Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Topics in Catalysis
Published in: Topics in Catalysis 15-16/2017

10-04-2017 | Original Paper

Development of Silver Based Catalysts Promoted by Noble Metal M (M = Au, Pd or Pt) for Glycerol Oxidation in Liquid Phase

Authors: Soraya Zaid, Elżbieta Skrzyńska, Ahmed Addad, Shreya Nandi, Louise Jalowiecki-Duhamel, Jean-Sebastien Girardon, Mickaël Capron, Franck Dumeignil

Published in: Topics in Catalysis | Issue 15-16/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The liquid-phase oxidation of glycerol was studied to obtain glycolic acid as a value-added molecule. The effect of metal addition to silver based catalyst was investigated under strong basic condition. The best catalytic performance was obtained over silver catalyst promoted with a small amount of platinum Ag95–Pt5/CeO2. Namely, the conversion close to 54% was reached after 5 h of reaction at 60 °C, with the selectivity to glycolic acid of 51%. Further increase in the amount of promotor (up to 50%) changed the reaction mechanism to product selectively the glyceric acid.

Graphical Abstract

previous article Deactivation of CuZn Catalysts Used in Glycerol Hydrogenolysis to Obtain 1,2-Propanediol
next article Influence of a Zeolite-Based Cascade Layer on Fischer–Tropsch Fuels Production over Silicon Carbide Supported Cobalt Catalyst

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Appendix
Available only for authorised users
Literature
1.
Bozell J, Petersen GR (2010) Technology development for the production of biobased products from biorefinery carbohydrates - The US department of Energy’s “Top 10” revisited. Green Chem 12:539–554CrossRef
2.
Katryniok B, Kimura H, Skrzyńska E, Girardon J-S, Fongarland P, Capron M, Ducoulombier R, Mimura N, Paul S, Dumeignil F (2011) Selective catalytic oxidation of glycerol: perspectives for high value chemicals. Green Chem 13:1960–1979CrossRef
3.
Skrzyńska E, Zaid S, Girardon J-S, Capron M, Dumeignil F (2015) Catalytic behaviour of four different supported noble metals in the crude glycerol oxidation. Appl Catal A 499:89–100CrossRef
4.
Bianchi CL, Canton P, Dimitratos N, Porta F, Prati L (2005) Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals. Catal Today 102–103:203–212CrossRef
5.
Mallat T, Baiker A (2004) Oxidation of alcohols with molecular oxygen on solid catalysts. Chem Rev 104:3037–3058CrossRef
6.
Duhamel L, Fang W, Paul S, Dumeignil F (2014) Method Prod Hydrogen FR3000737(A1)
7.
Skrzyńska E, Zaid S, Addad A, Girardon J.-S, Capron M, Dumeignil F (2016) Performance of Ag/Al2O3 catalysts in the liquid phase oxidation of glycerol—effect of preparation method and reaction conditions. Catal Sci Technol 6:3182–3196CrossRef
8.
Mott D, Mai NT, Thuy NTB, Sakata T, Higashimine K, Koyano M, Maenosono S (2011) Elucidation of the complex structure of nanoparticles composed of bismuth, antimony, and tellurium using scanning transmission microscopy. J Phys Chem C 11:17334–17340CrossRef
9.
Skrzyńska E, Wondołowska-Grabowska A, Capron M, Dumeignil F (2014) Crude glycerol as a raw material for the liquid phase oxidation reaction. Appl Catal A 482:245–257CrossRef
10.
Pelletier F (2012) Synthèse et étude de nanomatériaux hybrides magnétiques à base Fer-Bismuth. Thése de doctorat de l’université de Toulouse
11.
Sankar M, Dimitratos N, Miedziak PJ, Wells PP, Kiely CJ, Hutchings GJ (2012) Designing bimetallic catalysts for a green and sustainable future. Chem Soc Rev 41:8099–8139CrossRef
12.
Skrzyńska E, Ftouni J, Mamede A-S, Addad A, Trentesaux M, Girardon J-S, Capron M, Dumeignil F (2014) Glycerol oxidation over gold supported catalysts—“Two faces” of sulphur based anchoring agent. J Mol Catal A 382:71–78CrossRef
13.
Dimitratos N, Porta F, Prati L (2005) Au, Pd (mono and bimetallic) catalysts supported on graphite using the immobilisation method: synthesis and catalytic testing for liquid phase oxidation of glycerol. Appl Catal A 291:210–214CrossRef
14.
Cook MM, Lander JA (1979) Use of Sodium borohydride to control heavy metal discharge in the photographic industry. J Appl Photogr Eng 5:144–147
15.
Ding RG, Yan ZF (2002) Adsorption properties studies of the nickel catalysts for carbon dioxide reforming of methane. Fuel Chem Div Preprints 47:103–105.
16.
Stathatos E, Lianos P, Falaras P, Siokou A (2000) Photocatalytically deposited silver nanoparticles on mesoporous TiO2 films. Langmuir 16:2398–2400CrossRef
17.
Zhang G, Du M, Li Q, Li X, Huang J, Jianga X, Sun D (2013) Green synthesis of Au–Ag alloy nanoparticles using Cacumen platycladi extract. RSC Adv 3:1878–1884CrossRef
18.
Kiinig U, Marksteiner P, Redinger J, Weinberger P (1986) A theoretical study of X-Ray photoemission spectra (XPS) of some noble metal alloys: Au/Pt, Ag/Au, Ag/Pt and Au/Ni. Z Phys B 65:139–114CrossRef
19.
Nascente PA, de Castro SG, Landers R, Kleiman GG (1991) X-ray photoemission and Auger energy shifts in some gold-palladium alloys. Phys Rev B 43:4659–4666CrossRef
20.
21.
Zhou X, Zheng L, Li R, Li B, Pillai S, Xu P, Zhang Y (2012) Biotemplated fabrication of size controlled palladium nanoparticle chains. J Mater Chem 22:8862–8867CrossRef
22.
Yue B, Ma Y, Tao H, Yu L, Jian G, Wang X, Wang X, Lu Y, Hu Z (2008) CNx nanotubes as catalyst support to immobilize platinum nanoparticles for methanol oxidation. J Mater Chem 18:1747–1750CrossRef
23.
Xu J, Liu X, Chen Y, Zhou Y, Lu T, Tang Y (2012) Tang. Platinum–Cobalt alloy networks for methanol oxidation electrocatalysis. J Mater Chem 22:23659–23667CrossRef
24.
Lu Z, Yang Z (2010) Interfacial properties of NM/CeO2 (111) (NM = noble metal atoms or clusters of Pd, Pt and Rh): a first principles study. J Phys Condens Matter 22:p. 475003-1-10
Metadata
Title
Development of Silver Based Catalysts Promoted by Noble Metal M (M = Au, Pd or Pt) for Glycerol Oxidation in Liquid Phase
Authors
Soraya Zaid
Elżbieta Skrzyńska
Ahmed Addad
Shreya Nandi
Louise Jalowiecki-Duhamel
Jean-Sebastien Girardon
Mickaël Capron
Franck Dumeignil
Publication date
10-04-2017
Publisher
Springer US
Published in
Topics in Catalysis / Issue 15-16/2017
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-017-0800-6

Other articles of this Issue 15-16/2017

Topics in Catalysis 15-16/2017 Go to the issue

Original Paper

Structure and Reactivity of sol–gel V/SiO2 Catalysts for the Direct Conversion of Methane to Formaldehyde

Original Paper

Sustainable Desulfurization Processes Catalyzed by Titanium-Polyoxometalate@TM-SBA-15

Original Paper

Exploring the Redox Behavior of La0.6Sr0.4Mn1−xAlxO3 Perovskites for CO2-Splitting in Thermochemical Cycles

Original Paper

Influence of the Reduction of Graphene Oxide with Hydroiodic Acid on the Structure and Photoactivity of CdS–rGO Hybrids

Original Paper

Comparison of the Activity of Pd–M (M: Ag, Co, Cu, Fe, Ni, Zn) Bimetallic Electrocatalysts for Oxygen Reduction Reaction

Original Paper

Hydrogen Production from Aqueous Solutions of Glycerol on TiO2/Ru-MCM-41 Photocatalysts Using Solar Light

Premium Partners

    Image Credits