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Polymer Science, Series B
Published in: Polymer Science, Series B 2/2019

01-03-2019 | CATALYSIS

Effect of Diphenyl Ether in Ti-based Ternary Catalyst on Polymerization, Microstructure and Property of cis-1,4-Polyisoprene

Authors: Guanghong Lin, Hongping Xiang, Lu Xi, Zhixia Wen, Zhaowei Wang, Junwei Yu, Xiaoxuan Liu

Published in: Polymer Science, Series B | Issue 2/2019

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Abstract

A tricomponent catalyst comprising titanium tetrachloride, triisobutyl aluminum and diphenyl ether is developed for the highly cis-1,4-selective polymerization of isoprene. The influence of the content of diphenyl ether and its complexation order on polymerization, microstructure and performance of polyisoprene are studied. The polyisoprene synthesized presents high monomer conversion (91–99%). With the increasing of diphenyl ether content, intrinsic viscosity and viscosity-average molecular weight of polyisoprene increase. The molar percentage of cis-1,4-unit is almost unaffected by diphenyl ether and different complexation sequence. The polyisoprene reveals comparable Tg (–61.31°C) and mechanical strengths (11.14 MPa, 667%) to commercially available LHIR-80 synthesized with neodymium. However, the viscosity and viscosity-average molecular weight of the former are lower than that of the latter, which avails the processability and maintains excellent mechanical properties.
previous article Polymers Containing Azo and Azomethine Groups: Synthesis, Properties, and Application
next article Polymerization of Vinyl Monomers in the Presence of 4,6-Di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone

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Metadata
Title
Effect of Diphenyl Ether in Ti-based Ternary Catalyst on Polymerization, Microstructure and Property of cis-1,4-Polyisoprene
Authors
Guanghong Lin
Hongping Xiang
Lu Xi
Zhixia Wen
Zhaowei Wang
Junwei Yu
Xiaoxuan Liu
Publication date
01-03-2019
Publisher
Pleiades Publishing
Published in
Polymer Science, Series B / Issue 2/2019
Print ISSN: 1560-0904
Electronic ISSN: 1555-6123
DOI
https://doi.org/10.1134/S1560090419020052

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