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Metallurgical and Materials Transactions A
Published in: Metallurgical and Materials Transactions A 10/2018

11-07-2018

Effect of Temperature on the Initial Oxidation Behavior and Kinetics of 5Cr Ferritic Steel in Air

Authors: Enhui Wang, Jin Cheng, Jiawei Ma, Huibin Wu, Junhong Chen, Kuochih Chou, Xinmei Hou

Published in: Metallurgical and Materials Transactions A | Issue 10/2018

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Abstract

The oxidation behavior of 5 wt pct Cr (5Cr) ferritic steel in air at high temperatures has been investigated. A connected Cu-rich layer adjacently forms in inner oxidation layer (IOL) at 500 °C to 600 °C in addition to the formation of a continuous Cr-rich and Si-rich ribbon. Their synergistic effects imped growth of the Fe-rich oxide film towards the outer oxidation layer (OOL) and thus improve the oxidation resistance of 5Cr steel. With increasing oxidation temperature, the Cr, Si, and Cu oxide scales are gradually damaged and spallation of the oxide scale occurs at 1000 °C. Regarding the reaction kinetics, oxidation is controlled by oxygen inward diffusion. A gas–solid model is used to describe the oxidation behavior of 5Cr steel at 500 °C to 900 °C and there is good agreement with the experimental data. In particular, this model can predict the oxidation behavior and the typical results at 750 °C and 850 °C are provided.
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Metadata
Title
Effect of Temperature on the Initial Oxidation Behavior and Kinetics of 5Cr Ferritic Steel in Air
Authors
Enhui Wang
Jin Cheng
Jiawei Ma
Huibin Wu
Junhong Chen
Kuochih Chou
Xinmei Hou
Publication date
11-07-2018
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 10/2018
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-018-4781-2

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