Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 8/2017

06-07-2017

Effects of Duplex Nitriding and TiN Coating Treatment on Wear Resistance, Corrosion Resistance and Biocompatibility of Ti6Al4V Alloy

Authors: W. H. Kao, Y. L. Su, Y. T. Hsieh

Published in: Journal of Materials Engineering and Performance | Issue 8/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Ti6Al4V alloy substrates were nitrided at 900 °C. TiN coatings were then deposited on the nitrided substrates using a closed-field unbalanced magnetron sputtering system. The microstructure, hardness and adhesion properties of the TiN-N-Ti6Al4V substrates were evaluated and compared with those of an untreated Ti6Al4V sample, a nitrided Ti6Al4V sample and a TiN-coated Ti6Al4V sample, respectively. The tribological properties of the various samples were investigated by means of reciprocating sliding wear tests performed in 0.9 wt.% NaCl solution against 316L, Si3N4 and Ti6Al4V balls, respectively. In addition, the corrosion resistance was evaluated using potentiodynamic polarization tests. Finally, the biocompatibility of the samples was investigated by observing the attachment and growth of purified mouse leukemic monocyte/macrophage cells (Raw 264.7) on the sample surface after culturing periods of 24, 72 and 120 h, respectively. Overall, the results showed that the duplex nitriding/TiN coating treatment significantly improved the tribological, anti-corrosion and biocompatibility properties of the original Ti6Al4V alloy.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference C. Martini, L. Ceschini, B. Casadei, I. Boromei, and J.B. Guion, Dry Sliding Behaviour of Hydrogenated Amorphous Carbon (a-C:H) Coatings on Ti-6Al-4V, Wear, 2011, 271, p 2025–2036CrossRef C. Martini, L. Ceschini, B. Casadei, I. Boromei, and J.B. Guion, Dry Sliding Behaviour of Hydrogenated Amorphous Carbon (a-C:H) Coatings on Ti-6Al-4V, Wear, 2011, 271, p 2025–2036CrossRef
2.
go back to reference S.R. Hosseini and A. Ahmadi, Evaluation of the Effects of Plasma Nitriding Temperature and Time on the Characterisation of Ti 6Al 4V Alloy, Vacuum, 2013, 87, p 30–39CrossRef S.R. Hosseini and A. Ahmadi, Evaluation of the Effects of Plasma Nitriding Temperature and Time on the Characterisation of Ti 6Al 4V Alloy, Vacuum, 2013, 87, p 30–39CrossRef
3.
go back to reference W.H. Kao, Y.L. Su, J.H. Horng, and H.C. Huang, The Tribological Performance of Surface Treated Ti6A14V as Sliding Against Si3N4 Ball and 316L Stainless Steel Cylinder, J. Mater. Eng. Perform., 2016, 25(12), p 5209–5219CrossRef W.H. Kao, Y.L. Su, J.H. Horng, and H.C. Huang, The Tribological Performance of Surface Treated Ti6A14V as Sliding Against Si3N4 Ball and 316L Stainless Steel Cylinder, J. Mater. Eng. Perform., 2016, 25(12), p 5209–5219CrossRef
4.
go back to reference D. Rodriguez, F.J. Gil, J.A. Planell, and J. Biomech, Wear Resistance of the Nitrogen Diffusion, Hardening of the Ti-6AI-4V Alloy, J. Biomech., 1998, 31, p 49CrossRef D. Rodriguez, F.J. Gil, J.A. Planell, and J. Biomech, Wear Resistance of the Nitrogen Diffusion, Hardening of the Ti-6AI-4V Alloy, J. Biomech., 1998, 31, p 49CrossRef
5.
go back to reference B.R. Lanning and R.H. Wei, High Intensity Plasma Ion Nitriding of Orthopedic Materials Part II. Microstructural Analysis, Surf. Coat. Technol., 2004, 186, p 314–319CrossRef B.R. Lanning and R.H. Wei, High Intensity Plasma Ion Nitriding of Orthopedic Materials Part II. Microstructural Analysis, Surf. Coat. Technol., 2004, 186, p 314–319CrossRef
6.
go back to reference A.H. Liu, J.N. Deng, H.B. Cui, Y.Y. Chen, and J. Zhao, Friction and Wear Properties of TiN, TiAlN, AlTiN and CrAlN PVD Nitride Coatings, Int. J. Refract. Metals Hard Mater., 2012, 31, p 82–88CrossRef A.H. Liu, J.N. Deng, H.B. Cui, Y.Y. Chen, and J. Zhao, Friction and Wear Properties of TiN, TiAlN, AlTiN and CrAlN PVD Nitride Coatings, Int. J. Refract. Metals Hard Mater., 2012, 31, p 82–88CrossRef
7.
go back to reference M.P. Gispert, A.P. Serro, R. Colac, E. Pires, and B. Saramago, Wear of Ceramic Coated Metal-on-Metal Bearings Used for Hip Replacement, Wear, 2007, 263, p 1060–1065CrossRef M.P. Gispert, A.P. Serro, R. Colac, E. Pires, and B. Saramago, Wear of Ceramic Coated Metal-on-Metal Bearings Used for Hip Replacement, Wear, 2007, 263, p 1060–1065CrossRef
8.
go back to reference T. Grogler, O. Plewa, S.M. Rosiwal, and R.F. Singer, CVD Diamond Films as Protective Coatings on Titanium Alloys, Int. J. Refract. Metals Hard Mater., 1998, 16, p 217–222CrossRef T. Grogler, O. Plewa, S.M. Rosiwal, and R.F. Singer, CVD Diamond Films as Protective Coatings on Titanium Alloys, Int. J. Refract. Metals Hard Mater., 1998, 16, p 217–222CrossRef
9.
go back to reference Y. Balcaen, N. Radutoiu, J. Alexis, J.D. Beguin, L. Lacroix, D. Samélor, and C. Vahlas, Mechanical and Barrier Properties of MOCVD Processed Alumina Coatings on Ti6Al4V Titanium Alloy, Surf. Coat. Technol., 2011, 206, p 1684–1690CrossRef Y. Balcaen, N. Radutoiu, J. Alexis, J.D. Beguin, L. Lacroix, D. Samélor, and C. Vahlas, Mechanical and Barrier Properties of MOCVD Processed Alumina Coatings on Ti6Al4V Titanium Alloy, Surf. Coat. Technol., 2011, 206, p 1684–1690CrossRef
10.
go back to reference V. Fouquet, L. Pichon, M. Drouet, and A. Straboni, Plasma Assisted Nitridation of Ti-6Al-4V, Appl. Surf. Sci., 2004, 221, p 248–258CrossRef V. Fouquet, L. Pichon, M. Drouet, and A. Straboni, Plasma Assisted Nitridation of Ti-6Al-4V, Appl. Surf. Sci., 2004, 221, p 248–258CrossRef
11.
go back to reference F. Yildiz, A.F. Yetim, A. Alsaran, and A. Çelik, Plasma Nitriding Behavior of Ti6Al4V Orthopedic Alloy, Surf. Coat. Technol., 2008, 202, p 2471–2476CrossRef F. Yildiz, A.F. Yetim, A. Alsaran, and A. Çelik, Plasma Nitriding Behavior of Ti6Al4V Orthopedic Alloy, Surf. Coat. Technol., 2008, 202, p 2471–2476CrossRef
12.
go back to reference D. Nolan, S.W. Huang, V. Leskovsek, and S. Braun, Sliding Wear of Titanium Nitride Thin Films Deposited on Ti-6Al-4V Alloy by PVD and Plasma Nitriding Processes, Surf. Coat. Technol., 2006, 200, p 5698–5705CrossRef D. Nolan, S.W. Huang, V. Leskovsek, and S. Braun, Sliding Wear of Titanium Nitride Thin Films Deposited on Ti-6Al-4V Alloy by PVD and Plasma Nitriding Processes, Surf. Coat. Technol., 2006, 200, p 5698–5705CrossRef
13.
go back to reference S. Novak and M. Komac, Wear of Cermet Cutting Tools Coated with Physically Vapour Deposited TiN, Wear, 1997, 205, p 160–168CrossRef S. Novak and M. Komac, Wear of Cermet Cutting Tools Coated with Physically Vapour Deposited TiN, Wear, 1997, 205, p 160–168CrossRef
14.
go back to reference J.Y. Heo, S.H. Cho, T.J. Je, K.H. Kim, H.W. Lee, and M.C. Kang, Effects of Honing Treatment on AIP-TiN and TiAlN Coated End-Mill for High Speed Machining, Trans. Nonferr. Metals Soc. China, 2011, 21, p s83–s87CrossRef J.Y. Heo, S.H. Cho, T.J. Je, K.H. Kim, H.W. Lee, and M.C. Kang, Effects of Honing Treatment on AIP-TiN and TiAlN Coated End-Mill for High Speed Machining, Trans. Nonferr. Metals Soc. China, 2011, 21, p s83–s87CrossRef
15.
go back to reference C.H. Hsu, K.H. Huang, and M.R. Lin, Annealing Effect on Tribological Property of Arc-Deposited TiN Film on 316L Austenitic Stainless Steel, Surf. Coat. Technol., 2014, 259, p 167–171CrossRef C.H. Hsu, K.H. Huang, and M.R. Lin, Annealing Effect on Tribological Property of Arc-Deposited TiN Film on 316L Austenitic Stainless Steel, Surf. Coat. Technol., 2014, 259, p 167–171CrossRef
16.
go back to reference C.L. Liu, D.H. Yang, G.Q. Lin, and M. Qi, Corrosion Resistance and Hemocompatibility of Multilayered Ti/TiN-Coated Surgical AISI, 316L Stainless Steel, Mater. Lett., 2005, 59, p 3813–3819CrossRef C.L. Liu, D.H. Yang, G.Q. Lin, and M. Qi, Corrosion Resistance and Hemocompatibility of Multilayered Ti/TiN-Coated Surgical AISI, 316L Stainless Steel, Mater. Lett., 2005, 59, p 3813–3819CrossRef
17.
go back to reference C. Liu, Q. Bi, and A. Matthews, Tribological and Electrochemical Performance of PVD TiN Coatings on the Femoral Head of Ti-6Al-4V Artificial Hip Joints, Surf. Coat. Technol., 2003, 163-164, p 597–604CrossRef C. Liu, Q. Bi, and A. Matthews, Tribological and Electrochemical Performance of PVD TiN Coatings on the Femoral Head of Ti-6Al-4V Artificial Hip Joints, Surf. Coat. Technol., 2003, 163-164, p 597–604CrossRef
18.
go back to reference R.J. Tian and J.C. Sun, Corrosion Resistance and Interfacial Contact Resistance of TiN Coated 316L Bipolar Plates for Proton Exchange Membrane Fuel Cell, Int. J. Hydrogen Energy, 2011, 36, p 6788–6794CrossRef R.J. Tian and J.C. Sun, Corrosion Resistance and Interfacial Contact Resistance of TiN Coated 316L Bipolar Plates for Proton Exchange Membrane Fuel Cell, Int. J. Hydrogen Energy, 2011, 36, p 6788–6794CrossRef
19.
go back to reference C. Liu, Q. Bi, and A. Matthews, Tribological and Electrochemical Performance of PVD TiN Coatings on the Femoral Head of Ti-6Al-4V Artificial Hip Joints, Surf. Coat. Technol., 2003, 163-164, p 597–604CrossRef C. Liu, Q. Bi, and A. Matthews, Tribological and Electrochemical Performance of PVD TiN Coatings on the Femoral Head of Ti-6Al-4V Artificial Hip Joints, Surf. Coat. Technol., 2003, 163-164, p 597–604CrossRef
20.
go back to reference L. Escalada, J. Lutz, S.P. Brühl, M. Fazio, A. Márquez, S. Mändl, D. Manova, and S.N. Simison, Microstructure and Corrosion Behavior of AISI, 316L Duplex Treated by Means of Ion Nitriding and Plasma Based Ion Implantation and Deposition, Surf. Coat. Technol., 2013, 223, p 41–46CrossRef L. Escalada, J. Lutz, S.P. Brühl, M. Fazio, A. Márquez, S. Mändl, D. Manova, and S.N. Simison, Microstructure and Corrosion Behavior of AISI, 316L Duplex Treated by Means of Ion Nitriding and Plasma Based Ion Implantation and Deposition, Surf. Coat. Technol., 2013, 223, p 41–46CrossRef
21.
go back to reference E. De Las Heras, D.A. Egidi, P. Corengia, D. González-Santamaría, A. García-Luis, M. Brizuela, G.A. López, and M. Flores Martinez, Duplex Surface Treatment of an AISI, 316L Stainless Steel; Microstructure and Tribological Behavior, Surf. Coat. Technol., 2008, 202, p 2945–2954CrossRef E. De Las Heras, D.A. Egidi, P. Corengia, D. González-Santamaría, A. García-Luis, M. Brizuela, G.A. López, and M. Flores Martinez, Duplex Surface Treatment of an AISI, 316L Stainless Steel; Microstructure and Tribological Behavior, Surf. Coat. Technol., 2008, 202, p 2945–2954CrossRef
22.
go back to reference S. Mukherjee, M.F. Maitz, M.T. Pham, E. Richter, F. Prokert, and W. Moeller, Development and Biocompatibility of Hard Ti-Based Coatings Using Plasma Immersion Ion Implantation-Assisted Deposition, Surf. Coat. Technol., 2005, 196, p 312–316CrossRef S. Mukherjee, M.F. Maitz, M.T. Pham, E. Richter, F. Prokert, and W. Moeller, Development and Biocompatibility of Hard Ti-Based Coatings Using Plasma Immersion Ion Implantation-Assisted Deposition, Surf. Coat. Technol., 2005, 196, p 312–316CrossRef
23.
go back to reference S. Jin, Y. Zhang, Q. Wang, D. Zhang, and S. Zhang, Influence of TiN Coating on the Biocompatibility of Medical NiTi Alloy, Colloids Surf. B, 2013, 101, p 343–349CrossRef S. Jin, Y. Zhang, Q. Wang, D. Zhang, and S. Zhang, Influence of TiN Coating on the Biocompatibility of Medical NiTi Alloy, Colloids Surf. B, 2013, 101, p 343–349CrossRef
24.
go back to reference J. Zuo, Y.N. Xie, J. Zhang, Q.P. Wei, B. Zhou, J.Q. Luo, Y.J. Wang, Z.M. Yu, and Z.G. Tang, TiN Coated Stainless Steel Bracket: Tribological, Corrosion Resistance, Biocompatibility and Mechanical Performance, Surf. Coat. Technol., 2015, 277, p 227–233CrossRef J. Zuo, Y.N. Xie, J. Zhang, Q.P. Wei, B. Zhou, J.Q. Luo, Y.J. Wang, Z.M. Yu, and Z.G. Tang, TiN Coated Stainless Steel Bracket: Tribological, Corrosion Resistance, Biocompatibility and Mechanical Performance, Surf. Coat. Technol., 2015, 277, p 227–233CrossRef
25.
go back to reference I. Mutlu, Sinter-Coating Method for the Production of TiN-Coated Titanium Foam for Biomedical Implant Applications, Surf. Coat. Technol., 2013, 232, p 396–402CrossRef I. Mutlu, Sinter-Coating Method for the Production of TiN-Coated Titanium Foam for Biomedical Implant Applications, Surf. Coat. Technol., 2013, 232, p 396–402CrossRef
26.
go back to reference C.L. Liu, P.K. Chu, G.Q. Lin, and M. Qi, Anti-Corrosion Characteristics of Nitride-Coated AISI, 316L Stainless Steel Coronary Stents, Surf. Coat. Technol., 2006, 201, p 2802–2806CrossRef C.L. Liu, P.K. Chu, G.Q. Lin, and M. Qi, Anti-Corrosion Characteristics of Nitride-Coated AISI, 316L Stainless Steel Coronary Stents, Surf. Coat. Technol., 2006, 201, p 2802–2806CrossRef
27.
go back to reference S.H. Yao, Y.L. Su, W.H. Kao, and T.H. Liu, Tribology and Oxidation Behavior of TiN/AlN Nano-Multilayer Films, Tribol. Int., 2006, 39, p 332–341CrossRef S.H. Yao, Y.L. Su, W.H. Kao, and T.H. Liu, Tribology and Oxidation Behavior of TiN/AlN Nano-Multilayer Films, Tribol. Int., 2006, 39, p 332–341CrossRef
28.
go back to reference T. Arai, H. Fujita, and M. Watanabe, Evaluation of Adhesion Strength of Thin Hard Coatings, Thin Solid Films, 1987, 154, p 387–401CrossRef T. Arai, H. Fujita, and M. Watanabe, Evaluation of Adhesion Strength of Thin Hard Coatings, Thin Solid Films, 1987, 154, p 387–401CrossRef
29.
go back to reference A.C. Hee, S.S. Jamali, A. Bendavid, P.J. Martin, C. Kong, and Y. Zhao, Corrosion Behaviour and Adhesion Properties of Sputtered Tantalum Coating on Ti6Al4V Substrate, Surf. Coat. Technol., 2016, 307, p 666–675CrossRef A.C. Hee, S.S. Jamali, A. Bendavid, P.J. Martin, C. Kong, and Y. Zhao, Corrosion Behaviour and Adhesion Properties of Sputtered Tantalum Coating on Ti6Al4V Substrate, Surf. Coat. Technol., 2016, 307, p 666–675CrossRef
30.
go back to reference A.K. Bhattacharya and W.D. Nix, Analysis of Elastic and Plastic Deformation Associated with Indentation Testing of Thin Films on Substrates, Int. J. Solids Struct., 1988, 24, p 1287–1298CrossRef A.K. Bhattacharya and W.D. Nix, Analysis of Elastic and Plastic Deformation Associated with Indentation Testing of Thin Films on Substrates, Int. J. Solids Struct., 1988, 24, p 1287–1298CrossRef
31.
go back to reference L.A. Cyster, K.G. Parker, T.L. Parker, and D.M. Grant, The Effect of Surface Chemistry and Nanotopography of Titanium Nitride Films on 3T3-L1 Fibroblasts, J. Biomed. Mater. Res., 2003, 67A, p 138–147CrossRef L.A. Cyster, K.G. Parker, T.L. Parker, and D.M. Grant, The Effect of Surface Chemistry and Nanotopography of Titanium Nitride Films on 3T3-L1 Fibroblasts, J. Biomed. Mater. Res., 2003, 67A, p 138–147CrossRef
32.
go back to reference W.H. Kao, Y.L. Su, J.H. Horng, and K.X. Zhang, Effects of Ti-C:H Coating and Plasma Nitriding Treatment on Tribological, Electrochemical, and Biocompatibility Properties of AISI, 316L, J. Biomater. Appl., 2016, 31(2), p 215–229CrossRef W.H. Kao, Y.L. Su, J.H. Horng, and K.X. Zhang, Effects of Ti-C:H Coating and Plasma Nitriding Treatment on Tribological, Electrochemical, and Biocompatibility Properties of AISI, 316L, J. Biomater. Appl., 2016, 31(2), p 215–229CrossRef
33.
go back to reference P. Yang, N. Huang, Y.X. Leng, Z.Q. Yao, H.F. Zhou, M. Maitz, Y. Leng, and P.K. Chu, Wettability and Biocompatibility of Nitrogen-Doped Hydrogenated Amorphous Carbon Films: Effect of Nitrogen, Nucl. Instrum. Methods Phys. Res. Sect. B, 2006, 242, p 22–25CrossRef P. Yang, N. Huang, Y.X. Leng, Z.Q. Yao, H.F. Zhou, M. Maitz, Y. Leng, and P.K. Chu, Wettability and Biocompatibility of Nitrogen-Doped Hydrogenated Amorphous Carbon Films: Effect of Nitrogen, Nucl. Instrum. Methods Phys. Res. Sect. B, 2006, 242, p 22–25CrossRef
34.
go back to reference C.C. Chien, K.T. Liu, J.G. Duh, K.W. Chang, and K.H. Chung, Effect of Nitride Film Coatings on Cell Compatibility, Dent. Mater., 2008, 24, p 986–993CrossRef C.C. Chien, K.T. Liu, J.G. Duh, K.W. Chang, and K.H. Chung, Effect of Nitride Film Coatings on Cell Compatibility, Dent. Mater., 2008, 24, p 986–993CrossRef
Metadata
Title
Effects of Duplex Nitriding and TiN Coating Treatment on Wear Resistance, Corrosion Resistance and Biocompatibility of Ti6Al4V Alloy
Authors
W. H. Kao
Y. L. Su
Y. T. Hsieh
Publication date
06-07-2017
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 8/2017
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-017-2815-3

Other articles of this Issue 8/2017

Journal of Materials Engineering and Performance 8/2017 Go to the issue

Premium Partners