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Journal of Materials Science

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22-06-2020 | Chemical routes to materials

Effect of support morphology on the activity and reusability of Pd/SiO₂ for NBR hydrogenation

Authors: Peng Zhang, Hongwei Zhang, Shuhan Wang, Xueqin Lei, Jiangtao Yang, Zimeng Li, Haibo Zhu, Xiaojun Bao, Pei Yuan

Published in: Journal of Materials Science | Issue 27/2020

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Abstract

Silica hollow microspheres with moonscape-like rough surface (RS) and macroporous surface (MS) have been controllably synthesized by a water–oil–water three-phase emulsion method, which are used as supports of the heterogeneous catalysts for the catalytic hydrogenation of nitrile-butadiene rubber (NBR). It is found that Pd can be uniformly dispersed on both amino-functionalized RS and MS supports and both the catalysts show high hydrogenation activity with 100% selectivity to C=C bonds. However, the reusability of Pd/N-RS is much better than that of Pd/N-MS, maintaining 92% of activity without any regeneration treatment after five times of recycling experiment. The high activity retention is because the moonscape-like surface of the RS support is favorable for the contact of NBR macromolecules with the active sites, and more importantly, the NBR macromolecules do not need to diffuse into the interior of the catalyst, leading to fast desorption of the hydrogenated NBR from the surface of catalyst and re-exposure of the active sites.

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Title: Effect of support morphology on the activity and reusability of Pd/SiO2 for NBR hydrogenation
Authors: Peng Zhang
Hongwei Zhang
Shuhan Wang
Xueqin Lei
Jiangtao Yang
Zimeng Li
Haibo Zhu
Xiaojun Bao
Pei Yuan
Publication date: 22-06-2020
Publisher: Springer US
Published in: Journal of Materials Science / Issue 27/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-04986-9

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