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Colloid and Polymer Science

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16-09-2019 | Original Contribution

Effect of chain length and counter-ion on interaction study of mixed micellar system of isoquinoline-based surface active ionic liquid and cationic surfactants in aqueous medium

Authors: Amalendu Pal, Renu Punia

Published in: Colloid and Polymer Science | Issue 11-12/2019

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Abstract

In the present study, we have investigated the effect of nature of surfactant, chain length and counter-ion on the mixed micellization behaviour ofvarious cationic surfactants, tetradecyltrimethylammonium bromide (TTAB), dodecyltrimethylammonium chloride (DTAC) and cationic gemini surfactant, bis(tetradecyldimethylammonium)hexane dibromide(C14-6-C14,2Br) with surface active ionic liquid (SAIL) tetradecylisoquinolinium bromide [C₁₄iQuin][Br]. The interactions and mixed micellar behaviour of cationic surfactants and SAIL in aqueous medium have been studied by employing conductometry measurements and ¹H NMR technique. The critical micelle concentration (cmc) and various thermodynamic parameters like standard Gibbs free energy of micellization (ΔG_m⁰), change in standard enthalpy (ΔH_m⁰) and entropy of micellization (ΔS_m⁰) have been calculated from conductometry measurements. Mixed micellar parameters such as ideal cmc (cmc*), micellar mole fraction (X₁^m), micellar interaction parameter (β_m) and activity coefficients, (f₁ and f₂) have been evaluated by applying Clint, Rubingh and Motomura theoretical models. Synergistic and non-ideal interactions have been found between SAIL and surfactants.

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Title: Effect of chain length and counter-ion on interaction study of mixed micellar system of isoquinoline-based surface active ionic liquid and cationic surfactants in aqueous medium
Authors: Amalendu Pal
Renu Punia
Publication date: 16-09-2019
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 11-12/2019
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-019-04566-7

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