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02-01-2024 | Letter

Design and preparation of highly crystalline K-intercalated W@PCN: an efficient material for aniline elimination

Authors: Hao-Fei Li, Kai-Wen Yu, Xiao-Bi Jing, Lei Duan, Yi-Yang Zhang

Published in: Rare Metals | Issue 3/2024

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In this paper, we designed and prepared the polymeric carbon nitride-supported tungsten (W@PCN) materials. They were employed as the catalysts for photocatalytic oxidation of aniline in water. During the process, H₂O₂ was initially generated via the PCN-catalyzed hydrophotolysis. Catalyzed by supported tungsten, aniline was oxidized by the in situ generated H₂O₂ to obtain less toxic polyaniline. It was found that by using KBr as the additive, the highly crystalline K-intercalated material (W@PCN-K) could be prepared. Catalytic activity of the material was obviously enhanced due to its improved surface morphology with elevated specific surface areas. The novel highly crystalline K-intercalated material is expected to be applied in waste water treatment for its superior catalytic performances.

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Title: Design and preparation of highly crystalline K-intercalated W@PCN: an efficient material for aniline elimination
Authors: Hao-Fei Li
Kai-Wen Yu
Xiao-Bi Jing
Lei Duan
Yi-Yang Zhang
Publication date: 02-01-2024
Publisher: Nonferrous Metals Society of China
Published in: Rare Metals / Issue 3/2024
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02473-z

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