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Published in: Journal of Materials Science: Materials in Electronics 23/2020

23-10-2020

Electro-codeposition of V2O5-polyaniline composite on Ni foam as an electrode for supercapacitor

Authors: Asma Aamir, Adil Ahmad, Said Karim Shah, Noor ul Ain, Mazhar Mehmood, Yaqoob Khan, Zia ur Rehman

Published in: Journal of Materials Science: Materials in Electronics | Issue 23/2020

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Abstract

To fulfill the increasing energy demand, it is necessary to develop such an electrode material for pseudocapacitors having a high energy density, better cycle life, and potential for commercialization. Herein, we report an electro-codeposition technique to fabricate a high-performance V2O5-PANi composite deposited on the metallic Nickel foam substrate as an electrode for pseudocapacitors. Ni foam serves as a porous and conductive framework and therefore shortens the ions diffusion pathway. Composite shows good performance than pure V2O5 and PANi due to their synergistic effect. X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX) analysis have confirmed the successful incorporation of metal oxide into the polymer backbone. Moreover, V2O5-PANi composite exhibited a very wide voltage window of 2.5V (between − 1 and 1.5V vs. SCE), the highest specific capacitance of 1115 F/g, and less charge transfer resistance. The ability to prepare composite electrodes with high performance via a binder-free electro-codeposition technique could open up new prospects for high energy density pseudocapacitors.

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Metadata
Title
Electro-codeposition of V2O5-polyaniline composite on Ni foam as an electrode for supercapacitor
Authors
Asma Aamir
Adil Ahmad
Said Karim Shah
Noor ul Ain
Mazhar Mehmood
Yaqoob Khan
Zia ur Rehman
Publication date
23-10-2020
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 23/2020
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04616-9

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