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Journal of Materials Science
Published in: Journal of Materials Science 24/2020

12-05-2020 | Chemical routes to materials

Development of the hierarchical ETS-10 zeolite catalyst for improving the aqueous-phase biomass hydrodeoxygenation activity

Authors: Mei Xiang, Fen Zhang, Linchang Tong, Huaqin Wang, Yalong Ding, Wei Zhang, Zeying Wu, Zhenwei Zhang, Xuejiao Wei, Fuhua Jiang, Yaoyao Deng

Published in: Journal of Materials Science | Issue 24/2020

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Abstract

An imidazolium-based ionic liquid (IL) was employed and modified by sodium lignosulfonate (LnNa) to synthesize hierarchical ETS-10 zeolite with porous structure, morphology and surface properties effectively adjusted. The template and structure-directing effects of both IL and LnNa proved to be well maintained after modification. And more importantly, the unique molecular recognition of LnNa was preserved well, while the aggressiveness of LnNa implementing through interaction with other inorganic species can be efficiently suppressed. This led to the formation of hierarchical ETS-10 zeolite with not only high crystallinity and structure integrity but also enhanced catalytic performance in aqueous-phase biomass conversion. Thus, for guaiacol hydrodeoxygenation, a notable conversion (92.8%) and cyclohexane yield (89.7%) can be acquired. This remarkable catalytic reactivity should be owing to its distinguished analogous molecular recognition pattern, promoted crystallinity, modified morphology and porous structure, and what’s more, the strengthened acid property.
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Literature
1.
Moss RH, Edmonds JA, Hibbard KA, Manning MR, Rose SK, van Vuuren DP, Carter TR, Emori S, Kainuma M, Kram T, Meehl GA, Mitchell JFB, Nakicenovic N, Riahi K, Smith SJ, Stouffer RJ, Thomson AM, Weyant JP, Wilbanks TJ (2010) The next generation of scenarios for climate change research and assessment. Nature 463:747–756
2.
Hertzog J, Carré V, Jia LY, Mackay CL, Pinard L, Dufour A, Mašek O, Aubriet F (2018) Catalytic fast pyrolysis of biomass over microporous and hierarchical zeolites: Characterization of heavy products. ACS Sustain Chem Eng 6:4717–4728
3.
Dusselier M, Mascal M, Sels BF (2014) Selective catalysis for renewable feedstocks and chemicals, topics in current chemistry. In: Nicholas KM (Ed) Springer, Berlin, vol 353 (544), pp 1–40
4.
Kabir G, Hameed BH (2017) Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals. Renew Sust Energ Rev 70:945–967
5.
Shu RY, Lin BQ, Wang C, Zhang JT, Cheng ZD, Chen Y (2019) Upgrading phenolic compounds and bio-oil through hydrodeoxygenation using highly dispersed Pt/TiO2 catalyst. Fuel 239:1083–1090
6.
Ennaert T, Aelst J, Dijkmans J, Clercq R, Schutyser W, Dusselier M, Verboekend D, Sels BF (2016) Potential and challenges of zeolite chemistry in the catalytic conversion of biomass. Chem Soc Rev 45:584–611
7.
Weckhuysen BM, Yu JH (2015) Recent advances in zeolite chemistry and catalysis. Chem Soc Rev 44:7022–7024
8.
Bereciartua PJ, Cantín Á, Corma A, Jordá JL, Palomino M, Rey F, Valencia S, Corcoran JEW, Kortunov P, Ravikovitch PI, Burton A, Yoon C, Wang Y, Paur C, Guzman J, Bishop AR, Casty GL (2017) Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene. Science 358:1068–1071
9.
Jeon MY, Kim D, Kumar P, Lee PS, Rangnekar N, Bai P, Shete M, Elyassi B, Lee HS, Narasimharao K, Basahel SN, Al-Thabaiti S, Xu WQ, Cho HJ, Fetisov EO, Thyagarajan R, DeJaco RF, Fan W, Mkhoyan KA, Siepmann JI, Tsapatsis M (2017) Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets. Nature 543:690–694
10.
Zhang J, Wang L, Shao Y, Wang YQ, Gates BC, Xiao FS (2017) Catalyst for nitroarene hydrogenation with high product selectivity by sterically controlled adsorption in the zeolite micropores. Angew Chem 129:9879–9883
11.
Přech J, Pizarro P, Serrano DP, Čejka J (2018) From 3D to 2D zeolite catalytic materials. Chem Soc Rev 47:8263–8306
12.
Said S, Elhossieny M, Riad M, Mikhail S (2018) Pristine Cu (Co)/Fe layered double hydroxides (Co(Cu)/Fe-LDH) as active catalysts for the transalkylation of toluene to trimethylbenzenes. Mol Catal 46:213–222
13.
Qin ZX, Cychosz KA, Melinte G, Siblani HE, Gilson JP, Thommes M, Fernandez C, Mintova S, Ersen O, Valtchev V (2017) Opening the cages of faujasite-type zeolite. J Am Chem Soc 139:17273–17276
14.
Blay V, Louis B, Miravalles R, Yokoi T, Peccatiello KA, Clough M, Yilmaz B (2017) Engineering zeolites for catalytic cracking to light olefins. ACS Catal 7:6542–6566
15.
Zhang L, Dai Q, Fu WQ, Tang TD, Dong PX, He MY, Chen Q (2018) CoMo catalyst on zeolite TS-1 nanorod assemblies with high activity in the hydrodesulfurization of 4,6-dimethyldibenzothiophene. J Catal 359:130–142
16.
Tanimu G, Asaoka S, Al-Khattaf S (2017) Effect of support in Ni-Bi-O/support catalyst on oxidative dehydrogenation of n-butane to butadiene. Mol Catal 438:245–255
17.
Serrano DP, Melero JA, Morales G, Iglesias J, Pizarro P (2018) Progress in the design of zeolite catalysts biomass conversion into biofuels and bio-based chemicals. Catal Rev 60:1–70
18.
Tu CY, Chen JW, Li WL, Wang HY, Deng KX, Vinokurov VA, Huang W (2019) Hydrodeoxygenation of bio-derived anisole to cyclohexane over bi-functional IM-5 zeolite supported Ni catalysts. Sustain Energ Fuels 3:3462–3472
19.
20.
21.
Li JY, Corma A, Yu JH (2015) Synthesis of new zeolite structures. Chem Soc Rev 44:7112–7127
22.
Song S, Di L, Wu GJ, Dai WL, Guan NJ, Li LD (2017) Meso-Zr-Al-beta zeolite as a robust catalyst for cascade reactions in biomass valorization. Appl Catal B Environ 205:393–403
23.
Čejka J, Nachtigall P, Centi G (2018) New catalytic materials for energy and chemistry in transition. Chem Soc Rev 47:8066–8071
24.
Xiang M, Liu JN, Fu WQ, Tang TD, Wu DF (2017) Improved activity for cellulose conversion to levulinic acid through hierarchization of ETS-10 zeolite. ACS Sustain Chem Eng 5:5800–5809
25.
Ni XJ, Xiang M, Fu WQ, Ma YL, Zhu PY, Wang WC, He MY, Yang KQ, Xiong J, Tang TD (2016) Direct synthesis of mesoporous zeolite ETS-10 with good catalytic performance in the knoevenagel reaction. J Porous Mater 23:423–429
26.
Xiang M, Ni XJ, Yi XF, Zheng A, Wang WC, He MY, Xiong J, Liu TT, Ma YL, Zhu PY, Zheng X, Tang TD (2015) Preparation of mesoporous zeolite ETS-10 catalysts for high-yield synthesis of α, β-epoxy ketones. Chemcatchem 7:521–525
27.
Xiang M, Wu DF (2019) Facile preparation of pore- and morphology-controllable ETS-10 zeolite with enhanced biomass hydrogenation activity. Chem Eng J 369:180–194
28.
Welton T (1999) Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem Rev 99:2071–2084
29.
Hayes R, Warr GG, Atkin R (2015) Structure and nanostructure in ionic liquids. Chem Rev 115:6357–6426
30.
Amarasekara AS (2016) Acidic ionic liquids. Chem Rev 116:6133–6183
31.
Lei ZG, Chen BH, Koo Y-M, MacFarlane DR (2017) Introduction: Ionic liquids. Chem Rev 117:6633–6635
32.
MacFarlane DR, Forsyth M, Howlett PC, Kar M, Passerini S, Pringle JM, Ohno H, Watanabe M, Yan F, Zheng WJ, Zhang SG, Zhang J (2016) Ionic liquids and their solid-state analogues as materials for energy generation and storage. Nat Rev Mater 1:1–15
33.
Greaves TL, Drummond CJ (2016) Protic ionic liquids: evolving structure-property relationships and expanding applications. Chem Rev 115:11379–11448
34.
Costa Lopes AM, Bogel-Łukasik R (2015) Acidic ionic liquids as sustainable approach of cellulose and lignocellulosic biomass conversion without additional catalysts. Chemsuschem 8:947–965
35.
Mourad E, Coustan L, Lannelongue P, Zigah D, Mehdi A, Vioux A, Freunberger SA, Favier F, Fontaine O (2017) Biredox ionic liquids with solid-like redox density in the liquid state for high-energy supercapacitors. Nat Mater 16:446–453
36.
37.
Itoh T (2017) Ionic liquids as tool to improve enzymatic organic synthesis. Chem Rev 117:10567–10607
38.
Oncsik T, Vijayaraghavan R, MacFarlane DR (2018) High CO2 absorption by diamino protic ionic liquids using azolide anions. Chem Commun 54:2106–2109
39.
Wang CH, Hashimoto K, Tamate R, Kokubo H, Watanabe M (2018) Controlled sol-gel transitions of a thermoresponsive polymer in a photoswitchable azobenzene ionic liquid as a molecular trigger. Angew Chem Int Ed 57:227–230
40.
Egorova KS, Gordeev EG, Ananikov VP (2017) Biological activity of ionic liquids and their application in pharmaceutics and medicine. Chem Rev 117:7132–7189
41.
Cooper ER, Andrews CD, Wheatley PS, Webb PB, Wormald P, Morris RE (2004) Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues. Nature 430:1012–1016
42.
Chen L, Sharifzadeh M, Mac Dowell N, Welton T, Shahc N, Hallett JP (2014) Inexpensive ionic liquids: [HSO4]–based solvent production at bulk scale. Green Chem 16:3098–3106
43.
Kang XC, Sun XF, Han BX (2016) Synthesis of functional nanomaterial in ionic liquids. Adv Mater 28:1011–1030
44.
Smiglak M, Pringle JM, Lu X, Han L, Zhang S, Gao H, MacFarlane DR, Rogers RD (2014) Ionic liquids for energy, materials, and medicine. Chem Commun 50:9228–9250
45.
Elfgen R, Hollóczki O, Kirchner B (2017) A molecular level understanding of template effects in ionic liquids. Acc Chem Res 50:2949–2957
46.
Dai CN, Zhang J, Huang CP, Lei ZG (2017) Ionic liquids in selective oxidation: catalysts and solvents. Chem Rev 117:6929–6983
47.
Adams CJ, Radley AEB, Seddon KR (2001) Rapid communication: the synthesis of mesoporous materials using novel ionic liquid templates in water. Aust J Chem 54:679–681
48.
Blanes JMM, Szyja BM, Romero-Sarria F, Centeno MA, Hensen EJM, Odriozola JA, Ivanova S (2013) Multiple zeolite structures from one ionic liquid template. Chem Eur J 19:2122–2130
49.
Sachse A, García-Martínez J (2017) Surfactant-templating of zeolites: from design to application. Chem Rev 29:3827–3853
50.
51.
Faroldi B, Irusta S, Cornaglia L (2015) Influence of La incorporation on the catalytic activity of Ru/ETS-10 catalysts for hydrogen production. Appl Catal A Gen 504:391–398
52.
Surolia PK, Tayade RJ, Jasra RV (2010) Photocatalytic degradation of nitrobenzene in an aqueous system by transition-metal-exchanged ETS-10 zeolites. Ind Eng Chem Res 49:3961–3966
53.
Lv L, Zhou JK, Su F, Zhao XS (2007) Local structure changes of microporous titanosilicate ETS-10 upon acid treatment. J Phys Chem C 111:773–778
54.
Lu MH, Du H, Wei B, Zhu J, Li MS, Shan YH, Song CS (2017) Catalytic hydrodeoxygenation of guaiacol over palladium catalyst on different titania supports. Energy Fuels 31:10858–10865
55.
Baddour FG, Witte VA, Nash CP, Griffin MB, Ruddy DA, Schaidle JA (2017) Late-transition-metal-modified β-Mo2C catalysts for enhanced hydrogenation during guaiacol deoxygenation. ACS Sustainable Chem Eng 5:11433–11439
56.
57.
Zhang XH, Tang WW, Zhang Q, Wang TJ, Ma LL (2018) Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts. Appl Energy 227:73–79
58.
Jahromi H, Agblevor FA (2018) Hydrotreating of guaiacol: a comparative study of red mud-supported nickel and commercial Ni/SiO2-Al2O3 catalysts. Appl Catal A: Gen 558:109–121
Metadata
Title
Development of the hierarchical ETS-10 zeolite catalyst for improving the aqueous-phase biomass hydrodeoxygenation activity
Authors
Mei Xiang
Fen Zhang
Linchang Tong
Huaqin Wang
Yalong Ding
Wei Zhang
Zeying Wu
Zhenwei Zhang
Xuejiao Wei
Fuhua Jiang
Yaoyao Deng
Publication date
12-05-2020
Publisher
Springer US
Published in
Journal of Materials Science / Issue 24/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04785-2

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