ionic mechanism of cyclization grows, which is favorable for widening the temperature interval of cyclization and decrease in the intensity of heat flow. Reduction in the rate of introduction of acrylic acid into copolymerization and, as a consequence, its more uniform distribution in the chain lead to analogous effects and cause a decrease in the activation energy of cyclization by both the ionic and radical mechanism. Thus, the use of reversible addition-fragmentation chain transfer polymerization with the dosed introduction of the comonomer allows one to tune the properties of the copolymers during their heat treatment.
previous article Influence of the Structure of Polyimide Macromolecules on the Reinforcement of Polycaproamide
next article Synthesis and Properties of a Conducting Material Based on Hybrid Nanofibers of Aliphatic Copolyamide and Polypyrrole

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Footnotes
1
In this and further experiments, the volume of the reaction mixture was increased by an order of magnitude compared with ampoule experiments.
 
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Metadata
Title
Copolymers of Acrylonitrile and Acrylic Acid: Effect of Composition and Distribution of Chain Units on the Thermal Behavior of Copolymers
Authors
R. V. Toms
M. S. Balashov
A. A. Shaova
A. Yu. Gerval’d
N. I. Prokopov
A. V. Plutalova
N. A. Grebenkina
E. V. Chernikova
Publication date
01-03-2020
Publisher
Pleiades Publishing
Published in
Polymer Science, Series B / Issue 2/2020
Print ISSN: 1560-0904
Electronic ISSN: 1555-6123
DOI
https://doi.org/10.1134/S1560090420020086

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