Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 4/2020

20-04-2020

Effect of Graphene-Based Nanoadditives on the Tribological and Rheological Performance of Paraffin Grease

Authors: Sooraj Singh Rawat, A. P. Harsha, Ajay Chouhan, O. P. Khatri

Published in: Journal of Materials Engineering and Performance | Issue 4/2020

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The present study deals with tribological and rheological evaluations of paraffin grease having variable dosages (0.01-0.05 wt.%) of graphene oxide (GO), reduced graphene oxide (rGO), and octadecylamine-functionalized GO (GO-ODA). The microstructural and chemical characteristics of GO, rGO, and GO-ODA were analyzed by HRTEM, XRD, and FTIR. The graphene-based nanoadditives significantly improved the tribological properties between the steel tribo-pair by decreasing the wear and friction. The optimized dose of GO, rGO, and GO-ODA decreased the coefficient of friction (COF) by ~ 34.3, ~ 50.3, and ~ 34.3%, and wear volume by ~ 86.6, ~ 85.4, and ~ 80.9%, respectively. The friction reduction by GO, rGO, and GO-ODA nanoadditives conserved the energy by ~ 34.3, ~ 50.3, and ~ 34.4%, respectively. The spectroscopic and microscopic analyses of worn surfaces suggested the formation of graphene-based tribo-film, which facilitated the shearing under tribo-stress and protected the tribo-interfaces against the wear. The rheological results corroborate the roles of graphene-based nanoadditives and lube oil of grease under the tribo-stress, which is vital for the sustainability of tribo-film on the interacting surfaces. The graphene-based tribo-film reduced the friction, subsidized the wear, and conserved energy consumption.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference K. Akhtar, H. Khalid, I. Ul Haq, and A. Malik, Improvement in Tribological Properties of Lubricating Grease with Quartz-Enriched Rice Husk Ash, Tribol. Int., 2016, 93, p 58–62 K. Akhtar, H. Khalid, I. Ul Haq, and A. Malik, Improvement in Tribological Properties of Lubricating Grease with Quartz-Enriched Rice Husk Ash, Tribol. Int., 2016, 93, p 58–62
2.
go back to reference L. Wang, M. Zhang, X. Wang, and W. Liu, The Preparation of CeF3 Nanocluster Capped with Oleic Acid by Extraction Method and Application to Lithium Grease, Mater. Res. Bull., 2008, 43, p 2220–2227 L. Wang, M. Zhang, X. Wang, and W. Liu, The Preparation of CeF3 Nanocluster Capped with Oleic Acid by Extraction Method and Application to Lithium Grease, Mater. Res. Bull., 2008, 43, p 2220–2227
3.
go back to reference X. Ge, Y. Xia, and Z. Cao, Tribological Properties and Insulation Effect of Nanometer TiO2 and Nanometer SiO2 as Additives in Grease, Tribol. Int., 2015, 92, p 454–461 X. Ge, Y. Xia, and Z. Cao, Tribological Properties and Insulation Effect of Nanometer TiO2 and Nanometer SiO2 as Additives in Grease, Tribol. Int., 2015, 92, p 454–461
4.
go back to reference B.M. Kamel, A. Mohamed, M. El Sherbiny, and K.A. Abed, Tribological Behaviour of Calcium Grease Containing Carbon Nanotubes Additives, Ind. Lubr. Tribol., 2016, 68, p 723–728 B.M. Kamel, A. Mohamed, M. El Sherbiny, and K.A. Abed, Tribological Behaviour of Calcium Grease Containing Carbon Nanotubes Additives, Ind. Lubr. Tribol., 2016, 68, p 723–728
5.
go back to reference H. Xiao and S. Liu, 2D Nanomaterials as Lubricant Additive: A Review, Mater. Des., 2017, 135, p 319–332 H. Xiao and S. Liu, 2D Nanomaterials as Lubricant Additive: A Review, Mater. Des., 2017, 135, p 319–332
6.
go back to reference L. Wang, B. Wang, X. Wang, and W. Liu, Tribological Investigation of CaF2 Nanocrystals as Grease Additives, Tribol. Int., 2007, 40, p 1179–1185 L. Wang, B. Wang, X. Wang, and W. Liu, Tribological Investigation of CaF2 Nanocrystals as Grease Additives, Tribol. Int., 2007, 40, p 1179–1185
7.
go back to reference S.S. Rawat, A.P. Harsha, D.P. Agarwal, S. Kumari, and O.P. Khatri, Pristine and Alkylated MoS2 Nanosheets for Enhancement of Tribological Performance of Paraffin Grease under Boundary Lubrication Regime, J. Tribol., 2019, 141, p 072102–072112 S.S. Rawat, A.P. Harsha, D.P. Agarwal, S. Kumari, and O.P. Khatri, Pristine and Alkylated MoS2 Nanosheets for Enhancement of Tribological Performance of Paraffin Grease under Boundary Lubrication Regime, J. Tribol., 2019, 141, p 072102–072112
8.
go back to reference Q. He, A. Li, Y. Guo, S. Liu, Y. Zhang, and L. Kong, Tribological Properties of Nanometer Cerium Oxide as Additives in Lithium Grease, J. Rare Earths, 2018, 36, p 209–214 Q. He, A. Li, Y. Guo, S. Liu, Y. Zhang, and L. Kong, Tribological Properties of Nanometer Cerium Oxide as Additives in Lithium Grease, J. Rare Earths, 2018, 36, p 209–214
9.
go back to reference S.S. Rawat, A.P. Harsha, and A.P. Deepak, Tribological Performance of Paraffin Grease with Silica Nanoparticles as an Additive, Appl. Nanosci., 2019, 9, p 305–315 S.S. Rawat, A.P. Harsha, and A.P. Deepak, Tribological Performance of Paraffin Grease with Silica Nanoparticles as an Additive, Appl. Nanosci., 2019, 9, p 305–315
10.
go back to reference K. Kobayashi, S. Hironaka, A. Tanaka, K. Umeda, S. Iijima, M. Yudasaka, D. Kasuya, and M. Suzuki, Additive Effect of Carbon Nanohorn on Grease Lubrication Properties, J. Japan Pet. Inst., 2005, 48, p 121–126 K. Kobayashi, S. Hironaka, A. Tanaka, K. Umeda, S. Iijima, M. Yudasaka, D. Kasuya, and M. Suzuki, Additive Effect of Carbon Nanohorn on Grease Lubrication Properties, J. Japan Pet. Inst., 2005, 48, p 121–126
11.
go back to reference L. Hongtao, J. Hongmin, H. Haiping, and H. Younes, Tribological Properties of Carbon Nanotube Grease, Ind. Lubr. Tribol., 2014, 66, p 579–583 L. Hongtao, J. Hongmin, H. Haiping, and H. Younes, Tribological Properties of Carbon Nanotube Grease, Ind. Lubr. Tribol., 2014, 66, p 579–583
12.
go back to reference X. Ge, Y. Xia, and X. Feng, Influence of Carbon Nanotubes on Conductive Capacity and Tribological Characteristics of Poly(Ethylene Glycol-Ran-Propylene Glycol) Monobutyl Ether as Base Oil of Grease, J. Tribol., 2015, 138, p 11801–11806 X. Ge, Y. Xia, and X. Feng, Influence of Carbon Nanotubes on Conductive Capacity and Tribological Characteristics of Poly(Ethylene Glycol-Ran-Propylene Glycol) Monobutyl Ether as Base Oil of Grease, J. Tribol., 2015, 138, p 11801–11806
13.
go back to reference L. Peña-Parás, J. Taha-Tijerina, A. García, D. Maldonado, A. Nájera, P. Cantú, and D. Ortiz, Thermal Transport and Tribological Properties of Nanogreases for Metal-Mechanic Applications, Wear, 2015, 332–333, p 1322–1326 L. Peña-Parás, J. Taha-Tijerina, A. García, D. Maldonado, A. Nájera, P. Cantú, and D. Ortiz, Thermal Transport and Tribological Properties of Nanogreases for Metal-Mechanic Applications, Wear, 2015, 332–333, p 1322–1326
14.
go back to reference M.J. Nine, M.A. Cole, D.N.H. Tran, and D. Losic, Graphene: A Multipurpose Material for Protective Coatings, J. Mater. Chem. A., 2015, 3, p 12580–12602 M.J. Nine, M.A. Cole, D.N.H. Tran, and D. Losic, Graphene: A Multipurpose Material for Protective Coatings, J. Mater. Chem. A., 2015, 3, p 12580–12602
15.
go back to reference C. Gan, T. Liang, W. Li, X. Fan, and M. Zhu, Amine-Terminated Ionic Liquid Modified Graphene Oxide/Copper Nanocomposite Toward Efficient Lubrication, Appl. Surf. Sci., 2019, 491, p 105–115 C. Gan, T. Liang, W. Li, X. Fan, and M. Zhu, Amine-Terminated Ionic Liquid Modified Graphene Oxide/Copper Nanocomposite Toward Efficient Lubrication, Appl. Surf. Sci., 2019, 491, p 105–115
16.
go back to reference D. Berman, A. Erdemir, and A.V. Sumant, Graphene: A New Emerging Lubricant, Mater. Today, 2014, 17, p 31–42 D. Berman, A. Erdemir, and A.V. Sumant, Graphene: A New Emerging Lubricant, Mater. Today, 2014, 17, p 31–42
17.
go back to reference A. Chouhan, H.P. Mungse, O.P. Sharma, R.K. Singh, and O.P. Khatri, Chemically Functionalized Graphene for Lubricant Applications: Microscopic and Spectroscopic Studies of Contact Interfaces to Probe the Role of Graphene for Enhanced Tribo-Performance, J. Colloid Interface Sci., 2018, 513, p 666–676 A. Chouhan, H.P. Mungse, O.P. Sharma, R.K. Singh, and O.P. Khatri, Chemically Functionalized Graphene for Lubricant Applications: Microscopic and Spectroscopic Studies of Contact Interfaces to Probe the Role of Graphene for Enhanced Tribo-Performance, J. Colloid Interface Sci., 2018, 513, p 666–676
18.
go back to reference J. Lin, L. Wang, and G. Chen, Modification of Graphene Platelets and their Tribological Properties as a Lubricant Additive, Tribol. Lett., 2011, 41, p 209–215 J. Lin, L. Wang, and G. Chen, Modification of Graphene Platelets and their Tribological Properties as a Lubricant Additive, Tribol. Lett., 2011, 41, p 209–215
19.
go back to reference X. Fan and L. Wang, High-Performance Lubricant Additives Based on Modified Graphene Oxide by Ionic Liquids, J. Colloid Interface Sci., 2015, 452, p 98–108 X. Fan and L. Wang, High-Performance Lubricant Additives Based on Modified Graphene Oxide by Ionic Liquids, J. Colloid Interface Sci., 2015, 452, p 98–108
20.
go back to reference A.K. Rasheed, M. Khalid, W. Rashmi, T.C.S.M. Gupta, and A. Chan, Graphene Based Nanofluids and Nanolubricants: Review of Recent Developments, Renew. Sustain. Energy Rev., 2016, 63, p 346–362 A.K. Rasheed, M. Khalid, W. Rashmi, T.C.S.M. Gupta, and A. Chan, Graphene Based Nanofluids and Nanolubricants: Review of Recent Developments, Renew. Sustain. Energy Rev., 2016, 63, p 346–362
21.
go back to reference J. Singh, G. Anand, D. Kumar, and N. Tandon, Graphene Based Composite Grease for Elastohydrodynamic Lubricated Point Contact, IOP Conf. Ser. Mater. Sci. Eng., 2016, 149, p 1–9 J. Singh, G. Anand, D. Kumar, and N. Tandon, Graphene Based Composite Grease for Elastohydrodynamic Lubricated Point Contact, IOP Conf. Ser. Mater. Sci. Eng., 2016, 149, p 1–9
22.
go back to reference J. Singh, D. Kumar, and N. Tandon, Development of Nanocomposite Grease: Microstructure, Flow, and Tribological Studies, J. Tribol., 2017, 139, p 052001–052009 J. Singh, D. Kumar, and N. Tandon, Development of Nanocomposite Grease: Microstructure, Flow, and Tribological Studies, J. Tribol., 2017, 139, p 052001–052009
23.
go back to reference X. Fan, Y. Xia, L. Wang, and W. Li, Multilayer Graphene as a Lubricating Additive in Bentone Grease, Tribol. Lett., 2014, 55, p 455–464 X. Fan, Y. Xia, L. Wang, and W. Li, Multilayer Graphene as a Lubricating Additive in Bentone Grease, Tribol. Lett., 2014, 55, p 455–464
24.
go back to reference Z.L. Cheng and X.X. Qin, Study on Friction Performance of Graphene-Based Semi-solid Grease, Chin. Chem. Lett., 2014, 25, p 1305–1307 Z.L. Cheng and X.X. Qin, Study on Friction Performance of Graphene-Based Semi-solid Grease, Chin. Chem. Lett., 2014, 25, p 1305–1307
25.
go back to reference B.M. Kamel, A. Mohamed, M. El Sherbiny, K.A. Abed, and M. Abd-Rabou, Tribological Properties of Graphene Nanosheets as an Additive in Calcium Grease, J. Dispers. Sci. Technol., 2017, 38, p 1495–1500 B.M. Kamel, A. Mohamed, M. El Sherbiny, K.A. Abed, and M. Abd-Rabou, Tribological Properties of Graphene Nanosheets as an Additive in Calcium Grease, J. Dispers. Sci. Technol., 2017, 38, p 1495–1500
26.
go back to reference B.M. Kamel, A. Mohamed, M. El-Sherbiny, K.A. Abed, and M. Abd-Rabou, Rheological Characteristics of Modified Calcium Grease with Graphene Nanosheets, Fullerenes Nanotube Carbon Nanostruct., 2017, 25, p 429–434 B.M. Kamel, A. Mohamed, M. El-Sherbiny, K.A. Abed, and M. Abd-Rabou, Rheological Characteristics of Modified Calcium Grease with Graphene Nanosheets, Fullerenes Nanotube Carbon Nanostruct., 2017, 25, p 429–434
27.
go back to reference R. Gusain, H.P. Mungse, N. Kumar, T.R. Ravindran, R. Pandian, H. Sugimura, and O.P. Khatri, Covalently Attached Graphene-Ionic Liquid Hybrid Nanomaterials: Synthesis, Characterization and Tribological Application, J. Mater. Chem. A, 2016, 4, p 926–937 R. Gusain, H.P. Mungse, N. Kumar, T.R. Ravindran, R. Pandian, H. Sugimura, and O.P. Khatri, Covalently Attached Graphene-Ionic Liquid Hybrid Nanomaterials: Synthesis, Characterization and Tribological Application, J. Mater. Chem. A, 2016, 4, p 926–937
28.
go back to reference S. Choudhary, H.P. Mungse, and O.P. Khatri, Dispersion of Alkylated Graphene in Organic Solvents and Its Potential for Lubrication Applications, J. Mater. Chem., 2012, 22, p 21032–21039 S. Choudhary, H.P. Mungse, and O.P. Khatri, Dispersion of Alkylated Graphene in Organic Solvents and Its Potential for Lubrication Applications, J. Mater. Chem., 2012, 22, p 21032–21039
29.
go back to reference H.P. Mungse and O.P. Khatri, Chemically Functionalized Reduced Graphene Oxide as a Novel Material for Reduction of Friction and Wear, J. Phys. Chem. C, 2014, 118, p 14394–14402 H.P. Mungse and O.P. Khatri, Chemically Functionalized Reduced Graphene Oxide as a Novel Material for Reduction of Friction and Wear, J. Phys. Chem. C, 2014, 118, p 14394–14402
30.
go back to reference G. Wang, J. Yang, J. Park, X. Gou, B. Wang, H. Liu, and J. Yao, Facile Synthesis and Characterization of Graphene Nanosheets, J. Phys. Chem. C, 2008, 112, p 8192–8195 G. Wang, J. Yang, J. Park, X. Gou, B. Wang, H. Liu, and J. Yao, Facile Synthesis and Characterization of Graphene Nanosheets, J. Phys. Chem. C, 2008, 112, p 8192–8195
31.
go back to reference H.P. Mungse, R. Singh, H. Sugimura, N. Kumar, and O.P. Khatri, Molecular pillar Supported Graphene Oxide Framework: Conformational Heterogeneity and tunaBle d-Spacing, Phys. Chem. Chem. Phys., 2015, 17, p 20822–20829 H.P. Mungse, R. Singh, H. Sugimura, N. Kumar, and O.P. Khatri, Molecular pillar Supported Graphene Oxide Framework: Conformational Heterogeneity and tunaBle d-Spacing, Phys. Chem. Chem. Phys., 2015, 17, p 20822–20829
32.
go back to reference H.P. Mungse, N. Kumar, and O.P. Khatri, Synthesis, Dispersion and Lubrication Potential of Basal Plane Functionalized Alkylated Graphene Nanosheets, RSC Adv., 2015, 5, p 25565–25571 H.P. Mungse, N. Kumar, and O.P. Khatri, Synthesis, Dispersion and Lubrication Potential of Basal Plane Functionalized Alkylated Graphene Nanosheets, RSC Adv., 2015, 5, p 25565–25571
33.
go back to reference M. Acik, G. Lee, C. Mattevi, A. Pirkle, R.M. Wallace, M. Chhowalla, K. Cho, and Y. Chabal, The Role of Oxygen during Thermal Reduction of Graphene Oxide Studied by Infrared Absorption SPECTROSCOPY, J. Phys. Chem. C, 2011, 115, p 19761–19781 M. Acik, G. Lee, C. Mattevi, A. Pirkle, R.M. Wallace, M. Chhowalla, K. Cho, and Y. Chabal, The Role of Oxygen during Thermal Reduction of Graphene Oxide Studied by Infrared Absorption SPECTROSCOPY, J. Phys. Chem. C, 2011, 115, p 19761–19781
34.
go back to reference S.S. Rawat, A.P. Harsha, S. Das, and A.P. Deepak, Effect of CuO and ZnO Nano-additive on the Tribological Performance of Paraffin Oil-Based Lithium Grease, Tribol. Trans., 2019, 63, p 90–100 S.S. Rawat, A.P. Harsha, S. Das, and A.P. Deepak, Effect of CuO and ZnO Nano-additive on the Tribological Performance of Paraffin Oil-Based Lithium Grease, Tribol. Trans., 2019, 63, p 90–100
35.
go back to reference G.W. Stachowiak and A.W. Batchelor, Engineering Tribology, 4th ed., Butterworth-Heinemann, Oxford, 2013 G.W. Stachowiak and A.W. Batchelor, Engineering Tribology, 4th ed., Butterworth-Heinemann, Oxford, 2013
36.
go back to reference X. Fan, W. Li, H. Li, M. Zhu, Y. Xia, and J. Wang, Probing the Effect of Thickener on Tribological Properties of Lubricating Greases, Tribol. Int., 2018, 118, p 128–139 X. Fan, W. Li, H. Li, M. Zhu, Y. Xia, and J. Wang, Probing the Effect of Thickener on Tribological Properties of Lubricating Greases, Tribol. Int., 2018, 118, p 128–139
37.
go back to reference P.M. Lugt, A Review on Grease Lubrication in Rolling Bearings, Tribol. Trans., 2009, 52, p 470–480 P.M. Lugt, A Review on Grease Lubrication in Rolling Bearings, Tribol. Trans., 2009, 52, p 470–480
38.
go back to reference A. Adhvaryu, C. Sung, and S.Z. Erhan, Fatty Acids and Antioxidant Effects on Grease Microstructures, Ind. Crops Prod., 2005, 21, p 285–291 A. Adhvaryu, C. Sung, and S.Z. Erhan, Fatty Acids and Antioxidant Effects on Grease Microstructures, Ind. Crops Prod., 2005, 21, p 285–291
39.
go back to reference I. Couronné, P. Vergne, D. Mazuyer, N. Truong-Dinh, and D. Girodin, Effects of Grease Composition and Structure on Film Thickness in Rolling Contact, Tribol. Trans., 2003, 46, p 31–36 I. Couronné, P. Vergne, D. Mazuyer, N. Truong-Dinh, and D. Girodin, Effects of Grease Composition and Structure on Film Thickness in Rolling Contact, Tribol. Trans., 2003, 46, p 31–36
40.
go back to reference S.S. Rawat and A.P. Harsha, Current and future trends in grease lubrication, Automotive Tribology, 1st ed., J.B. Kumar, S. Bhattacharya, V.K. Patel, and V. Kumar, Ed., Springer, Singapore, 2019, p 147–182 S.S. Rawat and A.P. Harsha, Current and future trends in grease lubrication, Automotive Tribology, 1st ed., J.B. Kumar, S. Bhattacharya, V.K. Patel, and V. Kumar, Ed., Springer, Singapore, 2019, p 147–182
41.
go back to reference C. Gan, T. Liang, D. Chen, W. Li, X. Fan, G. Tang, B. Lin, and M. Zhu, Phosphonium-Organophosphate Modified Graphene gel Towards Lubrication Applications, Tribol. Int., 2020, 145, art. no. 106180 C. Gan, T. Liang, D. Chen, W. Li, X. Fan, G. Tang, B. Lin, and M. Zhu, Phosphonium-Organophosphate Modified Graphene gel Towards Lubrication Applications, Tribol. Int., 2020, 145, art. no. 106180
Metadata
Title
Effect of Graphene-Based Nanoadditives on the Tribological and Rheological Performance of Paraffin Grease
Authors
Sooraj Singh Rawat
A. P. Harsha
Ajay Chouhan
O. P. Khatri
Publication date
20-04-2020
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 4/2020
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-020-04789-8

Other articles of this Issue 4/2020

Journal of Materials Engineering and Performance 4/2020 Go to the issue

Premium Partners