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2018 | OriginalPaper | Chapter

4. Decomposition Behavior of Metal-Ion Exchanged Clays

Author : Dr. Indraneel Suhas Zope

Published in: Fire Retardancy Behavior of Polymer/Clay Nanocomposites

Publisher: Springer Singapore

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Abstract

This chapter deals with exploring the effect of different metal ions like Mg2+, Al3+, and Fe3+ present in/on MI-clays in altering the kinetics and/or decomposition mechanism of organic modifier, HDTMA-Br. The catalytic activity is seen to be a combined effect of Brønsted and Lewis acid characters associated with the metal ions. The effect varies significantly with the predominant cation in organically modified MI-clays (OMI-clays). Knowing the effect of each metal ion separately, the correlation between clay structural chemistry and organic decomposition onset is established.

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Metadata
Title
Decomposition Behavior of Metal-Ion Exchanged Clays
Author
Dr. Indraneel Suhas Zope
Copyright Year
2018
Publisher
Springer Singapore
DOI
https://doi.org/10.1007/978-981-10-8327-3_4

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