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01-04-2015 | Original Paper

Effect of Ir and Pt Addition on the HDO Performance of RuS₂/SBA-15 Sulfide Catalysts

Authors: Antonia Infantes-Molina, Barbara Pawelec, Jose Luis G. Fierro, Cristina V. Loricera, Antonio Jiménez-López, Enrique Rodríguez-Castellón

Published in: Topics in Catalysis | Issue 4-6/2015

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Abstract

Ir and Pt have been tested as dopants for ruthenium sulfide supported on ordered SBA-15 mesoporous silica. The incorporation of Ir or Pt into RuS₂/SBA-15 was found to enhance the activity in the gas-phase hydrodeoxygenation (HDO) of phenol carried out at 310 °C and 30 bar of total H₂ pressure. X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy, temperature programmed desorption of NH₃ and H₂-temperature-programmed reduction of the sulfided catalysts were used to characterize the catalysts. XPS analysis of the spent catalysts confirmed the oxidation of ruthenium sulfide during HDO of phenol. The main factor that influences the catalyst activity was the surface exposure of the active phases, whereas the formation of oxysulfide species did not inhibit the HDO reaction.

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Title: Effect of Ir and Pt Addition on the HDO Performance of RuS2/SBA-15 Sulfide Catalysts
Authors: Antonia Infantes-Molina
Barbara Pawelec
Jose Luis G. Fierro
Cristina V. Loricera
Antonio Jiménez-López
Enrique Rodríguez-Castellón
Publication date: 01-04-2015
Publisher: Springer US
Published in: Topics in Catalysis / Issue 4-6/2015
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-015-0366-0

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