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Journal of Materials Science
Published in: Journal of Materials Science 24/2020

11-05-2020 | Chemical routes to materials

Effect of Nb on catalyst nanoparticle sizes and catalytic activities of H2O2-mediated oxidative dehydrogenation of Cα–OH lignin model compounds

Authors: Kun Hao, Lu-Lu Zhang, Liang Song, Chang-Ming Li, Han-Yang Guan, Tong Liu, Qing Yu, Zhong-Wei Wang

Published in: Journal of Materials Science | Issue 24/2020

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Abstract

Nb-modified Mo–V–Nb tri-component oxides were synthesized for catalytic oxidative dehydrogenation of Cα–OH lignin model compounds. Nb–O octahedron as the nucleation center refined the Mo–V–Nb oxide particles with TiO2 as the support and changed the selective oxidation performance of the catalyst to a certain extent. However, the conversion of Cα–OH lignin model compounds was significantly reduced under the catalysis of Mo–V–Nb–O with too much Nb content. The experimental results showed that the effect of Nb in the three-component oxides not only reduced the crystal size of the catalyst, but also more importantly adjusted the valence state of vanadium. The valence state of vanadium in vanadyl octahedron formed based on Nb nucleation center was adjusted. The ratio between tetravalent vanadium and pentavalent vanadium was directly proportional to the conversion rate. The catalytic mechanism was that there were oxygen vacancies at the catalytic active sites of V4+, which provided a basis for the generation of reactive oxygen species in the oxidative dehydrogenation reaction.
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Appendix
Available only for authorised users
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Metadata
Title
Effect of Nb on catalyst nanoparticle sizes and catalytic activities of H2O2-mediated oxidative dehydrogenation of Cα–OH lignin model compounds
Authors
Kun Hao
Lu-Lu Zhang
Liang Song
Chang-Ming Li
Han-Yang Guan
Tong Liu
Qing Yu
Zhong-Wei Wang
Publication date
11-05-2020
Publisher
Springer US
Published in
Journal of Materials Science / Issue 24/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04783-4

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