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Journal of Materials Engineering and Performance

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01-09-2015

Effects of Nitrogen on Passivity of Nickel-Free Stainless Steels by Electrochemical Impedance Spectroscopy Analysis

Authors: Xinqiang Wu, Yao Fu, Wei Ke, Song Xu, Bing Feng, Botao Hu

Published in: Journal of Materials Engineering and Performance | Issue 9/2015

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Abstract

The effects of different nitrogen contents on the passivity of nickel-free stainless steels in 0.5 M sulfuric acid + 0.5 M sodium chloride solution were investigated by electrochemical impedance spectroscopy in the potential ranges of active dissolution and active-passive transition. A simplified reaction model containing adsorbed intermediates involved dissolution process, and passivation process was proposed to explain the impedance characteristics. Based on both equivalent circuit and mathematical model analysis, the effects of nitrogen on the passivity of stainless steels are discussed.

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Title: Effects of Nitrogen on Passivity of Nickel-Free Stainless Steels by Electrochemical Impedance Spectroscopy Analysis
Authors: Xinqiang Wu
Yao Fu
Wei Ke
Song Xu
Bing Feng
Botao Hu
Publication date: 01-09-2015
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 9/2015
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-015-1646-3

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