Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Bulletin
Published in: Polymer Bulletin 2/2024

06-04-2023 | ORIGINAL PAPER

Development of biodegradable vinyl acetate and acrylic acid grafted gelatin copolymer for dye adsorption

Authors: Muhammad Amjad, Ayesha Mohyuddin, Sohail Nadeem, Wajad Ulfat, Shagufta Saeed, Nadeem Asghar, Saeed Ahmed

Published in: Polymer Bulletin | Issue 2/2024

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A novel biodegradable copolymer and nanocomposite with nickel-doped zinc oxide were developed using grafting acrylic acid and vinyl acetate as gelatin backbone in the presence of ammonium persulfate as an initiator. The copolymer and its nanocomposite were formed through free radical polymerization. The prepared copolymer and its nanocomposite were characterized using Fourier Transform Infrared Spectroscopy (FTIR), thermogravimetric analysis (TGA), and Differential Scanning Calorimetry (DSC). The intense bands at 1750 cm−1, 1375 cm−1, 1250 cm−1, and 1050 cm−1in the FTIR spectrum of polymers confirm the grafting of monomers of the gelatin backbone. The TGA analysis indicates that the copolymers were not wholly exhausted up to 500 °C, and adding nanoparticles enhanced the thermal stability. The degradation study revealed a 25.29% and 15.01% weight loss over two months for copolymer and nanocomposite, respectively. Results showed that the initial weight of the copolymer and its nanocomposite increased due to water adsorption and then decreased, as identified by the soil burial method. The copolymer is biodegradable, and the addition of nanoparticles (nanocomposite) increased its shelf life and resistance to soil microbes. The synthesized nanocomposite was evaluated as an adsorbent for methylene blue dye from an aqueous solution. The adsorbent copolymer gelatin-g-poly(vinyl-acetate-co-acrylic acid) with Ni-doped ZnO NPs may prove to be a new route toward pollution control for the removal of methylene blue, having a removal capacity of 521.26 mg/g.

Graphical abstract

previous article Effect of curcumin-loaded poly(amidoamine) dendrimer on cancer cell lines: a comparison between physical loading and chemical conjugation of drug
next article Preparation of dendrimer/TiO2 polysulfone nanofiltration membrane to improve antibacterial, antifouling and separation performance of contaminants (heavy metals, salts, dyes)

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
2.
Kumar AA, Karthick K, Arumugam KP (2011) Biodegradable polymers and its applications. Int J Biosci Biochem Bioinf 1(3):173
3.
Ching C, Kaplan D, Thomas E (1993) Biodegradable polymers and packaging. Tech Publ Company Lancaster 29:97–110
4.
5.
Petersen K, Nielsen PV, Bertelsen G, Lawther M, Olsen MB, Nilsson NH, Mortensen G (1999) Potential of biobased materials for food packaging. Trends Food Sci Technol 10:52–68CrossRef
6.
Corcoran PL, Biesinger C, Grifi M (2009) Plastics and beaches: a degrading relationship. Mar Pollut Bull 58:80–84PubMedCrossRef
7.
Derraik JG (2002) The pollution of the marine environment by plastic debris: a review. Mar pollut bull 44:842–852PubMedCrossRef
8.
Guzman A, Gnutek N, Janik H (2011) Biodegradable polymers for food packaging–factors influencing their degradation and certification types–a comprehensive review. Chem Chem Technol 5:115–122CrossRef
9.
Lazar B, Gračan R (2011) Ingestion of marine debris by loggerhead sea turtles, Caretta caretta, in the Adriatic Sea. Mar pollut bullet 62:43–47CrossRef
10.
Azzarello MY, Edward S, Van-Vleet ES (1987) Marine birds and plastic pollution. Mar Ecol Prog Ser 37:295–303CrossRef
11.
12.
Barreiros JP, Barcelos J (2001) Plastic ingestion by a leatherback turtle Dermochelys coriacea from the Azores (NE Atlantic). Mar Pollut Bull 42:1196–1197PubMedCrossRef
13.
Pathania D, Kalia R (2012) Graft copolymerization of acrylic acid onto gelatinized patato starch for removal of metal ions and organic dyes from aqueous system. Adv Mater Lett 3:259–264CrossRef
14.
Carraher CE Jr (2017) Introduction to polymer chemistry. CRC Press, Boca RatonCrossRef
15.
Kim MN, Lee AR (1999) Effect of surface roughness on biodegradability of Poly (3-hydroxybutyrate). Korean J Environ Biol 17:249–255
16.
Negi H, Kapri A, Zaidi GH, Satlewal A, Goel R (2009) Comparative in-vitro biodegradation studies of epoxy and its silicone blend by selected microbial consortia. Int Biodeterior Biodegradation 63:553–558CrossRef
17.
Shi R, Bi J, Zhang Z, Zhu A, Chen D, Zhou X, Tian W (2008) The effect of citric acid on the structural properties and cytotoxicity of the polyvinyl alcohol/starch films when molding at high temperature. Carbohydr Polym 74(4):763–770CrossRef
18.
Gu SY, Zhang K, Ren J, Zhan H (2008) Melt rheology of polylactide/poly (butylene adipate-co-terephthalate) blends. Carbohydr Polym 74:79–85CrossRef
19.
Yang KK, Wang XL, Wang YZ (2007) Progress in nanocomposite of biodegradable polymer. Ind Eng Chem Res 13:485–500
20.
Fabra MJ, Busolo MA, Lopez-Rubio A, Lagaron JM (2013) Nanostructured biolayers in food packaging. Trends Food Sci Technol 31:79–87CrossRef
21.
Malina D, Sobczak-Kupiec A, Wzorek Z, Kowalski Z (2012) Silver nanoparticles synthesis with different concentrations of polyvinylpyrrolidone. Dig J Nanomater Biostruct 7:1527–1534
22.
Uddin M, Rahman M, Rukanuzzaman M, Islam M (2017) A potential low cost adsorbent for the removal of cationic dyes from aqueous solutions. Appl Water Sci 7:2831–2842CrossRef
23.
Jiang Y, Liu B, Xu J, Pan K, Hou H, Hu J, Yang J (2018) Cross-linked chitosan/β-cyclodextrin composite for selective removal of methyl orange: adsorption performance and mechanism. Carbohydr Polym 182:106–114PubMedCrossRef
24.
Guleria A, Kumari G, Lima EC (2020) Cellulose-g-poly-(acrylamide-co-acrylic acid) polymeric bioadsorbent for the removal of toxic inorganic pollutants from wastewaters. Carbohydr Polym 228:115396PubMedCrossRef
25.
Sivakumar R, Lee NY (2022) Adsorptive removal of organic pollutant methylene blue using polysaccharide-based composite hydrogels. Chemosphere 286:131890PubMedCrossRef
26.
Kong W, Chang M, Zhang C, Liu X, He B, Ren J (2019) Preparation of Xylan-G-/P (AA-co-AM)/GO nanocomposite hydrogel and its adsorption for heavy metal ions. Polymers 11:621PubMedPubMedCentralCrossRef
27.
28.
Xu R, Jia M, Zhang Y, Li F (2012) Sorption of malachite green on vinyl-modified mesoporous poly (acrylic acid)/SiO2 composite nanofiber membranes. Micropor Mesopor Mat 149:111–118CrossRef
29.
Yuan Z, Wang J, Wang Y, Liu Q, Zhong Y, Wang Y, Guo X (2019) Preparation of a poly (acrylic acid) based hydrogel with fast adsorption rate and high adsorption capacity for the removal of cationic dyes. RSC Adv 9:21075–21085PubMedPubMedCentralCrossRef
30.
He Y, Bao W, Hua Y, Guo Z, Fu X, Na B, Liu H (2022) Efficient adsorption of methyl orange and methyl blue dyes by a novel triptycene-based hyper-crosslinked porous polymer. RSC adv 19:5587–5594CrossRef
31.
Sultan M, Nagieb ZA, El-Masry HM, Taha GM (2022) Physically-crosslinked hydroxyethyl cellulose-g-poly (acrylic acid-co-acrylamide)-Fe3+/silver nanoparticles for water disinfection and enhanced adsorption of basic methylene blue dye. Int J Biol Macromol 196:180–193PubMedCrossRef
32.
Abdelhamid AE, Kandil H (2022) Facile approach to synthesis super-adsorptive hydrogel based on hyperbranched polymer for water remediation from methylene blue. React Funct Polym 177:105312CrossRef
33.
Alibak AH, Khodarahmi M, Fayyazsanavi P, Alizadeh SM, Hadi AJ, Aminzadehsarikhanbeglou E (2022) Simulation the adsorption capacity of polyvinyl alcohol/carboxymethyl cellulose based hydrogels towards methylene blue in aqueous solutions using cascade correlation neural network (CCNN) technique. J Clean Prod 337:130509CrossRef
34.
Chandran M, Asyraf Wan Mahmood WM, Omar FN, Lazim AM (2022) Removal of methylene blue from aqueous solution using modified polystyrene-calixarene (PS-C) composite. WAT AIR AND SOIL POLL 233:1–11CrossRef
35.
Chen Y, Li Q, Li Y, Zhang Q, Huang J, Wu Q, Wang S (2020) Fabrication of cellulose nanocrystal-g-poly (acrylic acid-co-acrylamide) aerogels for efficient Pb (II) removal. Polymers 12:333PubMedPubMedCentralCrossRef
36.
Tian H, Zhou H, Fu H, Li X, Gong W (2020) Enhanced electrical and dielectric properties of plasticized soy protein bioplastics through incorporation of nanosized carbon black. Polym Compos 41:5246–5256CrossRef
37.
Jiménez-Rosado M, Alonso-González M, Rubio-Valle JF, Perez-Puyana V, Romero A (2020) Biodegradable soy protein-based matrices for the controlled release of zinc in horticulture. J Appl Polym Sci 137:49187CrossRef
38.
Ranjbarha Z, Aliabad JM, Aberoomand-Azar P, Mirmohammadi SA, Saber-Tehrani M (2021) Effective Adsorptive Removal of Methylene Blue from Water Using Wood-Plastic Composite Containing High Density Polyethylene and Wood Particles.
39.
Gök MK, Özgümüş S, Demir K, Cirit Ü, Pabuccuoğlu S, Cevher E, Bacınoğlu S (2016) Development of starch based mucoadhesive vaginal drug delivery systems for application in veterinary medicine. Carbohydr Polym 136:63–70PubMedCrossRef
40.
Liufu SC, Xiao HN, Li YP (2005) Thermal analysis and degradation mechanism of polyacrylate/ZnO nanocomposites. Polym Degrad Stab 87:103–110CrossRef
41.
Soleimani F, Sadeghi M, Shahsavari H (2012) Graft copolymerization of gelatin-g-poly (acrylic acid-co-acrylamide) and calculation of grafting parameters. Indian J Sci Technol 5:2041–2046CrossRef
42.
Turco R, Zannini D, Mallardo S, Dal Poggetto G, Tesser R, Santagata G, Di Serio M (2021) Biocomposites based on poly (lactic acid), Cynara Cardunculus seed oil and fibrous presscake: a novel eco-friendly approach to hasten PLA biodegradation in common soil. Polym Degrad Stab 188:109576CrossRef
43.
Surip SN, Wan Jaafar WNR, Azmi NN, Anwar UMK (2012) Microscopy observation on nanocellulose from kenaf fibre. Open J Adv Mater Res 488:72–75CrossRef
44.
Matavuly M, Molitoris HP (2016) In vitro degradation of poly [(r)-3-hydroxybutyrate] and BIOPOL™ by marine-derived fungi. Biologia Serbica 37:1–2
45.
Maruthapandi M, Kumar VB, Luong JH, Gedanken A (2018) Kinetics, isotherm, and thermodynamic studies of methylene blue adsorption on polyaniline and polypyrrole macro–nanoparticles synthesized by C-dot-initiated polymerization. ACS Omega 3:7196–7203PubMedPubMedCentralCrossRef
46.
Ayad MM, El-Nasr AA, Stejskal J (2012) Kinetics and isotherm studies of methylene blue adsorption onto polyaniline nanotubes base/silica composite. Ind Eng Chem Res 18:1964–1969CrossRef
47.
Minisy IM, Salahuddin NA, Ayad MM (2019) Chitosan/polyaniline hybrid for the removal of cationic and anionic dyes from aqueous solutions. J Appl Polym Sci 136:47056CrossRef
48.
Iqbal S, Nadeem S, Javed M, Alsaab HO, Awwad NS, Ibrahium HA, Mohyuddin A (2022) Controlled preparation of grafted starch modified with Ni nanoparticles for biodegradable polymer nanocomposites and its application in food packaging. MRT 85:2331–2337
49.
Karimi M, Biria D (2019) The promiscuous activity of alpha-amylase in biodegradation of low-density polyethylene in a polymer-starch blend. Sci Rep 9:1–10CrossRef
50.
Gull N, Islam A, Ghaffar A, Jabeen S, Iqbal SS, Khan SM, Bilal M (2021) Development and characterization of chitosan and acrylic acid-based novel biodegradable polymeric films for soil conditioning. Int J Biol Macromol 182:950–958PubMedCrossRef
51.
Ahmad K, Shah HR, Ahmad M, Ahmed M, Naseem K, Riaz N, Ahmad Z (2022) Comparative study between two zeolitic imidazolate frameworks as adsorbents for removal of organoarsenic, As (III) and As (V) species from water. Braz J Anal Chem 9:78–97CrossRef
52.
Ahmad K, Khan MS, Iqbal A, Potrich E, Amaral LS, Rasheed S, Ashfaq M (2022) Lead In drinking water: adsorption method and role of zeolitic imidazolate frameworks for its remediation: A review. J Clean Pro 368:133010CrossRef
53.
Fallatah AM, Shah HUR, Ahmad K, Ashfaq M, Rauf A, Muneer M, Babras A (2022) Rational synthesis and characterization of highly water stable MOF@ GO composite for efficient removal of mercury (Hg2+) from water. Heliyon 8:e10936PubMedPubMedCentralCrossRef
54.
Naseem K, Ali F, Tahir MH, Afaq M, Yasir HM, Ahmed K, Habila MA (2022) Investigation of catalytic potential of sodium dodecyl sulfate stabilized silver nanoparticles for the degradation of methyl orange dye. J Mol Struct 1262:132996CrossRef
55.
Jayaramudu T, Pyarasani RD, Akbari-Fakhrabadi A, Abril-Milan D, Amalraj J (2021) Synthesis of gum acacia capped polyaniline-based nanocomposite hydrogel for the removal of methylene blue dye. J Polym Environ 29:2447–2462CrossRef
56.
Singh J, Dhaliwal AS (2021) Effective removal of methylene blue dye using silver nanoparticles containing grafted polymer of guar gum/acrylic acid as novel adsorbent. J Polym Environ 29:71–88CrossRef
57.
Yan B, Chen Z, Cai L, Chen Z, Fu J, Xu Q (2015) Fabrication of polyaniline hydrogel: synthesis, characterization and adsorption of methylene blue. Appl Surf Sci 356:39–47CrossRef
58.
Ren F, Li Z, Tan WZ, Liu XH, Sun ZF, Ren PG, Yan DX (2018) Facile preparation of 3D regenerated cellulose/graphene oxide composite aerogel with high-efficiency adsorption towards methylene blue. J Colloid Interface Sci 532:58–67PubMedCrossRef
59.
Aoopngan C, Nonkumwong J, Phumying S, Promjantuek W, Maensiri S, Noisa P, Srisombat L (2019) Amine-functionalized and hydroxyl-functionalized magnesium ferrite nanoparticles for Congo red adsorption. ACS Appl Nano Mater 2(8):5329–5341CrossRef
60.
Labena A, Abdelhamid AE, Husien S, Youssef T, Azab E, Gobouri AA, Safwat G (2021) Grafting of acrylic membrane prepared from fibers waste for dyes removal: methylene blue and Congo red. Separations 8(4):42CrossRef
61.
Abdelhamid AE, El-Sayed AA, Khalil AM (2020) Polysulfone nanofiltration membranes enriched with functionalized graphene oxide for dye removal from wastewater. J Polym Eng 40(10):833–841CrossRef
Metadata
Title
Development of biodegradable vinyl acetate and acrylic acid grafted gelatin copolymer for dye adsorption
Authors
Muhammad Amjad
Ayesha Mohyuddin
Sohail Nadeem
Wajad Ulfat
Shagufta Saeed
Nadeem Asghar
Saeed Ahmed
Publication date
06-04-2023
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 2/2024
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-023-04782-w

Other articles of this Issue 2/2024

Polymer Bulletin 2/2024 Go to the issue

ORIGINAL PAPER

Synthesis of novel antibacterial grafted sodium alginate copolymer-based adsorbent for wastewater treatment

REVIEW PAPER

Recent advances in carbohydrate-based paclitaxel delivery systems

ORIGINAL PAPER

Polylactic acid/poly(butylene adipate-co-terephthalate)/diatomite composites with antimicrobial properties for green packing

ORIGINAL PAPER

Preparation of carrageenan/konjac glucomannan/graphene oxide nanocomposite films with high mechanical and antistatic properties for food packaging

ORIGINAL PAPER

Emerging hybrid particle-reinforced high-density polyethylene nanocomposite for bone replacement

ORIGINAL PAPER

Hydrophobic modification of cellulose from oil palm waste in aqueous medium

Premium Partners

    Image Credits