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Polymer Bulletin
Published in: Polymer Bulletin 8/2023

10-10-2022 | Original Paper

Elaboration and characterization of new adsorbents based on conducting PANI/zeolite HY/TiO2 nanocomposite applied for chromate adsorption

Authors: Z. Ghebache, Z. Safidine, F. Hamidouche, N. Boudieb, A. Benaboura, M. Trari

Published in: Polymer Bulletin | Issue 8/2023

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Abstract

The preparation of polyaniline/HY/TiO2 p–n heterojunction/polymer is successfully performed by in situ chemical polymerization of aniline doped by 5 w% of HY zeolite (acid solid) using persulfate (NH4)2S2O8 as oxidant in aqueous solution containing 5 to 20 wt% of TiO2 with respect to aniline monomer quantity. The product is characterized by X-ray diffraction (XRD), FT-IR spectroscopy, SEM analysis, thermal gravimetry, UV–visible diffuse reflectance and electrical conductivity. The FT-IR spectra revealed the presence of TiO2 and PANI as a main matrix in nanocomposites while the XRD patterns show that the diameter of PANI/HY/TiO2 lies between 20 and 70 nm. In the second part, we investigate the effect of the physical parameters on the equilibrium adsorption of chromate Cr(VI) on PANI/HY/TiO2 nanocomposites. The adsorption characteristics of the composite toward Cr(VI) are followed by atomic absorption spectroscopy (AAS). The effect of contact time, sorbent size and Cr(VI) initial concentration (Co) on the Cr(VI) uptake is also studied. It has been observed that the capacity of Cr(VI) adsorption on PANI/HY/TiO2 increases with increasing Co while the PANI/HY/5TiO2 has a larger uptake capacity. The isotherm data are well fitted with the Langmuir isotherm model with maximum adsorption capacity of 454.54 mg/g. The calculated thermodynamic parameters showed that the Cr(VI) adsorption onto PANI/HY/5TiO2 is endothermic (ΔH° = 12.478 kJ/mol) and spontaneous (ΔG°300 K = − 11.186 kJ/mol).
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Metadata
Title
Elaboration and characterization of new adsorbents based on conducting PANI/zeolite HY/TiO2 nanocomposite applied for chromate adsorption
Authors
Z. Ghebache
Z. Safidine
F. Hamidouche
N. Boudieb
A. Benaboura
M. Trari
Publication date
10-10-2022
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 8/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-022-04500-y

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